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EP0279554A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Solid state cell electrolyte

Assignee: Dowty Electronic Components Ltd
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Filing: 1988-02-02
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Granted: —
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Expires: 2008-02-02
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Abstract

Abstract A solid polymer electrolyte for a solid state electro­chemical cell comprises a complex of a solid polymer such as poly(ethene oxide) and an alkali metal salt such as LiClO₄, which polymer is capable of forming donor:­acceptor type bonds with alkali metal ions and is capable of conducting alkali metal ions, the complex being associated with a mixture of more than one 1,3-dioxolane-­2-ones, for example ethylene carbonate and propylene carbonate, such that the electrolyte possesses satisfactory ambient temperature ionic conductivity (eg 10⁻³ to 10⁻⁴ ohm⁻¹ cm⁻¹) and a cell including the electrolyte substantially maintains its discharge capacity at ambient temperature after repeated charge/discharge cycling.

Inventors

  • 👤 John Malcolm North

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-30 09:21
CPC Classifications
H; H01; H01M; H01M10/00; H01M10/05; H01M10/052; H01M10/056; H01M10/0564; H01M10/0565; H01M6/00; H01M6/14; H01M6/16; H01M6/162; H01M6/164; Y; Y02; Y02E; Y02E60/00; Y02E60/10

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 55 words
A solid polymer electrolyte comprising a complex of a solid polymer and an alkali metal salt, which polymer is capable of forming donor-acceptor type bonds with alkali metal ions and is capable of conducting alkali metal ions, characterised in that the complex is associated with a mixture of more than one substituted or unsubstituted 1,3-dioxolane-2-ones.
Claim 2
Dependent Claim 55 words
A solid polymer electrolyte comprising a complex of a solid polymer and an alkali metal salt, which polymer is capable of forming donor-acceptor type bonds with alkali metal ions and is capable of conducting alkali metal ions, characterised in that the complex is associated with a mixture of more than one substituted or unsubstituted 1,3-dioxolane-2-ones.
Claim 3
Dependent Claim 17 words
A solid polymer electrolyte according to claim 1 wherein the mixture comprises ethylene carbonate and propylene carbonate.
Claim 4
Dependent Claim 21 words
A solid polymer electrolyte according to claim 1 or claim 2 wherein the solid polymer is poly(ethene oxide) or poly(propene oxide).
Claim 5
Dependent Claim 17 words
A solid polymer electrolyte according to any of the preceding claims wherein the alkali metal is lithium.
Claim 6
Dependent Claim 70 words
A solid polymer electrolyte according to claim 4 wherein the molar ratios of the constituents therein are represented by the general formula (I) below: [PEO a : [xEC : yPC] b ] n : LiX      (I) where PEO represents poly(ethene oxide) EC represents ethylene carbonate PC represents propylene carbonate and each of a, b, x, y and n is finite and represents a molar quantity, and X is an anion.
Claim 7
Dependent Claim 49 words
A solid polymer electrolyte according to claim 5 wherein the molar ratios of the constituents therein are represented by the formula (II) below: [PEO : [2EC : 2PC]] ₂₀ : LiClO₄      (II) where PEO, EC and PC are defined as in claim 5 and the numbers represent molar quantities.
Claim 8
Dependent Claim 26 words
A solid polymer electrolyte according to any of the preceding claims wherein the electrolyte is in association with an electrode material to form a composite cathode.
Claim 9
Dependent Claim 17 words
A solid polymer electrolyte according to claim 7 wherein the electrode material is an insertion electrode material.
Claim 10
Dependent Claim 18 words
A solid polymer electrolyte according to claim 8 wherein the insertion electrode material is an oxide of vanadium.
Claim 11
Dependent Claim 43 words
A solid polymer electrolyte according to any of claims 1 to 6 wherein the electrolyte is the electrolyte to a solid state electrochemical cell including an alkali metal or alkali metal-based anode and a cathode according to any of claims 7 to 9.

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