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EP0298345A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Method for preparing substrates for subsequent electroless metallization

Assignee: International Business Machines Corp
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Filing: 1988-06-28
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Granted: —
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Expires: 2008-06-28
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Abstract

Abstract A process for preparing a substrate, e.g., an epoxy printed circuit board, for subsequent metallization. Active chemical sites are formed adhering to the substrate surface. The substrate is then exposed to a vapor of a volatile organometallic compound, which chemically reacts with the active sites and is decomposed to at least a species of the metal constituent of the compound. This species adheres to the substrate and can be transformed into the free metal which is useful as a seed for subsequent electro­less deposition of a metal thereon. If selective deposition is desired, a resist masking layer is used prior to forming the seed layer.

Inventors

  • 👤 Thomas Carl Clarke
  • 👤 Caroline Ann Kovac
  • 👤 Dae Young Jung
  • 👤 Jae Myung Park
  • 👤 Richard Ronald Thomas

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-09 03:56
CPC Classifications
C; C23; C23C; C23C18/00; C23C18/16; C23C18/18; C23C18/20; C23C18/2006; C23C18/2026; C23C18/2033; C23C16/00; C23C16/04; C23C16/06; C23C16/18; C23C18/1601; C23C18/1603; C23C18/1605; C23C18/1607; C23C18/1608; C23C18/1851; C23C18/1862; C23C18/1865; C23C18/1872; C23C18/1886; C23C18/1893; C23C18/2046; C23C18/2073; C23C18/2086; C23C18/28; C23C18/30; C23C18/31; C23C18/32; C23C18/38; C23C18/42; H; H05; H05K; H05K3/00; H05K3/10; H05K3/18; H05K3/181; H05K3/14; H05K3/146; H05K3/182; H05K3/184

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 83 words
A method for preparing a substrate surface for subsequent metallization comprising the steps of: forming active chemical sites adherent to the substrate surface, said active chemical sites being capable of decomposing a volatile organo­metallic compound exposed to said sites to a species of the metal constituent of said compound and, contacting a portion of said substrate surface with a vapor of said volatile organometallic compound for a time sufficient to decompose said compound to said species, said species adhering to the substrate surface.
Claim 2
Independent Claim 83 words
A method for preparing a substrate surface for subsequent metallization comprising the steps of: forming active chemical sites adherent to the substrate surface, said active chemical sites being capable of decomposing a volatile organo­metallic compound exposed to said sites to a species of the metal constituent of said compound and, contacting a portion of said substrate surface with a vapor of said volatile organometallic compound for a time sufficient to decompose said compound to said species, said species adhering to the substrate surface.
Claim 3
Dependent Claim 22 words
Method according to claim 1 further including the step of transforming said species to said constituent metal adhering to the substrate surface.
Claim 4
Dependent Claim 14 words
Method according to claim 1 or 2 wherein said species is said constituent metal.
Claim 5
Dependent Claim 29 words
Method according to any one of claims 1 to 3 wherein the constituent metal of said organometallic compound is selected from the group consisting of nickel, copper and palladium.
Claim 6
Dependent Claim 27 words
Method according to any one of claims 1 to 4 wherein said active chemical sites are selected from the group consisting of acidic sites and ammonia functionals.
Claim 7
Dependent Claim 42 words
Method according to any one of claims 1 to 5 wherein said organometallic compound is selected from the group consisting of a (cyclopentadienyl) (allyl)palladium(II) compound, a bis(allyl) palladium(II) compound, a nickel carbonyl compound, a diallynickel(II) compound and a (cyclopentadienyl) (triethylphosphine) copper(I) compound.
Claim 8
Dependent Claim 25 words
Method according to any one of claims 1 to 6 wherein said substrate is selected from the group consisting of polymers, epoxies, semiconductors and ceramics.
Claim 9
Dependent Claim 64 words
Method according to any one of claims 1 to 7 wherein said step of contacting a portion of the substrate surface includes the steps of, prior to contacting the substrate surface with the organo­metallic vapor, covering the substrate with a resist-type material and selectively removing said resist material, where said vapor contacts active chemical sites only in said exposed portion of said substrate surface.
Claim 10
Dependent Claim 31 words
Method according to any one of claims 1 to 8 further including the step of electrolessly depositing a metal onto those areas of the substrate to which said constituent metal adheres.
Claim 11
Dependent Claim 24 words
Method according to claim 9 wherein the electrolessly deposited metal is selected from the group consisting of copper, cobalt, palladium, nickel, silver and gold.

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