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EP0308872A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Direct positive-type silver halide light-sensitive photographic material

Assignee: Konica Minolta Inc
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Filing: 1988-09-20
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Granted: —
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Expires: 2008-09-20
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Abstract

Abstract A direct positive type silver halide photographic material and developing method therefor are disclosed. The photographic material have blue-, green- and red-sensitive emulsion layers and each of these emulsion layer contains at least two kinds of silver halide emulsion being different from each other in average grain size. The average grain diameter S of the emulsion having the smallest average grain size and the average grain diameter of the emulsion having the largest average grain size in each emulsion layer have a proportional relation of 1.6 ≦ L/S. The emulsion having the smallest average grain size is contained in a ratio of from 2 to 50 % in the blue-sensitive layer and 2 to 40 % in green- and red-­sensitive emulsion layer.

Inventors

  • 👤 Kazuya Kuramoto
  • 👤 Bunzo Ueda
  • 👤 Yasuo Tosaka

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-02 19:22
CPC Classifications
G; G03; G03C; G03C7/00; G03C7/30; G03C7/3022

Claims Analysis

Total Claims: 23
Claim 1
Independent Claim 472 words
A direct positive type silver halide photographic light-­sensitive material comprising a support having thereon at least one blue-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer and at least one red-sensitive silver halide emulsion layer, which, after being imagewise exposed, are to directly form a positive image by being light-fogged while in developing or by developing in the presence of a fogging agent, wherein each of said silver halide emulsion layers is comprised of at least two silver halide emulsions being different in the average silver halide grain size, and in each of said emulsion layers, then average diameter S of silver halide grains of the emulsion having the smallest average grain size and the average diameter L of silver halide grains of the emulsion having the largest average grain size have a proportional relation of 1.6 ≦ L/S; and the ratio by weight of silver haide grains of the emulsion having the smallest average grain size in each silver halide emulsiom layer to the whole silver halide grains contained in each silver halide emulsion layer is within the range of from 2% to 50% in said blue-sensitive emulsion layer, from 2% to 40% in said green-sensitive and red-sensitive emulsion layers; and said blue-sensitive emulsion layer contains at least one sensitizing dye represented by the following Formula I, said green-sensitive emulsion layer contains at least one sensitizing dye represented by the following Formula II and said red-sensitive emulsion layer contains at least one sensitizing dye represented by the following Formula III, wherein Z₁ and Z₂ each represents a group of atoms necessary to complete a ring of benzothiazole, naphthothiazole, benzo­selenazole or naphthoselenazole; R₁ and R₂ each represents an unsubstituted or substituted alkyl group, provided that at least one of the R₁ and R₂ represents an alkyl group substituted by a sulfo group or a carboxyl group; X₁⁻ represents an anion; and ℓ represents an integer of 1 or 2, wherein Z₃ and Z₄ each represents a group of atoms necessary to complete a ring of benzoxazol or naphthoxazole; R₃ and R₄ each represents an unsubstituted or substituted alkyl group, provided that at least one of the R₃ and R₄ represents an alkyl group substituted by a sulfo group or a carboxyl group; R₅ represents a lower alkyl group; X₂⁻ represents an anion; and m represents an integer of 1 or 2, wherein Z₅ and Z₆ each represents a group of atoms necessary to complete a ring of benzothiazole, naphthothiazole, benzo­selenazole, or naphthoselenazole; R₆ and R₇ each represents an unsubstituted or substituted alkyl group, provided that at least one of the R₆ and R₇ represents an alkyl group substituted by a sulfo group or a carboxyl group; R₈ represents an alkyl group or an aryl group; X₃⁻ represents an anion; and n represents an integer of 1 or 2.
Claim 2
Dependent Claim 472 words
A direct positive type silver halide photographic light-­sensitive material comprising a support having thereon at least one blue-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer and at least one red-sensitive silver halide emulsion layer, which, after being imagewise exposed, are to directly form a positive image by being light-fogged while in developing or by developing in the presence of a fogging agent, wherein each of said silver halide emulsion layers is comprised of at least two silver halide emulsions being different in the average silver halide grain size, and in each of said emulsion layers, then average diameter S of silver halide grains of the emulsion having the smallest average grain size and the average diameter L of silver halide grains of the emulsion having the largest average grain size have a proportional relation of 1.6 ≦ L/S; and the ratio by weight of silver haide grains of the emulsion having the smallest average grain size in each silver halide emulsiom layer to the whole silver halide grains contained in each silver halide emulsion layer is within the range of from 2% to 50% in said blue-sensitive emulsion layer, from 2% to 40% in said green-sensitive and red-sensitive emulsion layers; and said blue-sensitive emulsion layer contains at least one sensitizing dye represented by the following Formula I, said green-sensitive emulsion layer contains at least one sensitizing dye represented by the following Formula II and said