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EP0339536A1 Expired / Lapsed EP ⏱️ 0.0 years remaining

Plating bath for electrodeposition of aluminum and plating process making use of the bath

Assignee: Mitsubishi Chemical Corp
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Filing: 1989-04-24
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Granted: —
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Expires: 2009-04-24
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Abstract

Abstract In the plating for electrodeposition of aluminum using a mixed molten salt bath comprising an aluminum halide and a quaternary ammonium salt, the mixed molten salt bath comprises from 20 to 80 mol % of the aluminum halide and from 20 to 80 mol % of a 1-alkyl- or 1,3-­dialkylimidazolium halide, provided that the alkyl group has 1 to 12 carbon atoms, by the use of which the plating can be carried out at a high current density of not less than 30 A/dm² without generation of burnt deposits, which has been difficult to carry out using the conventional molten salt bath. Addition of a halide of an alkali metal or alkaline earth metal, or an organic solvent, to the above plating bath can improve conductivity and also enhance uniform electrodeposition performance.

Inventors

  • 👤 Setsuko Takahashi

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-02 00:21
CPC Classifications
C; C25; C25D; C25D3/00; C25D3/02; C25D3/42; C25D3/44

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 46 words
A plating bath for electrodeposition of aluminum, comprising a molten mixture comprising from 20 to 80 mol % of an aluminum halide, and from 20 to 80 mol % of a 1-­alkyl- or 1,3-dialkylimidazolium halide, provided that the alkyl group has 1 to 12 carbon atoms.
Claim 2
Dependent Claim 46 words
A plating bath for electrodeposition of aluminum, comprising a molten mixture comprising from 20 to 80 mol % of an aluminum halide, and from 20 to 80 mol % of a 1-­alkyl- or 1,3-dialkylimidazolium halide, provided that the alkyl group has 1 to 12 carbon atoms.
Claim 3
Dependent Claim 25 words
The plating bath for electrodeposition of aluminum according to Claim 1, wherein a halide of an alkali metal or alkaline earth metal is further added.
Claim 4
Dependent Claim 18 words
The plating bath for electrodeposition of aluminum according to Claim 1, wherein an organic solvent is further added.
Claim 5
Dependent Claim 18 words
The plating bath for electrodeposition of aluminum according to Claim 2, wherein an organic solvent is further added.
Claim 6
Dependent Claim 95 words
A plating process for electrodeposition of aluminum, comprising carrying out plating by use of a plating bath for electrodeposition of aluminum, comprising a molten mixture comprising from 20 to 80 mol % of an aluminum halide, and from 20 to 80 mol % of a 1-alkyl- or 1,3-­dialkylimidazolium halide, provided that the alkyl group has 1 to 12 carbon atoms, in a dry oxygen-free atmosphere, using a direct current or pulse current, and under electrolysis conditions of a bath temperature of from 0 to 300°C and a current density of from 0.01 to 50 A/dm².
Claim 7
Dependent Claim 95 words
A plating process for electrodeposition of aluminum, comprising carrying out plating by use of a plating bath for electrodeposition of aluminum, comprising a molten mixture comprising from 20 to 80 mol % of an aluminum halide, and from 20 to 80 mol % of a 1-alkyl- or 1,3-­dialkylimidazolium halide, provided that the alkyl group has 1 to 12 carbon atoms, in a dry oxygen-free atmosphere, using a direct current or pulse current, and under electrolysis conditions of a bath temperature of from 0 to 300°C and a current density of from 0.01 to 50 A/dm².
Claim 8
Dependent Claim 24 words
The plating process for electrodeposition of aluminum according to Claim 5, wherein the plating is carried out by using an anode made of aluminum.

References Cited (Backward Citations)

US4071415A Cited

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