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EP0284441A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

II-VI Group compound crystal article and process for producing the same

Assignee: Canon Inc
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Filing: 1988-03-28
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Granted: —
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Expires: 2008-03-28
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Abstract

Abstract A II-VI group compound crystal article comprises a substrate having a non-nucleation surface with smaller nucleation density (S NDS ) and a nucleation surface (S NDL ) which is arranged adjacent to said non-nucleation surface (S NDS ), has a sufficiently small area for a crystal to grow only from a single nucleus and a larger nucleation density (ND L ) than the nucleation density (ND S ) of said non-­nucleation surface (S NDS ) and is comprised of an amorphous material, and a II-VI group compound monocrystal grown from said single nucleus on said substrate and spread on said non-nucleation surface (S NDS ) beyond said nucleation surface (S NDL ).

Inventors

  • 👤 Hiroyuki Tokunaga
  • 👤 Takao Yonehara

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-05 18:49
CPC Classifications
C; C30; C30B; C30B25/00; C30B25/02; C30B25/18; C30B29/00; C30B29/10; C30B29/46; C30B29/48; H; H10; H10P; H10P14/00; H10P14/20; H10P14/24; H10P14/27; H10P14/271; H10P14/276; H10P14/29; H10P14/2901; H10P14/2921; H10P14/2922; H10P14/34; H10P14/3402; H10P14/3424; H10P14/3426; H10P14/3428; H10P14/3431; Y; Y10; Y10S; Y10S117/00; Y10S117/901; Y10S117/902; Y10S117/913; Y10S148/00; Y10S148/064

