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EP0330246A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Curable dispersion

Assignee: DSM BV
•
Filing: 1989-01-06
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Granted: —
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Expires: 2009-01-06
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Abstract

Abstract The invention relates to a curable dispersion on the basis of a water-dispersed polymer of one or more ethylenically unsaturated monomers with an average molecular weight between 2 x 10⁵ and 2 x 10⁶ dalton, emulsion stabilizers and/or emulsifiers. The dispersion can be prepared by polymerizing, in a first step, a phosphate or phosphonate compound or mixtures thereof that contain at least an organic residue with a (meth)acrylate derivative or an other unsaturated compound or a styrene derivative, and after this polymerization adding an ethyleni­cally unsaturated and epoxy-containing monomer.

Inventors

  • 👤 Dick Adriaan Pons
  • 👤 Johannes Barend Van Hout

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-08 15:47
CPC Classifications
C; C08; C08F; C08F8/00; C08F8/14; C08F2810/00; C08F2810/30

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 168 words
Curable dispersion based on a water-dispersed polymer of one or more ethylenically unsaturated monomers with an average molecular weight between 2 x 10⁵ and 2 x 10⁶ dalton, emulsion stabilizers and/or emulsifiers, characterized in that it contains polymer groups according to formula I where m = 1 or 2 p = 0 or 1 n = 2 - m R¹ = organic group with 2-15 C atoms containing at least a group according to formula II where Ø-C-C-ع represents a polymer chain and R⁷, R⁸ and R⁹ independently represent H or an organic group with 1-4 C atoms, and R¹⁰ is an organic group with 1-10 C atoms or a chemical bond R² = H, an organic group with 1-10 C atoms or R¹ R⁶ = an organic group according to formula III the group being bound via R¹¹, and R⁷, R⁸ and R⁹ having the above-mentioned meaning, and R¹¹ representing C₂-C₁₂-alkyl and R³, R⁴ and R⁵ are the same or different and represent H, (C₁-C₄)alkyl or (C₆-C₁₀)aryl.
Claim 2
Dependent Claim 168 words
Curable dispersion based on a water-dispersed polymer of one or more ethylenically unsaturated monomers with an average molecular weight between 2 x 10⁵ and 2 x 10⁶ dalton, emulsion stabilizers and/or emulsifiers, characterized in that it contains polymer groups according to formula I where m = 1 or 2 p = 0 or 1 n = 2 - m R¹ = organic group with 2-15 C atoms containing at least a group according to formula II where Ø-C-C-ع represents a polymer chain and R⁷, R⁸ and R⁹ independently represent H or an organic group with 1-4 C atoms, and R¹⁰ is an organic group with 1-10 C atoms or a chemical bond R² = H, an organic group with 1-10 C atoms or R¹ R⁶ = an organic group according to formula III the group being bound via R¹¹, and R⁷, R⁸ and R⁹ having the above-mentioned meaning, and R¹¹ representing C₂-C₁₂-alkyl and R³, R⁴ and R⁵ are the same or different and represent H, (C₁-C₄)alkyl or (C₆-C₁₀)aryl.
Claim 3
Dependent Claim 17 words
Ultraviolet light curable coating composition based on a disper­sion according to claim 1 and a photoinitiator system.
Claim 4
Dependent Claim 33 words
Composition according to claim 1 or 2, characterized in that the dispersion also contains a prepolymer, which at least contains two ethylenic unsaturations and has a molecular weight between 300 and 6000 dalton.
Claim 5
Dependent Claim 19 words
Composition according to claim 2, characterized in that the dispersion also contains a prepolymer with 3 terminal acrylate groups.
Claim 6
Dependent Claim 73 words
Process for the preparation of a dispersion involving polymeriza­tion of ethylenically unsaturated monomers in a radical polymeri­zation step, characterized in that in a first step 0.5-25.0 wt.% relative to the monomers of a phosphate or phosphonate compound or mixtures thereof that contain at least an organic residue with a (meth)acryl derivative or another unsaturated compound or a styrene derivative are polymerized and after this polymerization an ethylenically unsaturated and epoxy-containing monomer is added.
Claim 7
Dependent Claim 73 words
Process for the preparation of a dispersion involving polymeriza­tion of ethylenically unsaturated monomers in a radical polymeri­zation step, characterized in that in a first step 0.5-25.0 wt.% relative to the monomers of a phosphate or phosphonate compound or mixtures thereof that contain at least an organic residue with a (meth)acryl derivative or another unsaturated compound or a styrene derivative are polymerized and after this polymerization an ethylenically unsaturated and epoxy-containing monomer is added.
Claim 8
Dependent Claim 40 words
Process for coating of textile by impregnating textile using a curable dispersion, characterized in that textile is impregnated using a dispersion according to any one of claims 1-4, water is evaporated, and the impregnated textile is irradiated using UV light.
Claim 9
Dependent Claim 37 words
Polymer based on one or more ethylenically unsaturated monomers with an average molecular weight between 2 x 10⁵ and 2 x 10⁶ dalton, characterized in that the polymer contains groups according to formula I as indicated above.
Claim 10
Dependent Claim 37 words
Polymer based on one or more ethylenically unsaturated monomers with an average molecular weight between 2 x 10⁵ and 2 x 10⁶ dalton, characterized in that the polymer contains groups according to formula I as indicated above.

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