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EP0330109A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

A silver halide photographic light-sensitive material capable of providing a high contrast image

Assignee: Konica Minolta Inc
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Filing: 1989-02-18
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Granted: —
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Expires: 2009-02-18
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Abstract

Abstract A silver halide photographic light-sensitive material having a support and provided thereon, at least one silver halide emulsion layer containing Compound [I] or Compound [II] represented by Formula [I] or [II] is disclosed; <CHEM> g

Inventors

  • 👤 Yasushi Usagawa
  • 👤 Fumi Ishii

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-31 20:32
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/06; G03C1/061

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 277 words
A silver halide photographic light-sensitive material having a support and provided thereon, hydrophilic colloid layers including an intermediate layer and at least one silver halide emulsion layer containing silver halide particles and additives, wherein said silver halide photographic light-sensitive material comprises at least one of Compound [I] and Compound [II] represented by Formulas [I] and [II], respectively; wherein A represents one selected from a group consisting of an aryl group and a heterocyclic group containing at least one of a sulfur atom and an oxygen atom; n represents an integer of 1 and 2; provided that n represents 1, R₁ and R₂ represent independently a hydrogen atom, an alkyl group, an alkenyl group, an alkinyl group, an aryl group, a heterocyclic group, a hydroxy group, an alkoxy group, an alkenyloxy group, an alkinyloxy group, an aryloxy group, and a heterocyclicoxy group, and R₁ and R₂ may form a ring with a nitrogen atom; provided that n represents 2, R₁ and R₂ represent independently a hydrogen atom, an alkyl group, an alkenyl group, an alkinyl group, an aryl group, a saturated and unsaturated heterocyclic group, a hydroxy group, an alkoxy group, an alkenyloxy group, an alkinyloxy group, an aryloxy group, and a heterocyclicoxy group, provided that at least one of R₁ and R₂ represents an alkenyl group, an alkinyl group, a saturated heterocyclic group, a hydroxy group, an alkoxy group, an alkenyloxy group, an alkinyloxy group, an aryloxy group, and a heterocyclicoxy group; R₃ represents one selected from a group consisting of an alkinyl grop and a saturated heterocyclic group; R₄ and R₅ represent independently a hydrogen atom, a sulfonyl group, an acyl group and an oxalyl group.
Claim 2
Dependent Claim 277 words
A silver halide photographic light-sensitive material having a support and provided thereon, hydrophilic colloid layers including an intermediate layer and at least one silver halide emulsion layer containing silver halide particles and additives, wherein said silver halide photographic light-sensitive material comprises at least one of Compound [I] and Compound [II] represented by Formulas [I] and [II], respectively; wherein A represents one selected from a group consisting of an aryl group and a heterocyclic group containing at least one of a sulfur atom and an oxygen atom; n represents an integer of 1 and 2; provided that n represents 1, R₁ and R₂ represent independently a hydrogen atom, an alkyl group, an alkenyl group, an alkinyl group, an aryl group, a heterocyclic group, a hydroxy group, an alkoxy group, an alkenyloxy group, an alkinyloxy group, an aryloxy group, and a heterocyclicoxy group, and R₁ and R₂ may form a ring with a nitrogen atom; provided that n represents 2, R₁ and R₂ represent independently a hydrogen atom, an alkyl group, an alkenyl group, an alkinyl group, an aryl group, a saturated and unsaturated heterocyclic group, a hydroxy group, an alkoxy group, an alkenyloxy group, an alkinyloxy group, an aryloxy group, and a heterocyclicoxy group, provided that at least one of R₁ and R₂ represents an alkenyl group, an alkinyl group, a saturated heterocyclic group, a hydroxy group, an alkoxy group, an alkenyloxy group, an alkinyloxy group, an aryloxy group, and a heterocyclicoxy group; R₃ represents one selected from a group consisting of an alkinyl grop and a saturated heterocyclic group; R₄ and R₅ represent independently a hydrogen atom, a sulfonyl group, an acyl group and an oxalyl group.
Claim 3
Dependent Claim 22 words
The photographic material of claim 1, wherein A comprises at lest one of a non-diffusible group and a silver halide adsorptive group.
Claim 4
Dependent Claim 21 words
The photographic material of claim 2, wherein said non-­diffusible group is a ballast group having not less than eight carbon atoms.
Claim 5
Dependent Claim 30 words
The photographic material of claim 3, wherein said ballast group is an alkyl group, an alkoxy group, a phenyl group, an alkylphenyl group, a phenoxy group or an alkylphenoxy group.
Claim 6
Dependent Claim 34 words
The photographic material of claim 2, 3 or 4, wherein said silver halide adsorptive group is a thiourea group, a thiourethane group, a thioamide heterocyclic group, a mercapto heterocyclic group, or a triazole group.
Claim 7
Dependent Claim 28 words
The photographic material of claims 1 or 2 to 5, wherein at least one of said Compound [I] and Compound [II] is incorporated into said hydrophilic colloid layers.
Claim 8
Dependent Claim 46 words
The photographic material of claim 6, wherein at least one of said Compound [I] and [II] is incorporated into at least one of the silver halide emulsion layer and the hydrophilic colloid layer adjacent directly or via the intermediate layer to said silver halide emulsion layer.
Claim 9
Dependent Claim 37 words
The photographic material of claim 7, wherein at least one of the silver halide emulsion layer and the hydrophilic colloid layer adjacent to said silver halide emulsion layer comprises said Compound [I], provided that n represents 2.
Claim 10
Dependent Claim 57 words
The photographic material of claim 8, wherein R₁ represents a hydrogen atom, an alkyl group, an alkenyl group, an alkinyl group, an aryl group, a saturated or unsaturated heterocyclic group, a hydroxy group, or an alkoxy group; and R₂ represents an alkenyl group, an alkinyl group, a saturated heterocyclic group, a hydroxy group, or an alkoxy group.
Claim 11
Dependent Claim 33 words
The material of claim 7, 8 or 9, wherein an addition amount of said Compound [I] or [II] is 5 × 10⁻⁷ mol to 5 × 10⁻¹ mol per mol of silver halide.
Claim 12
Dependent Claim 24 words
The material of claim 10, wherein the addition amount is 5 × 10⁻⁵ mol to 1 × 10⁻² mol per mol of silver halide.
Claim 13
Dependent Claim 24 words
The material of claims 1 or 2 to 11, wherein an average particle size of the silver halide particles is 0.05 to 0.5 µm.
Claim 14
Dependent Claim 40 words
The material of claim 12, wherein a monodispersion degree defined by Equation [I] is 5 to 20; wherein r represents an average halide particles; ri represents a particle size of the respective particles; and ni represents number of the particles.
Claim 15
Dependent Claim 27 words
The material of claims 1 or 2 to 13, wherein at least one of the additives contained in the silver halide emulsion layer is a rhodium salt.
Claim 16
Dependent Claim 17 words
The material of claim 14, wherein said rhodium salt is used in combination with an iridium salt.
Claim 17
Dependent Claim 32 words
The material of claim 15, wherein an addition amount of the rhodium salt and the iridium salt is each 1 × 10⁻⁸ mol to 1 × 10⁻⁴ mol per mol of silver.

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