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EP0314100A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Alpha-type titanyl phthalocyanine composition, method for production thereof, and electrophotographic sensitive material using same

Assignee: Kyocera Mita Industrial Co Ltd
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Filing: 1988-10-26
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Granted: —
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Expires: 2008-10-26
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Abstract

Abstract The first aspect of this invention resides in providing an α-type titanyl phthalocyanine composition comprising an α-type titanyl phthalocyanine and metal-­free phthalocyanine. This α-type titanyl phthalocyanine composition is stable, wide in range of absorption wavelengths, and high in spectral sensitivity because it contains an α-type titanyl phthalocyanine in combination with metal-free phthalocyanine. The second aspect of this invention resides in providing a method for the production of an α-type titanyl phthalocyanine composition comprising an α-type titanyl phthalocyanine and a metal-free phthalocyanine, which method comprises pigmenting a concentrated sulfuric acid solution containing at least titanyl phthalocyanine by the acid paste process consisting in pouring said concentrated sulfuric acid solution into water. By this method, an α-type titanyl phthalocyanine composition stable to withstand the impact of aging can be easily produced. The third aspect of this invention resides in providing an electrophotographic sensitive material having superposed on an electroconductive substrate a sensitive layer comprising an α-type titanyl phthalo­cyanine and a metal-free phthalocyanine. This electro­ photographic sensitive material excels in charging property and dark attenuation property and exhibits high sensitivity and sparing residual potential. The fourth aspect of this invention resides in providing an electrophotographic sensitive material having superposed on an electroconductive substrate a sensitive layer comprising an α-type titanyl phthalocyanine composition and an electric charge transferring material exhibiting oxidation potential in the range of 0.45 to 0.65 eV. This electrophotographic sensitive material enjoys high sensitivity and shows sparing residual potential.

Inventors

  • 👤 Eiichi Miyamoto
  • 👤 Nariaki Mutou
  • 👤 Tooru Nakazawa
  • 👤 Tatsuo Maeda

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-07 12:50
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/06; G03G5/0664; G03G5/0696; C; C09; C09B; C09B47/00; C09B47/04; C09B47/045; C09B67/00; C09B67/0001; C09B67/0017; C09B67/0019; C09B67/0025; C09B67/0026; C09B67/0033; C09B67/0034; C09B67/0035; C09B67/0096

