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EP0286219A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Opaque ink composition containing hollow microspheres for use in ink jet printing

Assignee: Videojet Technologies Inc
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Filing: 1988-02-26
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Granted: —
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Expires: 2008-02-26
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Abstract

Abstract A non-pigmented ink suitable for use in jet printing is disclosed. The ink comprises a resin component, hollow microspheres, and a suitable carrier vehicle. The hollow microspheres contain a central void region filled with a liquid capable of diffusing through the walls of said microspheres and have an inside diameter from about 0.1 to about 0.5 micron and an outside diameter from about 0.4 to about 1 micron.

Inventors

  • 👤 Adrian Loria
  • 👤 Josephine Aguilar

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-25 15:10
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/30

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 144 words
A non-pigmented ink suitable for use in ink jet printing comprising: (a) from about 2 to about 20 percent by weight of a resin component; (b) from about 5 to about 25 percent by weight of hollow microspheres; and (c) the remainder being a suitable carrier vehicle, all percentages being based upon the total weight of the ink; the hollow microspheres having permeable walls comprised of a synthetic polymeric material, a central void region filled with a liquid capable of diffusing through the walls of said microspheres, an inside diameter from about 0.1 to about 0.5 micron and an outside diameter from about 0.4 to about 1 micron; the resin component, the hollow microspheres and the carrier vehicle being chemically non-reactive with each other; and the specific gravity of the ink being about equal to or greater than the specific gravity of the microspheres.
Claim 2
Dependent Claim 144 words
A non-pigmented ink suitable for use in ink jet printing comprising: (a) from about 2 to about 20 percent by weight of a resin component; (b) from about 5 to about 25 percent by weight of hollow microspheres; and (c) the remainder being a suitable carrier vehicle, all percentages being based upon the total weight of the ink; the hollow microspheres having permeable walls comprised of a synthetic polymeric material, a central void region filled with a liquid capable of diffusing through the walls of said microspheres, an inside diameter from about 0.1 to about 0.5 micron and an outside diameter from about 0.4 to about 1 micron; the resin component, the hollow microspheres and the carrier vehicle being chemically non-reactive with each other; and the specific gravity of the ink being about equal to or greater than the specific gravity of the microspheres.
Claim 3
Dependent Claim 18 words
An ink according to claim 1, wherein the carrier vehicle comprises water, ammonium hydroxide, and a volatile solvent.
Claim 4
Dependent Claim 35 words
An ink according to claim 2, wherein the volatile slvent is a lower alkanol and is present in an amount from about 1 to about 20 percent, based on the total weight of the ink.
Claim 5
Dependent Claim 37 words
An ink according to any one of claims 1 to 3, wherein the hollow microspheres have an inside diameter from about 0.2 to about 0.4 micron and an outside diameter from about 0.5 to about 0.7 micron.
Claim 6
Dependent Claim 18 words
An ink according to any preceding claim, wherein the hollow microspheres have walls comprised of an acrylic/styrene copolymer.
Claim 7
Dependent Claim 14 words
An ink according to any preceding claim, wherein the resin is an acrylic/styrene copolymer.
Claim 8
Dependent Claim 43 words
An ink according to any preceding claim, wherein the ink has a viscosity at 25°C from about 3 to about 6 centipoise, an electrical resistivity from about 100 to about 1000 ohm-cm, and a sonic velocity from about 1500 to about 1700 metres/sec.
Claim 9
Dependent Claim 17 words
An ink according to any preceding claim, wherein the pH is from about 7 to about 9.
Claim 10
Dependent Claim 12 words
An ink according to any preceding claim, also comprising a coalescent agent.
Claim 11
Dependent Claim 21 words
An ink according to claim 9, wherein the coalescent agent is selected from the group consisting of carbitol and glycol ethers.
Claim 12
Dependent Claim 15 words
An ink according to any preceding claim, also comprising a plasticizer and a defoaming agent.
Claim 13
Dependent Claim 35 words
An ink according to any preceding claim, wherein the hollow microspheres have permeable walls comprised of a polymer selected from the group consisting of 2-ethylhexyacrylate, methyl methacrylate and copolymers of styrene and a vinyl monomer.
Claim 14
Dependent Claim 31 words
An ink according to any preceding claim, wherein the microspheres have an inside diameter of about 0.3 micron and an outside diameter of about 0.5 micron and are filled with water.

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