Claims Analysis

Total Claims: 36
Claim 1
Independent Claim 112 words
A II-VI group compound crystal article comprising a substrate having a non-nucleation surface with smaller nucleation density (S NDS ) and a nucleation surface (S NDL ) which is arranged adjacent to said non-nucleation surface (S NDS ), has a sufficiently small area for a crystal to grow only from a single nucleus and a larger nucleation density (ND L ) than the nucleation density (ND S ) of said non-­nucleation surface (S NDS ) and is comprised of an amorphous material, and a II-VI group compound monocrystal grown from said single nucleus on said substrate and spread on said non-nucleation surface (S NDS ) beyond said nucleation surface (S NDL ).
Claim 2
Dependent Claim 112 words
A II-VI group compound crystal article comprising a substrate having a non-nucleation surface with smaller nucleation density (S NDS ) and a nucleation surface (S NDL ) which is arranged adjacent to said non-nucleation surface (S NDS ), has a sufficiently small area for a crystal to grow only from a single nucleus and a larger nucleation density (ND L ) than the nucleation density (ND S ) of said non-­nucleation surface (S NDS ) and is comprised of an amorphous material, and a II-VI group compound monocrystal grown from said single nucleus on said substrate and spread on said non-nucleation surface (S NDS ) beyond said nucleation surface (S NDL ).
Claim 3
Dependent Claim 23 words
A II-VI group compound crystal article according to claim 1, wherein said nucleation surface (S NDL ) is arranged in a plural number.
Claim 4
Dependent Claim 25 words
A II-VI group compound crystal article according to claim 1, wherein said nucleation surface (S NDL ) is arranged in a plural number as sectionalized.
Claim 5
Dependent Claim 33 words
A II-VI group compound crystal article according to claim 1, wherein said nucleation surface (S NDL ) is arranged in a plural number as sectionalized regularly within the non-nucleation surface (S NDS ).
Claim 6
Dependent Claim 33 words
A II-VI group compound crystal article according to claim 1, wherein said nucleation surface (S NDL ) is arranged in a plural number as sectionalized irregularly within the non-nucleation surface (S NDS ).
Claim 7
Dependent Claim 36 words
A II-VI group compound crystal article according to claim 2, wherein the monocrystals grown respectively from said nucleation surfaces (S NDL ) are adjacent to the monocrystals grown from the adjoining nucleation surfaces (S NDL ).
Claim 8
Dependent Claim 37 words
A II-VI group compound crystal article according to claim 2, wherein the monocrystals grown respectively from said nucleation surfaces (S NDL ) are spatially apart from the monocrystals grown from the adjoining nucleation surfaces (S NDL ).
Claim 9
Dependent Claim 45 words
A II-VI group compound crystal article according to claim 1, wherein said nucleation surface (S NDL ) is formed on the bottom surface of a recess provided in said non-nucleation surface (S NDS ), and said monocrystal is formed so as to fill said recess
Claim 10
Dependent Claim 21 words
A II-VI group compound crystal article according to claim 1, wherein said non-nucleation surface (S NDL ) comprises an amorphous material.
Claim 11
Dependent Claim 16 words
A II-VI group compound crystal article accrding to claim 9, wherein said amorphous material is SiO₂.
Claim 12
Dependent Claim 24 words
A II-VI group compound crystal article according to claim 1, wherein said II-VI group compound semiconductor is a binary system II-VI group compound semiconductor.
Claim 13
Dependent Claim 24 words
A II-VI group compound crystal article according to claim 1, wherein said II-VI group compound semiconductor is a mixed crystal II-VI group compound semiconductor.
Claim 14
Dependent Claim 117 words
A process for forming a II-VI group compound crystal, which comprises applying, in a gas phase including a starting material for supplying Group II atoms and a starting material for supplying Group VI atoms, crystal forming treatment on a substrate having a free surface comprising a non-­nucleation surface (S NDS ) with smaller nucleation density and a nucleation surface (SNDL) arranged adjacent thereto having a sufficiently small area for a crystal to grow only from a single nucleus and a larger nucleation density (ND L ) than the nucleation density (ND S ) of said non-nucleation surface (S NDS ) and comprised of an amorphous material, thereby growing a II-VI group compound monocrystal from said single nucleus.
Claim 15
Dependent Claim 117 words
A process for forming a II-VI group compound crystal, which comprises applying, in a gas phase including a starting material for supplying Group II atoms and a starting material for supplying Group VI atoms, crystal forming treatment on a substrate having a free surface comprising a non-­nucleation surface (S NDS ) with smaller nucleation density and a nucleation surface (SNDL) arranged adjacent thereto having a sufficiently small area for a crystal to grow only from a single nucleus and a larger nucleation density (ND L ) than the nucleation density (ND S ) of said non-nucleation surface (S NDS ) and comprised of an amorphous material, thereby growing a II-VI group compound monocrystal from said single nucleus.
Claim 16
Dependent Claim 139 words
A process for forming a II-VI group compound crystal, which comprises forming with an amorphous material, in a gas phase including a starting material for supplying Group II atoms and a starting material for supplying Group VI atoms, on a substrate having a non-nucleation surface (S NDS ) with smaller nucleation density at a desired position of said non-nucleation surface (S NDS ) , a nucleation surface (S NDL ) having a larger nucleation density (ND L ) than the nucleation density (ND S ) of said non-­nucleation surface (S NDS ) and a sufficiently small area for a crystal to grow only from a single nucleus and then applying crystal forming treatment on said substrate to form a single nucleus on said nucleation surface (S NDL ) to grow a II-VI group compound monocrystal from said single nucleus.
