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EP0307587A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Solid cast warewashing composition

Assignee: Ecolab Inc
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Filing: 1988-07-23
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Granted: —
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Expires: 2008-07-23
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Abstract

Abstract Solid cast detergent-containing articles are produced for use in automatic washing machines. A liquid detergent composition is cast into a mold where it is allowed to solidify. The cast detergent composition includes alkali metal metasilicate, alkali metal condensed phosphate, an encapsulated bleaching source, and water for hydration. The composition optionally further includes a dye, a perfume, a surfactant, a defoamer, an additional sequestering agent such as an alkali metal salt of a polyacrylic compound, a neutral soluble salt such as an alkali metal sulphate or an alkali metal chloride, an alkali compound such as an alkali metal hydroxide, an alkali metal carbonate, an alkali metal bicarbonate, an alkali metal sesquicarbonte, an alkali metal borate, or mixtures thereof.

Inventors

  • 👤 Keith Edward Olson

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-27 17:14
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/02; C11D3/04; C11D3/06; C11D17/00; C11D17/0039; C11D17/0047; C11D17/0052; C11D3/08; C11D3/395

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 363 words
A solid cast warewashing composition which comprises: (a) about 20 to 55 wt-%, based upon the solid cast warewashing composition and calculated on an anhydrous basis, of a hydratable, crystalline alkali metal silicate composition; (b) about 1 to 70 wt-%, based upon the solid cast warewashing composition, of an alkali metal condensed phosphate composition, having sufficient water of hydration to allow the cast warewashing composition to solidify; (c) about 0.1 to 20 wt-%, based upon the solid cast warewashing composition, of an encapsulated bleaching source which comprises: (i) a bleaching agent core; (ii) an inner coating of a separating compound in an amount sufficient to retard any chemical interaction between the bleaching agent core and an outer coating compound; and (iii) an outer coating of an encapsulating amount of a water soluble cellulose ether compound selected from the group consisting of (C₁₋₄) alkyl cellulose, carboxy (C₁₋₄) alkyl cellulose, hydroxy (C₁₋₄) alkyl cellulose, carboxy (C₁₋₄) alkyl hydroxy (C₁₋₄) alkyl cellulose, (C₁₋₄) alkyl hydroxy (C₁₋₄) alkyl cellulose, and mixtures thereof. (d) about 8 to 60 wt-%, based upon the solid cast warewashing composition, water; (e) about 0 to 10 wt-%, based upon the solid cast warewashing composition, dye; (f) about 0 to 10 wt-%, based upon the solid cast warewashing composition, perfume; (g) about 0 to 15 wt-%, based upon the solid cast warewashing composition, surfactant; (h) about 0 to 15 wt-%, based upon the solid cast warewashing composition, defoamer; (i) about 0 to 20 wt-%, based upon the solid cast warewashing composition, alkali metal salt of a polyacrylic acid compound; (j) about 0 to 20 wt-%, based upon the solid cast warewashing composition of a neutral soluble salt selected from the group consisting of an alkali metal sulphate compound and an alkali metal chloride compound; and (k) about 0 to 30 wt-%, based upon the solid cast warewashing composition, of an alkali compound selected from the group consisting of alkali metal hydroxides, soluble alkali metal silicates with the formula (M₂O) x :(SiO₂) y wherein M is an alkali metal and the ratio of x:y is about 1.0:1.6 to 1.0:3.75, alkali metal carbonates, alkali metal bicarbonates, alkali metal sesquicarbonates, alkali metal borates and mixtures thereof.
Claim 2
Dependent Claim 363 words
