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EP0339821A1 Expired / Lapsed EP ⏱️ 0.0 years remaining

Bonding to metal surfaces

Assignee: United Kingdom Atomic Energy Authority
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Filing: 1989-04-11
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Granted: —
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Expires: 2009-04-11
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Abstract

Abstract Metal surfaces have chemical species, e.g. biologically active water-soluble macromolecular substances such as proteins, bonded thereto by means of an interposed coordinating polymer. The polymer has a first set of functional groups bonded to the surface and a second set of functional groups bonded to the species; the groups of the first set are pendant from the polymer chain or form part thereof, each such group preferably containing an atom with electrons for donation to the metal surface to form the bond therewith. The metal may be a transition metal such as a Group 11 metal, e.g. Au or Ag, and, in the coordinating polymer, the sets may comprise functional groups that are the same or different chemically, e.g. the first set may comprise S-containing groups and the second set amino groups. A specific example of co-ordinating polymer that may be used is a water soluble form of poly(iminoethene)N-dithiocarboxylate. Metal surfaces so treated may be useful as biosensor materials such as in immunosensors.

Inventors

  • 👤 Andrew Thomas Chadwick
  • 👤 Michael James Hudson

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-03 05:15
CPC Classifications
G; G01; G01N; G01N33/00; G01N33/48; G01N33/50; G01N33/53; G01N33/543; G01N33/551; G01N33/553; G01N33/54353

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 63 words
A metal surface having a chemical species bonded thereto by means of an interposed polymer, characterised in that the polymer is a co-ordinating polymer having a first set of functional groups bonded to the surface and having a second set of functional groups bonded to the species, the groups of the first set being pendant from the polymer chain or forming part thereof.
Claim 2
Dependent Claim 63 words
A metal surface having a chemical species bonded thereto by means of an interposed polymer, characterised in that the polymer is a co-ordinating polymer having a first set of functional groups bonded to the surface and having a second set of functional groups bonded to the species, the groups of the first set being pendant from the polymer chain or forming part thereof.
Claim 3
Dependent Claim 22 words
A metal surface according to claim 1 wherein the metal is a metal of Group II (formerly 1B) of the Periodic Table.
Claim 4
Dependent Claim 20 words
A metal surface according to either of the preceding claims wherein the coordinating polymer is a polyimine or a polythiol.
Claim 5
Dependent Claim 30 words
A metal surface according to any of the preceding claims wherein the groups of the first set are S-containing groups and the groups of the second set are amino groups.
Claim 6
Dependent Claim 13 words
A metal surface according to claim 4 wherein the coordinating polymer is poly(iminoethene)N-dithiocarboxylate.
Claim 7
Dependent Claim 21 words
A metal surface according to any of the preceding claims wherein the chemical species is a biologically active, water-soluble macromolecular substance.
Claim 8
Dependent Claim 13 words
A metal surface according to claim 6 wherein the substance is a protein.
Claim 9
Dependent Claim 13 words
A metal surface according to claim 7 wherein the protein is an antibody.
Claim 10
Independent Claim 103 words
A method of bonding a chemical species to a metal surface, characterised by the steps of (i) bonding a co-ordinating polymer to a metal surface, the polymer having a first set of functional groups capable of bonding to the surface and having a second set of functional groups capable of bonding to the chemical species, the groups of the first set being pendant from the polymer chain or forming part thereof, the second set being such that the groups thereof do not bond to the metal surface; and (ii) bonding the chemical species to the polymer via the second set of functional groups.
Claim 11
Independent Claim 103 words
A method of bonding a chemical species to a metal surface, characterised by the steps of (i) bonding a co-ordinating polymer to a metal surface, the polymer having a first set of functional groups capable of bonding to the surface and having a second set of functional groups capable of bonding to the chemical species, the groups of the first set being pendant from the polymer chain or forming part thereof, the second set being such that the groups thereof do not bond to the metal surface; and (ii) bonding the chemical species to the polymer via the second set of functional groups.
Claim 12
Dependent Claim 66 words
A method according to claim 9 wherein the coordinating polymer is water-soluble and step (i) is carried out by contacting an aqueous solution thereof with the metal surface, and wherein the chemical species is a biologically active, water-soluble macromolecular substance and step (ii) is carried out by contacting the metal surface to which the polymer has been bonded with an aqueous solution of the chemical species.

References Cited (Backward Citations)

GB1500127A Cited
US3979184A Cited
GB2136953A Cited
WO1986003837A1 Cited
EP0254575A2 Cited

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