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EP0294648A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Novel copolymer and water- and oil-repellent comprising the same

Assignee: Daikin Industries Ltd
•
Filing: 1988-05-25
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Granted: —
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Expires: 2008-05-25
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Abstract

Abstract A fluorine-containing copolymer comprising (a) 40 to 90 % by weight of repeating units derived from a polymerizable compound having a C4-C20 perfluoroalkyl group, (b) 5 to 50 % by weight of repeating units derived from at least one unsaturated ester selected from the group consisting of stearyl acrylate and stearyl methacrylate, (c) 5 to 50 % by weight of repeating units derived from at least one monomer selected from the group consisting of alkyl acrylate and alkyl methacrylate having 2 to 8 carbon atoms in the alkyl group, which is useful as an active component of a water- and oil-repellent.

Inventors

  • 👤 Yoshio Amimoto
  • 👤 Masayoshi Shinjo
  • 👤 Takashi Enomoto
  • 👤 Kazunori Hayashi

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-04 07:12
CPC Classifications
C; C08; C08F; C08F220/00; C08F220/02; C08F220/10; C08F220/22; C08F220/24; D; D06; D06M; D06M15/00; D06M15/19; D06M15/21; D06M15/263; D06M15/277

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 89 words
A fluorine-containing copolymer comprising (a) 40 to 90 % by weight of repeating units deri­ved from a polymerizable compound having a C₄-C₂₀ perfluoro­alkyl group, (b) 5 to 50 % by weight of repeating units derived from at least one unsaturated ester selected from the group consisting of stearyl acrylate and stearyl methacrylate, (c) 5 to 50 % by weight of repeating units derived from at least one monomer selected from the group consisting of alkyl acrylate and alkyl methacrylate having 2 to 8 car­bon atoms in the alkyl group.
Claim 2
Dependent Claim 89 words
A fluorine-containing copolymer comprising (a) 40 to 90 % by weight of repeating units deri­ved from a polymerizable compound having a C₄-C₂₀ perfluoro­alkyl group, (b) 5 to 50 % by weight of repeating units derived from at least one unsaturated ester selected from the group consisting of stearyl acrylate and stearyl methacrylate, (c) 5 to 50 % by weight of repeating units derived from at least one monomer selected from the group consisting of alkyl acrylate and alkyl methacrylate having 2 to 8 car­bon atoms in the alkyl group.
Claim 3
Dependent Claim 58 words
The fluorine-containing copolymer according to claim 1, which further comprises 0.1 to 5 % by weight of (d) repeating units derived from an acrylate or methacrylate having at least one nitrogen atom or (e) repeating units derived from an acrylate and methacrylate having at least one hydroxyl group or (f) repeating units derived from gly­cidyl acrylate or methacrylate.
Claim 4
Dependent Claim 65 words
The fluorine-containing copolymer according to claim 1, which further comprises 0.1 to 5 % by weight of (d) repeating units derived from an acrylate or methacrylate having at least one nitrogen atom, and 0.1 to 5 % by weight of (e) repeating units derived from an acrylate and meth­acrylate having at least one hydroxyl group or (f) repeating units derived from glycidyl acrylate or methacrylate.
Claim 5
Dependent Claim 49 words
The fluorine-containing copolymer according to claim 1, which further comprises 0.1 to 5 % by weigh of (e) repeating units derived from an acrylate and methacrylate having at least one hydroxyl group and 0.1 to 5 % by weight of (f) repeating units derived from glycidyl acrylate or methacrylate.
Claim 6
Dependent Claim 71 words
The fluorine-containing copolymer according to claim 1, which further comprises 0.1 to 5 % by weight of (d) repeating units derived from an acrylate or methacrylate having at least one nitrogen atom, 0.1 to 5 % by weight of (e) repeating units derived from an acrylate and methacry­late having at least one hydroxyl group and 0.1 to 5 % by weight of (f) repeating units derived from glycidyl acrylate or methacrylate.
Claim 7
Dependent Claim 95 words
A water- and oil-repellent comprising a fluo­rine-containing copolymer which comprises (a) 40 to 90 % by weight of repeating units deri­ved from a polymerizable compound having a C₄-C₂₀ perfluoro­alkyl group, (b) 5 to 50 % by weight of repeating units derived from at least one unsaturated ester selected from the group consisting of stearyl acrylate and stearyl methacrylate, (c) 5 to 50 % by weight of repeating units derived from at least one monomer selected from the group consisting of alkyl acrylate and alkyl methacrylate having 2 to 8 car­bon atoms in the alkyl group.
Claim 8
Dependent Claim 95 words
A water- and oil-repellent comprising a fluo­rine-containing copolymer which comprises (a) 40 to 90 % by weight of repeating units deri­ved from a polymerizable compound having a C₄-C₂₀ perfluoro­alkyl group, (b) 5 to 50 % by weight of repeating units derived from at least one unsaturated ester selected from the group consisting of stearyl acrylate and stearyl methacrylate, (c) 5 to 50 % by weight of repeating units derived from at least one monomer selected from the group consisting of alkyl acrylate and alkyl methacrylate having 2 to 8 car­bon atoms in the alkyl group.
Claim 9
Dependent Claim 61 words
The water- and oil-repellent according to claim 6, wherein the copolymer further comprises 0.1 to 5 % by weight of (d) repeating units derived from an acrylate or methacrylate having at least one nitrogen atom or (e) repea­ting units derived from an acrylate and methacrylate having at least one hydroxyl group or (f) repeating units derived from glycidyl acrylate or methacrylate.
Claim 10
Dependent Claim 68 words
The water- and oil-repellent according to claim 6, wherein the copolymer further comprises 0.1 to 5 % by weight of (d) repeating units derived from an acrylate or methacrylate having at least one nitrogen atom, and 0.1 to 5 % by weight of (e) repeating units derived from an acrylate and methacrylate having at least one hydroxyl group or (f) repeating units derived from glycidyl acrylate or methacry­late.
Claim 11
Dependent Claim 52 words
The water- and oil-repellent according to claim 6, wherein the copolymer further comprises 0.1 to 5 % by weigh of (e) repeating units derived from an acrylate and methacrylate having at least one hydroxyl group and 0.1 to 5 % by weight of (f) repeating units derived from glycidyl acrylate or methacrylate.
Claim 12
Dependent Claim 74 words
The water- and oil-repellent according to claim 6, wherein the copolymer further comprises 0.1 to 5 % by weight of (d) repeating units derived from an acrylate or methacrylate having at least one nitrogen atom, 0.1 to 5 % by weight of (e) repeating units derived from an acrylate and methacrylate having at least one hydroxyl group and 0.1 to 5 % by weight of (f) repeating units derived from glyci­dyl acrylate or methacrylate.

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