A solid cast warewashing composition which comprises: (a) about 20 to 55 wt-%, based upon the solid cast warewashing composition and calculated on an anhydrous basis, of a hydratable, crystalline alkali metal silicate composition; (b) about 1 to 70 wt-%, based upon the solid cast warewashing composition, of an alkali metal condensed phosphate composition, having sufficient water of hydration to allow the cast warewashing composition to solidify; (c) about 0.1 to 20 wt-%, based upon the solid cast warewashing composition, of an encapsulated bleaching source which comprises: (i) a bleaching agent core; (ii) an inner coating of a separating compound in an amount sufficient to retard any chemical interaction between the bleaching agent core and an outer coating compound; and (iii) an outer coating of an encapsulating amount of a water soluble cellulose ether compound selected from the group consisting of (C₁₋₄) alkyl cellulose, carboxy (C₁₋₄) alkyl cellulose, hydroxy (C₁₋₄) alkyl cellulose, carboxy (C₁₋₄) alkyl hydroxy (C₁₋₄) alkyl cellulose, (C₁₋₄) alkyl hydroxy (C₁₋₄) alkyl cellulose, and mixtures thereof. (d) about 8 to 60 wt-%, based upon the solid cast warewashing composition, water; (e) about 0 to 10 wt-%, based upon the solid cast warewashing composition, dye; (f) about 0 to 10 wt-%, based upon the solid cast warewashing composition, perfume; (g) about 0 to 15 wt-%, based upon the solid cast warewashing composition, surfactant; (h) about 0 to 15 wt-%, based upon the solid cast warewashing composition, defoamer; (i) about 0 to 20 wt-%, based upon the solid cast warewashing composition, alkali metal salt of a polyacrylic acid compound; (j) about 0 to 20 wt-%, based upon the solid cast warewashing composition of a neutral soluble salt selected from the group consisting of an alkali metal sulphate compound and an alkali metal chloride compound; and (k) about 0 to 30 wt-%, based upon the solid cast warewashing composition, of an alkali compound selected from the group consisting of alkali metal hydroxides, soluble alkali metal silicates with the formula (M₂O) x :(SiO₂) y wherein M is an alkali metal and the ratio of x:y is about 1.0:1.6 to 1.0:3.75, alkali metal carbonates, alkali metal bicarbonates, alkali metal sesquicarbonates, alkali metal borates and mixtures thereof.
Claim 3
Dependent Claim 59 words
Composition according to Claim 1, which comprises: (a) about 20 to 40 wt-% of the said alkali metal silicate composition; (b) about 15 to 40 wt-% of the said alkali metal condensed phosphate composition; (c) about 0.1 to 15 wt-% of the said encapsulated bleaching source, the water content of said bleaching source being about 8 to 35 %.
Claim 4
Dependent Claim 22 words
Composition according to Claim 1 or 2 wherein the inner coating compound of the encapsulated bleaching source comprises a water-soluble coating compound.
Claim 5
Dependent Claim 22 words
Composition according to anyone of Claims 1 to 3 wherein the bleaching agent core comprises a core of an active chlorine source.
Claim 6
Dependent Claim 40 words
Composition according to anyone of Claims 1 to 4 wherein the hydratable crystalline alkali metal silicate has the formula (M₂O) x :(SiO₂) y wherein M is an alkali metal and the ratio of x:y is about 1:1 to about 3:1.
Claim 7
Dependent Claim 18 words
Composition according to anyone of Claims 1 to 5 wherein the alkali metal condensed phosphate composition is hydrated.
Claim 8
Dependent Claim 33 words
Composition according to anyone of Claims 1 to 6 wherein the alkali metal condensed phosphate comprises a hydrated alkali metal tripolyphosphate having sufficient water of hydration to allow the cast composition to solidify.
Claim 9
Dependent Claim 37 words
Composition according to anyone of Claims 1 to 7 wherein the alkali metal condensed phosphate comprises a hydrated alkali metal tripolyphosphate having at least about 15 wt-%, based upon the hydrated alkali metal tripolyphosphate, water of hydration.
Claim 10
Independent Claim 409 words
A method of cleaning ware which comprises the steps of: (a) contacting a solid cast warewashing composition and water to form an aqueous cleaning solution; and (b) contacting soiled ware with the cleaning solution so as to remove soil from the soiled ware; wherein the solid cast warewashing composition comprises: (i) about 20 to 55 wt-%, based upon the solid cast warewashing composition and calculated on an anhydrous basis, of a hydratable crystalline alkali metal silicate; (ii) about 1 to 70 wt-%, based upon the solid cast warewashing composition, of an alkali metal condensed phosphate composition having sufficient water of hydration to allow the cast warewashing composition to solidify; and (iii) about 0.1 to 20 wt-%, based upon the solid cast warewashing composition, of an encapsulated bleaching source