EP0324391A2
Expired / Lapsed
EP
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Method for the formation of high-contrast images
Assignee: Konica Minolta Inc
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Filing: 1989-01-07
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Granted: —
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Expires: 2009-01-07
Abstract
Abstract @ A processing method for silver halide photogrphic material is disclosed, which stably provides images having high contrast and high dot quality with little degradation in sensitivity by rapid processing. In the method, a silver halide light-sensitive material having a silver halide emulsion layer containing a 3-pyrazolidone type compound, a dihydroxybenzene type compound or trihydroxybenzene type compound, is developed by a developer containing a di- or tri-hydroxybenzene type compound; a sulfite and an amino compound in the presence of a compound represented by the following Formula 1, 2 and 3;
Inventors
- 👤 Yasuhiko Takamuki
- 👤 Takeshi Habu
- 👤 Junichi Fukawa
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-11-03 08:35
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/06; G03C1/061; G03C1/42; G03C5/00; G03C5/26; G03C5/29; G03C5/305
Claims Analysis
Total Claims: 31
Claim 1
Independent Claim
238 words
A method for forming an image comprising a step of development of a silver halide photographic light-sensitive material having a silver halide emulsion layer with a developer, wherein said silver halide emulsion layer contains a compound selected from the group consisting of 3-pyrazolidone type compounds, dihydroxybenzene type compounds or trihydroxybenzene type compounds; said developer contains a compound selected from the group consisting of dihydroxybenzene type compounds and trihydroxybenzene type compounds; a sulfite and an amino compound; and said development is performed in the presence of a compound selected from the group consisting of compounds represented by the following Formula 1, 2 and 3; wherein R 1 and R 2 each represents an aryl group or a heterocyclic group, R is a divalent organic group, n is an integer of zero to 6 and m is an integer of zero or 1, provided that when n is 2 to 6 the Rs are the same as or different from each other, wherein, R 21 is an aliphatic group, an aromatic group or a heterocyclic group; R 22 is a hydrogen atom, an alkoxy group, a heterocyclic oxy group, an amino group, or an aryloxy group; P 1 and P 2 each represents a hydroqen atom, an acyl qroup or a sulfinic acid group, wherein Ar is an aryl group containing a non-diffusible group or a silver halide adsorption accelerating group; and R 3 , is a substituted alkyl group.
Claim 2
Independent Claim
238 words
A method for forming an image comprising a step of development of a silver halide photographic light-sensitive material having a silver halide emulsion layer with a developer, wherein said silver halide emulsion layer contains a compound selected from the group consisting of 3-pyrazolidone type compounds, dihydroxybenzene type compounds or trihydroxybenzene type compounds; said developer contains a compound selected from the group consisting of dihydroxybenzene type compounds and trihydroxybenzene type compounds; a sulfite and an amino compound; and said development is performed in the presence of a compound selected from the group consisting of compounds represented by the following Formula 1, 2 and 3; wherein R 1 and R 2 each represents an aryl group or a heterocyclic group, R is a divalent organic group, n is an integer of zero to 6 and m is an integer of zero or 1, provided that when n is 2 to 6 the Rs are the same as or different from each other, wherein, R 21 is an aliphatic group, an aromatic group or a heterocyclic group; R 22 is a hydrogen atom, an alkoxy group, a heterocyclic oxy group, an amino group, or an aryloxy group; P 1 and P 2 each represents a hydroqen atom, an acyl qroup or a sulfinic acid group, wherein Ar is an aryl group containing a non-diffusible group or a silver halide adsorption accelerating group; and R 3 , is a substituted alkyl group.
Claim 3
Dependent Claim
132 words
The method of claim 1, wherein said compounds represented by Formula 2 are compounds represented by the following Formula 2-a; wherein R 23 and R 24 each is a hydrogen atom, an alkyl group, a phenyl group, a naphtyl group, a cyclohexyl group, a pyridyl group or a pyrrolidyl group; R 25 is a benzyl group, an alkoxy group or an alkyl group; R 26 and R 27 each is a divalent aromatic group; Y is a sulfur atom or an oxygen atom; L is a divalent linkage atom or group; R 28 is an -NR R group or an -OR 28 group, R, R and R 29 each is an alkyl group, a phenyl group or a naphthyl group; and m and n each is an integer of zero or 1.
