EP0313474A2
Expired / Lapsed
EP
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An optical article exhibiting a high level of second order polarization susceptibility
Assignee: Eastman Kodak Co
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Filing: 1988-09-12
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Granted: —
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Expires: 2008-09-12
Abstract
Abstract An optical article is disclosed containing, for the transmission of electromagnetic radiation, a medium exhibiting a second order polarization susceptibility greater than 10⁻⁹ electrostatic units comprised of polar aligned noncentrosymmetric molecular dipoles. The molecular dipoles have an electron donor moiety linked through a conjugated π bonding system to an electron acceptor sulfonyl moiety.
Inventors
- 👤 Abraham Eastman Kodak Company Ulman
- 👤 Douglas Robert Eastman Kodak Company Robello
- 👤 Jay Stuart Eastman Kodak Company Schildkraut
- 👤 Michael Eastman Kodak Company Scozzafava
- 👤 Thomas Lorne Eastman Kodak Company Penner
- 👤 Craig Stanley Eastman Kodak Company Willand
- 👤 David James Eastman Kodak Company Williams
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-10-30 13:30
CPC Classifications
B; B82; B82Y; B82Y20/00; G; G02; G02B; G02B1/00; G02B1/08; G02F; G02F1/00; G02F1/01; G02F1/061; G02F1/065; G02F1/35; G02F1/355; G02F1/361; G02F1/3613; G02F1/3615; G02F1/3617; G02F1/3618; Y; Y10; Y10S; Y10S430/00; Y10S430/001; Y10S430/10; Y10S430/1053; Y10S430/1055; Y10S430/114; Y10S430/122
Claims Analysis
Total Claims: 32
Claim 1
Independent Claim
77 words
An optical article containing, for the transmission of electromagnetic radiation, a medium exhibiting a second order polarization susceptibility greater than 10⁻⁹ electrostatic units comprised of polar aligned noncentrosymmetric molecular dipoles having an electron donor moiety linked through a conjugated π bonding system to an electron acceptor moiety to permit oscillation of the molecular dipole between a lower polarity ground state and a higher polarity excited state, characterized in that the electron acceptor moiety is a sulfonyl moiety.
Claim 2
Dependent Claim
77 words
An optical article containing, for the transmission of electromagnetic radiation, a medium exhibiting a second order polarization susceptibility greater than 10⁻⁹ electrostatic units comprised of polar aligned noncentrosymmetric molecular dipoles having an electron donor moiety linked through a conjugated π bonding system to an electron acceptor moiety to permit oscillation of the molecular dipole between a lower polarity ground state and a higher polarity excited state, characterized in that the electron acceptor moiety is a sulfonyl moiety.
Claim 3
Dependent Claim
22 words
An optical article according to claim 1 further characterized in that means are provided for directing electromagnetic radiation to said transmission medium.
Claim 4
Dependent Claim
26 words
An optical article according to claim 1 or 2 further characterized in that biasing means are provided for placing an electric field across said transmission medium.
Claim 5
Dependent Claim
26 words
An optical article according to claim 3 further characterized in that said biasing means includes at least one transparent electrode in contact with said transmission medium.
Claim 6
Dependent Claim
26 words
An optical article according to claim 1 or 2 further characterized in that said transmission medium lies in contact with a linear waveguide for electromagnetic radiation.
Claim 7
Dependent Claim
26 words
An optical article according to any one of claims 1 to 6 inclusive further characterized in that said transmission medium is comprised of a Langmuir-Blodgett film.
Claim 8
Dependent Claim
22 words
An optical article according to claim 1 further characterized in that said Langmuir-Blodgett film is comprised of a Z-type Langmuir-Blodgett film assembly.
Claim 9
Dependent Claim
24 words
An optical article according to any one of claims 1 to 7 inclusive further characterized in that said sulfonyl moiety includes a hydrophilic substituent.
Claim 10
Dependent Claim
24 words
An optical article according to any one of claims 1 to 7 inclusive further characterized in that said sulfonyl moiety includes a hydrophobic substituent.
Claim 11
Dependent Claim
22 words
An optical article according to claim 6 further characterized in that said Langmuir-Blodgett film is comprised of a Y-type Langmuir-Blodgett film assembly.
Claim 12
Dependent Claim
40 words
An optical article according to claim 7 further characterized in that said molecular dipole exhibits the structure Y-E-A where A is a hydrophilic sulfonyl moiety; E is a conjugated π bonding system; and Y is a hydrophobic electron donor moiety.