red-sensitive emulsion layer contains at least one sensitizing dye represented by the following Formula III, wherein Z₁ and Z₂ each represents a group of atoms necessary to complete a ring of benzothiazole, naphthothiazole, benzo­selenazole or naphthoselenazole; R₁ and R₂ each represents an unsubstituted or substituted alkyl group, provided that at least one of the R₁ and R₂ represents an alkyl group substituted by a sulfo group or a carboxyl group; X₁⁻ represents an anion; and ℓ represents an integer of 1 or 2, wherein Z₃ and Z₄ each represents a group of atoms necessary to complete a ring of benzoxazol or naphthoxazole; R₃ and R₄ each represents an unsubstituted or substituted alkyl group, provided that at least one of the R₃ and R₄ represents an alkyl group substituted by a sulfo group or a carboxyl group; R₅ represents a lower alkyl group; X₂⁻ represents an anion; and m represents an integer of 1 or 2, wherein Z₅ and Z₆ each represents a group of atoms necessary to complete a ring of benzothiazole, naphthothiazole, benzo­selenazole, or naphthoselenazole; R₆ and R₇ each represents an unsubstituted or substituted alkyl group, provided that at least one of the R₆ and R₇ represents an alkyl group substituted by a sulfo group or a carboxyl group; R₈ represents an alkyl group or an aryl group; X₃⁻ represents an anion; and n represents an integer of 1 or 2.
Claim 3
Dependent Claim 15 words
The material of claim 1, wherein said proportional relation is 1.6 ≦ L/S ≦ 2.3.
Claim 4
Dependent Claim 38 words
The material of claim 1, wherein said ratio of said silver halide grains of said silver halide emulsion having the smallest average grain size in said blue-sensitive emulsion layer is within the range of from 2% to 40%.
Claim 5
Dependent Claim 17 words
The material of claim 3, wherein said ratio is within the range of from 10% to 40%.
Claim 6
Dependent Claim 38 words
The material of claim 1, wherein said ratio of said silver halide grains of said silver halide emulsion having the smallest average grain size in said green-sensitive emulsion layer is within the range of from 2% to 25%.
Claim 7
Dependent Claim 17 words
The material of claim 5, wherein said ratio is within the range of from 8% to 25%.
Claim 8
Dependent Claim 38 words
The material of claim 1, wherein said ratio of said silver halide grains of said silver halide emulsion having the smallest average grain size in said red-sensitive emulsion layer is within the range of from 2% to 20%.
Claim 9
Dependent Claim 17 words
The material of claim 7, wherein said ratio is within the range of from 5% to 20%.
Claim 10
Dependent Claim 46 words
The material of claim 1, wherein said blue-sensitive emulsion layer contains at least one silver halide emulsion containing said sensitizing dye represented by Formula I in an amount of not less than 5.5 × 10⁻⁷ mol per square meter of surface area of silver halide grains.
Claim 11
Dependent Claim 37 words
The material of claim 9, wherein said amount of said sensitizing dye is within the range of from 5.5 × 10⁻⁷ mol to 15 × 10⁻⁷ mol per square meter of surface area of silver halide grains.
Claim 12
Dependent Claim 37 words
The material of claim 10, wherein said amount of said sensitizing dye is within the range of from 6.5 × 10⁻⁷ mol to 11.0 × 10⁻⁷ mol per square meter of surface area of silver halide grains.
Claim 13
Dependent Claim 44 words
The material of claim 1, wherein said green-sensitive emulsion layer contains at least one emulsion containing said sensitizing dye represented by Formula II in an amount of ont less than 2.0 × 10⁻⁷ mol per square meter of surface area of silver halide grains.
Claim 14
Dependent Claim 37 words
The material of claim 12, wherein said amount of said sensitizing dye is within the range of from 2.0 × 10⁻⁷ mol to 8.0 × 10⁻⁷ mol per square meter of surface area of silver halide grains.
Claim 15
Dependent Claim 37 words
The material of claim 13, wherein said amount of said sensitizing dye is within the range of from 2.5 × 10⁻⁷ mol to 5.0 × 10⁻⁷ mol per suare meter of surface area of silver halide grains.
Claim 16
Dependent Claim 46 words
The material of claim 1, wherein said red-sensitive emulsion layer contains at least one silver halide mulsion containing said sensitizing dye represented by Formula III in an amount of ont less than 1.5 × 10⁻⁷ mol per square meter of surface area of silver halide grains.
Claim 17
Dependent Claim 32 words
The material of claim 15, wherein said amount of said sensitizing dye is 1.5 × 10⁻⁷ mol to 7.5 × 10⁻⁷ mol per square meter of surface area of silver halide grains.
Claim 18
Dependent Claim 37 words
The material of claim 16, wherein said amount of said sensitizing dye is within the range of from 2.0 × 10⁻⁷ mol to 4.5 × 10⁻⁷ mol per square meter of surface area of silver halide grains.
Claim 19
Dependent Claim 51 words
The material of claim 1, wherein each of said emulsions is a monodispersed emulsion in which silver halide grains having a diameter within the range of ±20 % of the average grain diameter are contained in an amount of not less than 60 % of the weight of whole silver halide.
Claim 20
Dependent Claim 14 words
The material of claim 18, wherein said amount is not less than 70 %.
Claim 21
Dependent Claim 14 words
The material of claim 19, wherein said amount is not less than 80 %.
Claim 22
Dependent Claim 39 words
The material of claim 1, wherein said said emulsions each comprises silver halide grains comprised of at least two strata including an internal core stratum and an external shell stratum, different from each other in the silver halide composition.
Claim 23
Dependent Claim 34 words
The material of claim 21, wherein said silver halide grains have a silver chloride content of not less than 30 mol% in the grain surface and not less than 20 mol% as a whole.

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