Claim 4
Independent Claim
38 words
The method of calim 1, wherein said non-diffusible group of Formula 3 is an alkyl group, an alkoxy group, a phenyl group, an alkylphenyl group, a phenoxy group or alkylphenoxy group, which have 8 or more carbon atoms.
Claim 5
Independent Claim
38 words
The method of calim 1, wherein said non-diffusible group of Formula 3 is an alkyl group, an alkoxy group, a phenyl group, an alkylphenyl group, a phenoxy group or alkylphenoxy group, which have 8 or more carbon atoms.
Claim 6
Dependent Claim
30 words
The method of claim 1, wherein said silver halide adsorption accelerating group is a thioureido group, thiouretano group, a heterocyclic thioamido group, a mercapto heterocyclic group or a triazolyl group.
Claim 7
Dependent Claim
28 words
The method of claim 1 or claims 2 to 4, wherein said compound represented by Formula 1, 2 or 3 is contained in said silver halide photographic material.
Claim 8
Dependent Claim
48 words
The method of claim 5, wherein said compound represented by Formula 1, 2 or 3 is contained in said photographic material in an amount of from 1 x 10- 8 to 1 x 10 -1 mole per mole of silver halide contained in said silver halide emulsion layer.
Claim 9
Independent Claim
47 words
The method of calim 6, wherein said compound represented by Formula 1, 2 or 3 is contained in said photographic material in an amount of from 1 x 10- 4 to 1 ×10 -2 mole per mole of silver halide contained in said silver halide emulsion layer.
Claim 10
Independent Claim
47 words
The method of calim 6, wherein said compound represented by Formula 1, 2 or 3 is contained in said photographic material in an amount of from 1 x 10- 4 to 1 ×10 -2 mole per mole of silver halide contained in said silver halide emulsion layer.
Claim 11
Dependent Claim
25 words
The method of claim 1 or claims 2 to 4, wherein said compound represented by Formula 1, 2 or 3 is contained in said developer.
Claim 12
Dependent Claim
37 words
The method of claim 8, wherein said compound represented by formula 1, 2 or 3 is contained in said developer in an amount of from 1×10 -5 to 1 ×10 -2 mole per liter of the developer.
Claim 13
Dependent Claim
38 words
The method of claim 9, wherein said compound represented by formula 1, 2 or 3 is contained in said developer in an amount of from 1 x 10- 3 to 1×10 -4 mole per liter of the developer.
Claim 14
Dependent Claim
45 words
The method of claim 1 or claims 2 to 10, wherein said 3-pyrazolidones compound are represented by the following formula; wherein R' is an unsubstituted or substituted aryl group; R 2 , R 3 and R 4 each is an unsubstituted or substituted alkyl group.
Claim 15
Dependent Claim
83 words
The method of claim 1 or claims 2 to 10, wherein said dihydroxybenzene comounds and trihydroxybenzene compounds are represented by the following formula; wherein R 11 , R 12 and R 13 , each is a hydrogen atom, a halogen atom, an alkyl group, an aryl group, a heterocyclic group, an -OR 14 group or an -SR' 4 group; R 14 is a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group; n is an integer of zero or 1.
Claim 16
Dependent Claim
40 words
The method of claim 1 or claims 2 to 10 or 12, wherein said dihydroxybenzene compound or trihydroxybenzene compound is contained in said silver halide emulsion layer in,an amount of from 0.001 to 0.10 mole per mole of silver halide.
Claim 17
Dependent Claim
36 words
14, The method of claim 13, wherein said dihydroxybenzene compound or trihydroxybenzene compound is contained in said said silver halide emulsion layer in an amount of from 0.005 to 0.03 mole per mole of silver halide.
Claim 18
Dependent Claim
37 words
The method of claim 1 or claims 2 to10 or 12, wherein said dihydroxybenzene or trihydrox- ybenezene compound is contained in said developer in an amount of from 0.05 to 0.5 mole per litler of the developer.
Claim 19
Dependent Claim
36 words
16 The method of claim 1 or claims 2 to 15, wherein said sulfite is sodium sulfite, potssium sulfite, lithium sulfite, ammonium sulfite, sodium bisulfite, potassium metabisulfite or an additional compound of formaldehyde with sodium bisulfite.
