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EP0308286A1 Expired / Lapsed EP ⏱️ 0.0 years remaining

Reinforced thermoplastic sheet of high moldability

Assignee: ExxonMobil Chemical Patents Inc
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Filing: 1988-08-25
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Granted: —
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Expires: 2008-08-25
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Abstract

Abstract This semifinished product is a non-densified flexible sheet containing, as an intimate mixture, reinforcing fibers dispersed in the unit state, particles of polyolefinic resin and at least one organic peroxide whose decomposition, during hot con­version of the sheet, gives the mixture a high moldability. The articles obtained by compression exhibit a homogeneous distribution of the reinforcing fibers.

Inventors

  • 👤 Michel Goguelin

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-09 07:02
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/18; C08K; C08K5/00; C08K5/04; C08K5/14

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 56 words
A method of preparation of a flexible sheet comprising a thermoplastic resin and reinforcing fibers and intended for conversion by heating and molding, characterised in that it comprises incorporating in said sheet at least one organic peroxide, in the active state, whose decomposition temperature is compatible with the melting point and conversion temperature of the sheet.
Claim 2
Independent Claim 56 words
A method of preparation of a flexible sheet comprising a thermoplastic resin and reinforcing fibers and intended for conversion by heating and molding, characterised in that it comprises incorporating in said sheet at least one organic peroxide, in the active state, whose decomposition temperature is compatible with the melting point and conversion temperature of the sheet.
Claim 3
Dependent Claim 18 words
The method according to claim 1, wherein the resin is in the form of powder, fibers or fibrils.
Claim 4
Dependent Claim 15 words
The method according to claim 1 or claim 2, wherein the resin is a polyolefin.
Claim 5
Dependent Claim 13 words
The method according to claim 3, wherein the resin is a polypropylene homopolymer.
Claim 6
Independent Claim 33 words
The method according to any one of claims 1 to 4, wherein the peroxide is selected from monofunctional or polyfunctional peroxides whose temperature at which the half-life is 1 minute is above 170°.
Claim 7
Independent Claim 41 words
The method according to any one of claims 1 to 5, wherein the peroxide is selected from : - dicumyl peroxide - tert-butyl cumyl peroxide - 2,5-dimethyl-2,5-bis(tert-butylperoxy) hexane - 1,3-bis (tert-butyperoxyisopropyl) benzene - ditert-butyl peroxide - 2,5-dimethyl-2,5-bis (tert-butylperoxy) hexyne - 3,3,6,6,9,9-hexamethyl-1,2,4,5-textraoxacylononane
Claim 8
Independent Claim 35 words
The method according to any one of claims 1 to 6, wherein the peroxide is present in the sheet in a proportion of from 0.05 to 1% of the total dry weight of the sheet.
Claim 9
Independent Claim 36 words
The method according to any one of claims 1 to 7, wherein the reinforcing fibers are present in a proportion of 15 to 60%, preferably 20 to 40%, of the total dry weight of the sheet.
Claim 10
Independent Claim 33 words
The method according to any one of claims 1 to 8 wherein the reinforcing fibers are glass fibers preferably from 6 to 25mm long and/or preferably from 9 to 15 microns in diameter.
Claim 11
Independent Claim 22 words
The method according to any one of claims 1 to 9, which is a flexible sheet made by the wet paper-making process.
Claim 12
Dependent Claim 29 words
The method according to claim 10 wherein the peroxide under suspended form in an aqueous solution, is added to a slurry comprising polymer particles, reinforcing fibers and process aids.
Claim 13
Independent Claim 78 words
A method of forming a molding from a sheet obtained by the method according to any one of claims 1 to 10 which comprises heating the sheet to a temperature sufficient to melt the resin and decompose the peroxide, thereby degrading the resin and increasing its melt flow value, and coating and compressing the heated sheet in a mold of desired shape to form a molding of a continuous plastic matrix having discrete reinforcing fibers homogeneously dispersed therein.

References Cited (Backward Citations)

GB2100268A Cited
US4489034A Cited
EP0211479A2 Cited
EP0208353A1 Cited

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