Claim 13
Dependent Claim
40 words
An optical article according to claim 7 further characterized in that said molecular dipole exhibits the structure K-E-M where K is a hydrophobic sulfonyl moiety; E is a conjugated π bonding system; and M is a hydrophilic electron donor moiety.
Claim 14
Dependent Claim
33 words
An optical article according to any one of claims 1 to 5 inclusive further characterized in that said transmission medium is comprised of a substrate and a self-assembled film containing said molecular dipole.
Claim 15
Dependent Claim
30 words
An optical article according to any one of claims 1 to 5 inclusive further characterized in that said molecular dipole is held in polar alignment in a surround polymeric medium.
Claim 16
Dependent Claim
21 words
An optical article according to claim 14 further characterized in that said molecular dipole is covalently bonded to said polymeric medium.
Claim 17
Dependent Claim
29 words
An optical article according to claim 15 further characterized in that said molecular dipole is covalently bonded to said polymeric medium through the sulfur atom of the sulfonyl moiety.
Claim 18
Dependent Claim
56 words
An optical article according to any one of claims 1 to 16 inclusive further characterized in that said molecular dipole is comprised of the following moieties: where D is an electron donor moiety, E is a conjugated π bonding system, which provides a pathway for charge transfer resonance, and R is an optionally substituted hydrocarbon moiety.
Claim 19
Dependent Claim
46 words
An optical article according to claim 17 further characterized in that the molecular dipole is comprised of the following moieties: where E is a conjugated π bonding system; R is an optionally substituted hydrocarbon moiety; and R² and R³ are hydrogen or optionally substituted hydrocarbon moieties.
Claim 20
Dependent Claim
42 words
An optical article according to claim 17 further characterized in that the molecular dipole is comprised of the following moieties: where E is a conjugated π bonding system; R and R⁴ are optionally substituted hydrocarbon moieties; and X is oxygen or sulfur.
Claim 21
Dependent Claim
68 words
An optical article according to any one of claims 1 to 19 inclusive further characterized in that the molecular dipoles are comprised of the following moieties: where D is an electron donor moiety; G is independently in each occurrence methine or aza, with the proviso that no more than two aza groups can be next adjacent; n is 4 to 20; and R is an optionally substituted hydrocarbon.
Claim 22
Dependent Claim
16 words
An optical article according to claim 20 further characterized in that n is 8 to 14.
Claim 23
Dependent Claim
24 words
An optical article according to claim 20 further characterized in that the linking moiety formed by G includes at least two planar aromatic rings.
Claim 24
Dependent Claim
35 words
An optical article according to claim 22 further characterized in that the sulfonyl electron acceptor moiety of the molecular dipole is linked to the electron donor moiety through at least two copolanar carbocyclic aromatic rings.
Claim 25
Dependent Claim
18 words
An optical article according to claim 23 further characterized in that the linking moiety is a 4,4′-stilbenoid moiety.
Claim 26
Dependent Claim
18 words
An optical article according to claim 24 further characterized in that the linking moiety is a 4,4′-stilbene moiety.
Claim 27
Dependent Claim
24 words
An optical article according to any one of claims 1 to 23 inclusive further characterized in that the sulfonyl moiety is a sulfonimino moiety.
Claim 28
Dependent Claim
34 words
An optical article according to any one of claims 1 to 26 inclusive further characterized in that the electron donor moiety forms a heterocyclic ring with a portion of the conjugated π bonding system.
Claim 29
Dependent Claim
31 words
An optical article according to any one of claims 1 to 18 inclusive and 20 to 27 inclusive further characterized in that the electron donor moiety is a secondary amino moiety.
Claim 30
Dependent Claim
28 words
An optical article according to claims 1 to 18 inclusive and 20 to 27 inclusive further characterized in that the electron donor moiety is a tertiary amino moiety.
Claim 31
Dependent Claim
26 words
An optical article according to any one of claims 1 to 5 inclusive further characterized in that the molecular dipole is present in a crystalline form.
Claim 32
Dependent Claim
31 words
An optical article according to any one of claims 1 to 30 inclusive further characterized in that the transmission medium exhibits a second order polarization susceptibiity greater than 10⁻⁸ electrostatic units.
References Cited (Backward Citations)
No citation records indexed.
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