Claim 17
Dependent Claim 139 words
A process for forming a II-VI group compound crystal, which comprises forming with an amorphous material, in a gas phase including a starting material for supplying Group II atoms and a starting material for supplying Group VI atoms, on a substrate having a non-nucleation surface (S NDS ) with smaller nucleation density at a desired position of said non-nucleation surface (S NDS ) , a nucleation surface (S NDL ) having a larger nucleation density (ND L ) than the nucleation density (ND S ) of said non-­nucleation surface (S NDS ) and a sufficiently small area for a crystal to grow only from a single nucleus and then applying crystal forming treatment on said substrate to form a single nucleus on said nucleation surface (S NDL ) to grow a II-VI group compound monocrystal from said single nucleus.
Claim 18
Dependent Claim 30 words
A process for forming a II-VI group compound crystal according to claim 14, wherein said nucleation surface (S NDL ) is formed internally of said non-nucleation surface (S NDS ).
Claim 19
Dependent Claim 32 words
A process for forming a II-VI group compound crystal according to claim 14, wherein said nucleation surface (S NDL ) is formed on the face of said non-nucleation surface (S NDS ).
Claim 20
Dependent Claim 28 words
A process for forming a II-VI group compound crystal according to claim 15, wherein said nucleation surface (S NDL ) is formed in a plural number as sectionalized.
Claim 21
Dependent Claim 29 words
A process for forming a II-VI group compound crystal according to claim 15, wherein said nucleation surface (S NDL ) is formed in a plural number as sectionalized regularly.
Claim 22
Dependent Claim 29 words
A process for forming a II-VI group compound crystal according to claim 15, wherein said nucleation surface (S NDL ) is formed in a plural number as sectionalized irregularly.
Claim 23
Dependent Claim 27 words
A process for forming a II-VI group compound crystal according to claim 15, wherein said nucleation surface (S NDL ) is formed in shape of a lattice.
Claim 24
Dependent Claim 40 words
A process for forming a II-VI group compound crystal according to claim 14, wherein said nucleation surface (S NDL ) is formed in a plural number as sectionalized, and monocrystals are formed from said nucleation surfaces (S NDL ), respectively.
Claim 25
Dependent Claim 46 words
A process for forming a II-VI group compound crystal according to claim 21, wherein the monocrystals grown from the above respective nucleation surfaces (S NDL ) are grown in the directions of the respective nucleation surfaces (S NDL ) beyond said nucleation surfaces (S NDL ).
Claim 26
Dependent Claim 40 words
A process for forming a II-VI group compound crystal according to claim 21, wherein the monocrystals grown from the respective nucleation surfaces (S NDL ) are grown to the sizes to be adjacent to adjoining nucleation surfaces (S NDL ).
Claim 27
Dependent Claim 39 words
A process for forming a II-VI group compound crystal according to claim 14, wherein said nucleation surface (S NDL ) is formed of a material which is modified from the material for forming said non-nucleation surface (S NDS ).
Claim 28
Dependent Claim 27 words
A process for forming a II-VI group compound crystal according to claim 14, wherein said nucleation surface (S NDL ) is formed by the ion implantation method.
Claim 29
Dependent Claim 54 words
A process for forming a II-VI group compound crystal according to claim 14, wherein said nucleation surface (S NDL ) is formed by depositing a material having sufficiently larger nucleation density than the material for forming said non-nucleation surface (S NDS ) on said non-nucleation surface (S NDS ), followed by sufficiently fine patterning.
Claim 30
Dependent Claim 76 words
A process for forming a II-VI group compound crystal according to claim 14, wherein said non-nucleation surface (S NDS ) is formed so as to cover over the surface comprising the material constituting said nucleation surface (S NDL ) and the desired portion of said non-nucleation surface (S NDS ), is removed thereby having exposed a nucleation surface (S NDL ) with a suficiently small area for a crystal to grow only from a single nucleus.
Claim 31
Dependent Claim 22 words
A process for forming a II-VI group compound crystal according to claim 14, wherein said substrate is constituted of an amorphous material.
Claim 32
Dependent Claim 19 words
A process for forming a II-VI group compound crystal according to claim 28, wherein said amorphous material is SiO₂.
Claim 33
Dependent Claim 25 words
A process for forming a II-VI group compound crystal according to claim 14, wherein said II-VI group compound is a binary system II-VI group compound.
Claim 34
Dependent Claim 25 words
A process for forming a II-VI group compound crystal according to claim 14, wherein said II-VI group compound is a mixed crystal II-VI group compound.
Claim 35
Dependent Claim 22 words
A process for forming a II-VI group compound crystal according to claim 30, wherein said crystal forming treatment is the MOCVD method.
Claim 36
Dependent Claim 35 words
A process for forming a II-VI group compound crystal according to claim 14, wherein the group II element of the II-VI group compound is replaced by the group I element and the group III element.

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