Claims Analysis

Total Claims: 23
Claim 1
Independent Claim 16 words
An α-type titanyl phthalocyanine composition, characterized by comprising an α-type titanyl phthalocyanine and a metal-free phthalocyanine.
Claim 2
Dependent Claim 16 words
An α-type titanyl phthalocyanine composition, characterized by comprising an α-type titanyl phthalocyanine and a metal-free phthalocyanine.
Claim 3
Dependent Claim 43 words
A α-type titanyl phthalocyanine composition according to Claim 1, wherein the content of said -type titanyl phthalocyanine is in the range of 60 to 90% by weight and the content of said metal-free phthalocyanine in the range of 10 to 40% by weight.
Claim 4
Dependent Claim 46 words
An α-type titanyl phthalocyanine composition according to Claim 1, wherein said α-type titanyl phthalocyanine shows strong diffraction peaks at Bragg angles 6.9°, 9.6°, 15.6°, 17.6°, 21.9°, 23.6°, 27.7°, and 28.0° and the strongest diffraction peak at Bragg angle 6.9° among others in an X-ray diffraction spectrum.
Claim 5
Dependent Claim 20 words
An α-type titanyl phthalocyanine composition according to Claim 1, which has undergone a surface treatment with a silane coupling agent.
Claim 6
Independent Claim 56 words
A method for the production of an α-type titanyl phthalocyanine composition, which comprises converting titanyl phthalocyanine into a pigment by the acid paste process consisting in pouring into cold water a concentrated sulfuric acid solution containing at least titanyl phthalocyanine thereby producing an α-type titanyl phthalocyanine composition comprising an α-type titanyl phthalocyanine and a metal-free phthalocyanine.
Claim 7
Independent Claim 56 words
A method for the production of an α-type titanyl phthalocyanine composition, which comprises converting titanyl phthalocyanine into a pigment by the acid paste process consisting in pouring into cold water a concentrated sulfuric acid solution containing at least titanyl phthalocyanine thereby producing an α-type titanyl phthalocyanine composition comprising an α-type titanyl phthalocyanine and a metal-free phthalocyanine.
Claim 8
Dependent Claim 28 words
A method according to Claim 5, wherein the temperature at which said concentrated sulfuric acid solution is poured into water is in the range of -5° to 40°C.
Claim 9
Dependent Claim 61 words
A method according to Claim 6, wherein said concentrated sulfuric acid solution is prepared by using a concentrated sulfuric acid of a concentration in the range of 92 to 105% in an amount not less than 15 times the amount of titanyl phthalocyanine and said concentrat­ed sulfuric acid solution is kept at a temperature in the range of 0 to 40°C.
Claim 10
Dependent Claim 29 words
A method according to Claim 5, wherein said pigmentation of said concentrated sulfuric acid solution is carried out by wet milling in the presence of a chlorine type solvent.
Claim 11
Dependent Claim 22 words
A method according to Claim 5, wherein said α-type titanyl phthalocyanine composition is given a surface treatment with a silane coupling agent.
Claim 12
Dependent Claim 18 words
A method according to Claim 9, wherein said silane coupling agent is an epoxy type silane coupling agent.
Claim 13
Dependent Claim 22 words
An electrophotographic sensitive material, having superposed on an electroconductive substrate a sensitive layer comprising an α-type titanyl phthalocyanine and a metal-free phthalocyanine.
Claim 14
Dependent Claim 22 words
An electrophotographic sensitive material, having superposed on an electroconductive substrate a sensitive layer comprising an α-type titanyl phthalocyanine and a metal-free phthalocyanine.
Claim 15
Dependent Claim 42 words
An electrophotographic sensitive material according to Claim 11, wherein the content of said α-type titanyl phthalocyanine is in the range of 60 to 90% by weight and the content of said metal-free phthalocyanine in the range of 10 to 40% by weight.
Claim 16
Dependent Claim 38 words
An electrophotographic sensitive material according to Claim 11, wherein said sensitive layer comprises an electric charge generating layer and an electric charge transfer layer and said electric charge generating layer contains said α-type titanyl phthalocyanine and metal-free phthalocyanine.
Claim 17
Dependent Claim 19 words
An electrophotographic sensitive material according to Claim 11, which has undergone a surface treatment with a silane coupling agent.
Claim 18
Dependent Claim 37 words
An electrophotographic sensitive material, having superposed on an electroconductive substrate a sensitive layer comprising an α-type titanyl phthalocyanine composition and an electric charge transferring material possessing an oxidation potential in the range of 0.45 to 0.65 eV.
Claim 19
Dependent Claim 37 words
An electrophotographic sensitive material, having superposed on an electroconductive substrate a sensitive layer comprising an α-type titanyl phthalocyanine composition and an electric charge transferring material possessing an oxidation potential in the range of 0.45 to 0.65 eV.
Claim 20
Dependent Claim 50 words
An electrophotographic sensitive material according to Claim 15, wherein said sensitive layer compresses an electric charge generating layer and an electric charge transfer layer, said electric generating layer contains said α-type titanyl phthalocyanine composition, and said electric charge transfer layer contains an electric charge transferring material possessing said oxidation potential.
Claim 21
Dependent Claim 29 words
An electrophotographic sensitive material according to Claim 15, wherein said sensitive layer has said α-type titanyl phthalocyanine composition and said electric charge transferring material dispersed in a binding resin.
Claim 22
Dependent Claim 33 words
An electrophotographic sensitive material according to Claim 15, wherein said α-type titanyl phthalocyanine composition comprises 60 to 90% by weight of α-type titanyl phthalocyanine and 10 to 40% by weight of metal-free phthalocyanine.
Claim 23
Dependent Claim 46 words
An electrophotographic sensitive material according to Claim 15, wherein said α-type titanyl phthalocyanine composition shows strong diffraction peaks at Bragg angles 6.9°, 9.6°, 15.6°, 17.6°, 21.9°, 23.6°, 27.7°, and 28.0° and the strongest diffraction peak at Bragg angle 6.9° among others in an X-ray diffraction spectrum.

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