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EP0338823A1 Expired / Lapsed EP ⏱️ 0.0 years remaining

Solid electrolyte type fuel cells

Assignee: Tonen General Sekiyu KK
•
Filing: 1989-04-20
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Granted: —
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Expires: 2009-04-20
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Abstract

Abstract A plate (11) 0.05 - 0.3 mm thick is made of a solid electrolyte, e.g. zirconia containing 2-5 wt % of yttria, and is coated on one side with a cathode layer (12) of material resistant to 0₂, e.g. made from powdered LaSr .MnO₃ and on the other side with an anode layer (13) of material resistant to H₂, each layer being porous to gases and electrically conductive; an assembly of plates (11) is made up with alternating interconnectors (14) having grooves (14a, 14b) on each side to define gas passages; the interconnectors and plates are made of conductive heat-­resistant material, preferably of an alloy containing Co, Cr, Ni, Fe or Mn coated with a composite oxide of La and an alkaline earth metal, or of a noble metal. The ends of the assembly are formed by terminals (15, 16) groov­ed only on their inner faces. The parts can be sealed together with glass paste, and gas supply lines (23-26, Fig 5) are provided externally. When the cell is heated at 1000 o C and H₂ and O₂ are supplied to the anodes and cathodes, a current is generated between the terminals (15, 16). The cells are simple of low internal resistance and efficient in operation.

Inventors

  • 👤 Toshihiko C/O Toa Nenryo Kogyo K.K. Yoshida
  • 👤 Tsukasa C/O Toa Nenryo Kogyo K.K. Shima
  • 👤 Fumiya C/O Toa Nenryo Kogyo K.K. Ishizaki
  • 👤 Hiroyuki C/O Toa Nenryo Kogyo K.K. Iwasaki
  • 👤 Isao C/O Toa Nenryo Kogyo K.K. Mukaizawa
  • 👤 Yoshiyuki C/O Toa Nenryo Kogyo K.K. Someya
  • 👤 Satoshi C/O Toa Nenryo Kogyo K.K. Sakurada
  • 👤 Osamu C/O Toa Nenryo Kogyo K.K. Yamamoto

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-08 10:53
CPC Classifications
H; H01; H01M; H01M8/00; H01M8/02; H01M8/0202; H01M8/0204; H01M8/0206; H01M8/0208; H01M8/0215; H01M8/0217; H01M8/0219; H01M8/0223; H01M8/0228; H01M8/10; H01M8/12; H01M8/124; H01M8/1246; H01M8/1253; H01M8/24; H01M8/241; H01M8/242; H01M8/2425; H01M8/2432; H01M8/2465; H01M8/2484; H01M2008/1293; H01M2300/00; H01M2300/0017; H01M2300/0065; H01M2300/0068; H01M2300/0071; H01M2300/0074; Y; Y02; Y02E; Y02E60/00; Y02E60/30; Y02E60/50; Y02P; Y02P70/00; Y02P70/50

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 132 words
A solid electrolyte type of fuel cell which comprises a cathode (12) and anode (13) formed on each side of a solid electrolyte plate (11), to which fuel gas can be fed, a plurality of the cells being connected in series, whereby an electrical current can be generated between the ends (15, 16) of the assembly of cells, charac­terised in that the cathodes (12) and anodes (13) are porous layers, and that each adjacent pair of plates (11) is laminated together by an interconnector plate (14) which is electrically conductive and electrically connects the adjacent electrodes, the interconnectors (14) having grooves (14a, 14b) formed on each side so as to define passages for fuel gas and oxidizing agent, the interconn­ectors being made of heat-resistant material and preferably also the cathodes and anodes.
Claim 2
Dependent Claim 132 words
A solid electrolyte type of fuel cell which comprises a cathode (12) and anode (13) formed on each side of a solid electrolyte plate (11), to which fuel gas can be fed, a plurality of the cells being connected in series, whereby an electrical current can be generated between the ends (15, 16) of the assembly of cells, charac­terised in that the cathodes (12) and anodes (13) are porous layers, and that each adjacent pair of plates (11) is laminated together by an interconnector plate (14) which is electrically conductive and electrically connects the adjacent electrodes, the interconnectors (14) having grooves (14a, 14b) formed on each side so as to define passages for fuel gas and oxidizing agent, the interconn­ectors being made of heat-resistant material and preferably also the cathodes and anodes.
Claim 3
Dependent Claim 35 words
A fuel cell as claimed in Claim 1, wherein each of said solid electrolyte plates (11) was formed by sinter­ing Y₂O₃-containing partially stabilized zirconia to which 5 to 20 % of alumina has been added.
Claim 4
Dependent Claim 70 words
A fuel cell as claimed in Claim 1 or 2, wherein said heat-resistant part was formed by coating on the surface of a heat-resistant alloy substrate containing chromium, cobalt, nickel, iron or manganese (i) lanthanum and an alkaline earth metal, (ii) lanthanum oxide and an alkaline earth metal, (iii) lanthanum and an oxide of an alkaline earth metal, or (iv) lanthanum oxide and an oxide of an alkaline earth metal.
Claim 5
Dependent Claim 57 words
A fuel cell as claimed in Claim 1, wherein said heat-resistant part was formed by coating on the surface of a heat-resistant alloy substrate a composite metal oxide of a formula: La 1-x M¹ x M²O₃ wherein M¹ is an alkaline earth metal, M² is Co, Fe, Mn, Ni or Cr, and 0 ≦ x < 1.
Claim 6
Dependent Claim 25 words
A fuel cell as claimed in Claim 4 wherein said heat-resistant part is formed of La 1-x M¹ x M²O₃ of a perov­skite-type crystal structure.
Claim 7
Dependent Claim 30 words
A fuel cell as claimed in Claim 4 or 5 wherein said heat-resistant part has a molar ratio of lanthanum and the alkaline earth metals of from 1:0.05 to 1:0.7.
Claim 8
Dependent Claim 30 words
A fuel cell as claimed in any preceding claim, wherein the substrate of said heat-resistant part is formed of a heat-resistant alloy based on cobalt, nickel, titanium or metallic chromium.
Claim 9
Dependent Claim 23 words
A fuel cell as claimed in Claim 1, wherein said heat-resistant part has a surface film 0.1 µm to 10 µm in thickness.
Claim 10
Dependent Claim 34 words
A fuel cell as claimed in any preceding claim, wherein said heat-resistant interconnector (14) connects the cathode of one unit cell of a high-temperature fuel cell to the anode of the adjacent unit cell.
Claim 11
Dependent Claim 22 words
A fuel cell as claimed in any preceding claim, wherein said heat-resistant part is a cathodic collector of a high-temperature fuel cell.

References Cited (Backward Citations)

US3300344A Cited
US3394032A Cited
FR1534093A Cited
FR2306540A1 Cited
FR2347783A1 Cited
GB2002739A Cited
DE2810134A1 Cited
US4476196A Cited
WO1986006762A1 Cited

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