which comprises: (1) a bleaching agent core; (2) an inner coating of a separating compound in an amount sufficient to retard any chemical interaction between the bleaching agent core and an outer coating compound; and (3) an outer coating of an encapsulating amount of a water soluble cellulose ether compound selected from the group consisting of (C₁₋₄) alkyl cellulose, carboxy (C₁₋₄) alkyl cellulose, hydroxy (C₁₋₄) alkyl cellulose, carboxy (C₁₋₄) alkyl hydroxy (C₁₋₄) alkyl cellulose, (C₁₋₄) alkyl hydroxy (C₁₋₄) alkyl cellulose, and mixtures thereof; (iv) about 8 to 60 wt-% water, based upon the solid cast warewashing composition; (v) about 0 to 10 wt-%, based upon the solid cast warewashing composition, of a dye; (vi) about 0 to 10 wt-%, based upon the solid cast warewashing composition of a perfume; (vii) about 0 to 15 wt-%, based upon the solid cast composition, of a surfactant; (viii) about 0 to 15 wt-%, based upon the solid cast composition, of a defoamer; (ix) about 0 to 20 wt-%, based upon the solid cast composition, of an alkali metal salt of a polyacrylic acid compound; (x) about 0 to 20 wt-%, based upon the solid cast composition, a neutral soluble salt selected from the group consisting of an alkali metal sulphate compound an alkali metal chloride compound; and (xi) about 0 to 30 wt-%, based upon the solid cast warewashing composition, of an alkali compound selected from the group consisting of alkali metal hydroxides, soluble alkali metal silicates with the formula (M₂O) x :(SiO₂)y wherein M is an alkali metal and the ratio of x:y is about 1.0:1.6 to 1.0:3.75, alkali metal carbonates, alkali metal bicarbonates, alkali metal sesquicarbonates, alkali metal borates and mixtures thereof.
Claim 11
Independent Claim 409 words
A method of cleaning ware which comprises the steps of: (a) contacting a solid cast warewashing composition and water to form an aqueous cleaning solution; and (b) contacting soiled ware with the cleaning solution so as to remove soil from the soiled ware; wherein the solid cast warewashing composition comprises: (i) about 20 to 55 wt-%, based upon the solid cast warewashing composition and calculated on an anhydrous basis, of a hydratable crystalline alkali metal silicate; (ii) about 1 to 70 wt-%, based upon the solid cast warewashing composition, of an alkali metal condensed phosphate composition having sufficient water of hydration to allow the cast warewashing composition to solidify; and (iii) about 0.1 to 20 wt-%, based upon the solid cast warewashing composition, of an encapsulated bleaching source which comprises: (1) a bleaching agent core; (2) an inner coating of a separating compound in an amount sufficient to retard any chemical interaction between the bleaching agent core and an outer coating compound; and (3) an outer coating of an encapsulating amount of a water soluble cellulose ether compound selected from the group consisting of (C₁₋₄) alkyl cellulose, carboxy (C₁₋₄) alkyl cellulose, hydroxy (C₁₋₄) alkyl cellulose, carboxy (C₁₋₄) alkyl hydroxy (C₁₋₄) alkyl cellulose, (C₁₋₄) alkyl hydroxy (C₁₋₄) alkyl cellulose, and mixtures thereof; (iv) about 8 to 60 wt-% water, based upon the solid cast warewashing composition; (v) about 0 to 10 wt-%, based upon the solid cast warewashing composition, of a dye; (vi) about 0 to 10 wt-%, based upon the solid cast warewashing composition of a perfume; (vii) about 0 to 15 wt-%, based upon the solid cast composition, of a surfactant; (viii) about 0 to 15 wt-%, based upon the solid cast composition, of a defoamer; (ix) about 0 to 20 wt-%, based upon the solid cast composition, of an alkali metal salt of a polyacrylic acid compound; (x) about 0 to 20 wt-%, based upon the solid cast composition, a neutral soluble salt selected from the group consisting of an alkali metal sulphate compound an alkali metal chloride compound; and (xi) about 0 to 30 wt-%, based upon the solid cast warewashing composition, of an alkali compound selected from the group consisting of alkali metal hydroxides, soluble alkali metal silicates with the formula (M₂O) x :(SiO₂)y wherein M is an alkali metal and the ratio of x:y is about 1.0:1.6 to 1.0:3.75, alkali metal carbonates, alkali metal bicarbonates, alkali metal sesquicarbonates, alkali metal borates and mixtures thereof.
Claim 12
Independent Claim 263 words