Claim 20
Dependent Claim
32 words
The method of claim 1 or claims 2 to 16, wherein said sulfite is contained in said developer in an amount of not less than 0.05 mole per liter of the developer.
Claim 21
Dependent Claim
27 words
The method of claim 17, wherein said sulfite is contained in said developer in an amount of not less than 0.15 mole per liter of the developer.
Claim 22
Dependent Claim
106 words
The method of claim 1 or claims 2 tol8, wherein said amine is an alkanol amine represented by the following formula; wherein R 21 is a hydroxyalkyl group having 2 to 10 carbon atoms; R 22 and R 23 each is a hydrogen atom. an alkyl group havin 1 to 10 carbon atoms, a hydroxy alkyl having 2 to 10 carbon atoms; a benzyl group or a group, in which n is an integer of 1 to 10, X and Y each is a hydrogen atom, an alkyl group having 1 to 10 carbon atoms or a hydroxy alkyl group having 2 to 10 carbon atoms.
Claim 23
Dependent Claim
49 words
The method of claim 1 or claims 2 to 18, wherein said amine is an alkyl amine represented by the following formula; wherein R 24 is an alkyl group having 1 to 10 carbon atoms; R 25 and R 26 each is a hydrogen atom or an alkyl group.
Claim 24
Dependent Claim
32 words
The method of claim 1 or claims 2 to 20, wherein said amine is contained in said developer in an amount of from 0.01 to 1.0 mole per liter of the developer.
Claim 25
Dependent Claim
27 words
The method of claim 21, wherein said amine is contained in said developer in an amount of from 0.01 to 0.04 mole per liter of the developer.
Claim 26
Dependent Claim
33 words
The method of claim 1 or claims 2 to 22, wherein said silver halide emulsion comprised of said silver halide emulsion layer has a silver bromide content of not less than 50 mole%.
Claim 27
Dependent Claim
21 words
The method of claim 23, wherein said silver halide emulsion has a silver iodide content of not more than 5 mole%.
Claim 28
Dependent Claim
67 words
The method of claim 1 or claims 2 to 24, wherein said silver halide photo graphic material coantains a compound represented by the following Formula 4; Formula 4 wherein A is a phosphorous atom or a nitrogen atom; R 41 , R 42 , R 43 and R 44 each is an alkyl group, an aryl group or an aralkyl group; and X- is an acid anion.
Claim 29
Independent Claim
73 words
The method of claims 1,2 to 24 or 25, wherein said silver halide photographic material coantains a compound represented by the following Formula 5; wherein Y and Z each is a nitrogen atom or a carbon atom, provided that when either one of Z and Y is a nitrogen atom, the other is a carbon atom; R 51 is a hydrogen atom, a lower alkyl group, a halogen atom or a nitro group.
Claim 30
Independent Claim
56 words
The method of claims 1, 2 to 24, 25 or 26, wherein said silver halide photographic material coantains a compound represented by the following Formula 6; wherein R 61 , R 62 and R 63 each is a hydrogen atom, a hydroxy group, an amino group, a mercapto group, an alkyl group or an aryl group.
Claim 31
Independent Claim
222 words
The method of claims 1, 2 to 24, 25, 26 or 27, wherein said silver halide photographic material coantains a compound represented by the following Formula 7; Formula 7 Y-[S-L 1 -(J 1 )k-(L 2 )l-(Z) m-(L 3 ) n-(J 2 L 4 ) p(G)q]r wherein L 1 through L4 each is a divalent hydrocarbon group, J 1 and J 2 each is an -O- atom, a -COO- group, a -CONR 71 - group, an -S0 2 NR 71 group, an -NR 71 -CO-NR 72 - group, an -S0 2 - group, an -N=N- group, an -NR 71 - group or -CO- group; Y is a hydrogen atom, a divalent group or a linkage, or an amidino group; Z is a heterocyclic group; G is a sulfonic acid group, a carboxyl group or a phosphoric acid group; R 71 and R 72 , each is a hydrogen atom, an alkyl group or an aryl group; k, I, m, and n each is an integer of 0 to 2; p is an integer of 0 to 4; g is an integer of 1 to 4 and r is an integer of 1 to 2; provided that when G is a carboxyl group, m is an integer of 1 to 2, and when Y is a divalent group or a linkage, r is 2.
References Cited (Backward Citations)
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