Light-sensitive silver halide photographic material

Claim 1

A silver halide photographic light-sensitive material comprising a support having thereon a photographic constituent layer including at least one silver halide emulsion layer, wherein said silver halide emulsion layer contains silver halide grains of which the silver chloride content is not less than 90 mole%, and said photographic constituent layer con­tains at least one first compound selected from organic com­pounds capable of forming a compound having a solubility product Ksp of not more than 1x10⁻¹¹ with a silver ion, and at least one second compound selected from the group consisting of the compounds having the following Formula I, II, III or IV: wherein R₁ represents a hydrogen atom, an alkyl group or an aryl group; R₂ represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group, a nitro group, a carboxy group, a sulfo group, a sulfamoyl group, a hydroxy group, an alkoxy group or a thiazolyl group; Z₁ represents a group of non-metal atoms necessary to complete a thiazoline ring, wherein R₃ and R₄ each independently represents an alkyl group, an aryl group, in which R, R′ and R˝ each independently represents an alkyl group or an aryl group, and R₃ and R₄ may be combined to form a ring together with the nitrogen atom; and R₅, R₆ and R₇ each independently represents a halogen atom or an alkyl group, wherein R₈ and R₉ each independently represents a hydrogen atom, an alkyl group, an aryl group or a nitrogen-containing heterocyclic group, wherein R₁₀ represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, an aryl group, a hetero­cyclic group, an alkylaminocarbonyl group, an arylaminocar­bonyl group, an alkylaminosulfonyl group or an arylamino­sulfonyl group; R₁₁ and R₁₂ each independently represents a hydrogen atom, a halogen atom, an alkyl group, a cycloalkyl group, an aryl group, a cyano group, an alkylthio group, an arylthio group, an alkylsulfonyl group, an alkylsulfonyloxy group or a heterocyclic group, provided that the R₁₁ and R₁₂ may be combined with each other to form a ring.