A method of making a solid cast warewashing composition which comprises the steps of: (a) combining about 8 to 60 wt-%, based upon the solid cast warewashing composition, water and about 20 to 55 wt-%, based upon the solid cast warewashing composition, of a hydratable, crystalline alkali metal silicate composition to form an aqueous composition; (b) heating the aqueous composition to a temperature sufficient to hydrate the alkali metal silicate; (c) cooling the hydrated alkali metal silicate; (d) combining about 1 to 70 wt-%, based upon the solid cast warewashing composition, alkali metal condensed phosphate composition having sufficient water of hydration to allow the cast warewashing composition to solidify, and the cooled hydrated alkali metal silicate composition to form a mixture; (e) cooling the mixture to about 110 to 140 °F.; (f) combining the cooled mixture and about 0.1 to 20 wt-%, based upon the solid cast warewashing composition, of an encapsulated bleaching source to form a liquid detergent composition; the encapsulated bleaching source comprising: (i) a bleaching agent core; (ii) an inner coating of a separating compound in an amount sufficient to retard any chemical interaction between the bleaching agent core and an outer coating compound; and (iii) an outer coating of an encapsulating amount of a water soluble cellulose ether compound selected from the group consisting of (C₁₋₄) alkyl cellulose, carboxy (C₁₋₄) alkyl cellulose, hydroxy (C₁₋₄) alkyl cellulose, carboxy (C₁₋₄) alkyl hydroxy (C₁₋₄) alkyl cellulose, (C₁₋₄) alkyl hydroxy (C₁₋₄) alkyl cellulose, and mixtures thereof; and (g) casting the liquid detergent composition into a container to form the solid cast warewashing composition.
Claim 13
Independent Claim 263 words
A method of making a solid cast warewashing composition which comprises the steps of: (a) combining about 8 to 60 wt-%, based upon the solid cast warewashing composition, water and about 20 to 55 wt-%, based upon the solid cast warewashing composition, of a hydratable, crystalline alkali metal silicate composition to form an aqueous composition; (b) heating the aqueous composition to a temperature sufficient to hydrate the alkali metal silicate; (c) cooling the hydrated alkali metal silicate; (d) combining about 1 to 70 wt-%, based upon the solid cast warewashing composition, alkali metal condensed phosphate composition having sufficient water of hydration to allow the cast warewashing composition to solidify, and the cooled hydrated alkali metal silicate composition to form a mixture; (e) cooling the mixture to about 110 to 140 °F.; (f) combining the cooled mixture and about 0.1 to 20 wt-%, based upon the solid cast warewashing composition, of an encapsulated bleaching source to form a liquid detergent composition; the encapsulated bleaching source comprising: (i) a bleaching agent core; (ii) an inner coating of a separating compound in an amount sufficient to retard any chemical interaction between the bleaching agent core and an outer coating compound; and (iii) an outer coating of an encapsulating amount of a water soluble cellulose ether compound selected from the group consisting of (C₁₋₄) alkyl cellulose, carboxy (C₁₋₄) alkyl cellulose, hydroxy (C₁₋₄) alkyl cellulose, carboxy (C₁₋₄) alkyl hydroxy (C₁₋₄) alkyl cellulose, (C₁₋₄) alkyl hydroxy (C₁₋₄) alkyl cellulose, and mixtures thereof; and (g) casting the liquid detergent composition into a container to form the solid cast warewashing composition.
Claim 14
Dependent Claim 121 words
Method according to Claim 10 wherein (i) about 8 to 35 wt-%, based upon the solid cast warewashing composition, water and about 20 to 40 wt-%, based upon the solid cast warewashing composition, hydratable, crystalline alkali metal silicate composition are combined to form the aqueous composition, and (ii) about 15 to 40 wt-%, based upon the solid cast warewashing composition, alkali metal condensed phosphate composition having sufficient water of hydration to allow the cast warewashing composition to solidify, is combined with the cooled hydrated alkali metal silicate composition to form the mixture, and (iii) about 0.1 to 15 wt-%, based upon the solid cast warewashing composition, encapsulated bleaching source is combined with the cooled mixture to form the liquid detergent composition.

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