EP0279319A2
Expired / Lapsed
EP
⏱️ 0.0 years remaining
Cosmetic compositions comprising oil-in-water emulsion containing pigment
Assignee: Revlon Consumer Products LLC
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Filing: 1988-02-08
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Granted: —
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Expires: 2008-02-08
Abstract
Abstract Compositions comprising oil-in-water emulsions are disclosed comprising pigment coated with polysiloxane; a silicone phase; a water phase; and a polydiorganosiloxane-polyoxyalkylene copolymeric surfactant.
Inventors
- 👤 Hernando Brieva
- 👤 Natividad Jose
- 👤 Marlene Tietjen
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-10-25 00:23
CPC Classifications
A; A61; A61K; A61K8/00; A61K8/18; A61K8/72; A61K8/84; A61K8/89; A61K8/891; A61K8/02; A61K8/0241; A61K8/04; A61K8/06; A61K8/062; A61K8/894; A61Q; A61Q1/00; A61K2800/00; A61K2800/40; A61K2800/41; A61K2800/412; A61K2800/42; A61K2800/43; A61K2800/60; A61K2800/61; A61K2800/62; A61K2800/624
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
398 words
A cosmetic composition which is an oil-in-water emulsion comprising a) an oil phase which comprises i) a coated pigment consisting essentially of finely divided particles of pigment whose surfaces are chemically bonded to, and physically completely coated by, polysiloxane which coating renders the particles hydrophobic, and ii) a silicone component selected from a dimethyl polysiloxane having the formula (CH₃)₃SiO(Si(CH₃)₂O) d -Si(CH₃)₃ wherein the degree of polymerization d is effective to give the fluid a viscosity of 0.65 to one million centistokes at 25°C; and/or cyclomethicone having a degree (D) of polymerization of 3 to 6 repeating units of the formula -(Si(CH₃)₂O) D -; and/or organopolysiloxane having the fomula X(CH₃)₂SiO-Y-Si(CH₃)₂X wherein X is alkyl or alkoxy having 1 to 30 carbon atoms and Y is a chain of 1 to 100 repeating (Si-O) units containing 1 to 100 units of the formula (-Si(R₁)(R₂)O-) and 0 to 100 units of the formula (Si(R₃)(R₄)O) wherein each of R₁, R₂, R₃ and R₄ can be alkyl containing 2 to 30 carbon atoms, phenyl, or phenyl connected to the Si atom by a vinyl group of an alkylene bridge 1 to 3 carbon atoms long; wherein each R₁ and R₃ can also be -CH₃, and each R₁ and R₂ can also be trimethylsiloxy; and mixtures thereof; b) an aqueous phase; c) a surfactant component which comprises one or more polydiorganosiloxane-polyoxyalkylene copolymers containing at least one polydiorganosiloxane segment consisting of siloxane units having the formula: R b SiO (4-b)/2 wherein b has a value of from 0 to 3 inclusive, there being an average of approximately two R radicals per silicon in the copolymer, and R denotes a radical selected from methyl, ethyl, vinyl, phenyl or a divalent radical of 2-6 carbons bonding a polyoxyalkylene segment to the polydiorganosiloxane segment, at least 95 percent of all R radicals being methyl; and containing at least one polyoxyalkylene segment having an average molecular weight of less than 5000 and consisting of from 0 to 50 mol percent polyoxypropylene units and from 50 to 100 mol percent polyoxyethylene units, at least one terminal portion of said polyoxyalkylene segment being bonded to said polydiorganosiloxane segment, any terminal portion of said polyoxyalkylene segment not bonded to said polydiorganosiloxane segment being satisfied by a terminating radical; and wherein said surfactant component is present in an amount effective to form a stable emulsion of said oil phase in said water phase.
Claim 2
Dependent Claim
398 words
A cosmetic composition which is an oil-in-water emulsion comprising a) an oil phase which comprises i) a coated pigment consisting essentially of finely divided particles of pigment whose surfaces are chemically bonded to, and physically completely coated by, polysiloxane which coating renders the particles hydrophobic, and ii) a silicone component selected from a dimethyl polysiloxane having the formula (CH₃)₃SiO(Si(CH₃)₂O) d -Si(CH₃)₃ wherein the degree of polymerization d is effective to give the fluid a viscosity of 0.65 to one million centistokes at 25°C; and/or cyclomethicone having a degree (D) of polymerization of 3 to 6 repeating units of the formula -(Si(CH₃)₂O) D -; and/or organopolysiloxane having the fomula X(CH₃)₂SiO-Y-Si(CH₃)₂X wherein X is alkyl or alkoxy having 1 to 30 carbon atoms and Y is a chain of 1 to 100 repeating (Si-O) units containing 1 to 100 units of the formula (-Si(R₁)(R₂)O-) and 0 to 100 units of the formula (Si(R₃)(R₄)O) wherein each of R₁, R₂, R₃ and R₄ can be alkyl containing 2 to 30 carbon atoms, phenyl, or phenyl connected to the Si atom by a vinyl group of an alkylene bridge 1 to 3 carbon atoms long; wherein each R₁ and R₃ can also be -CH₃, and each R₁ and R₂ can also be trimethylsiloxy; and mixtures thereof; b) an aqueous phase; c) a surfactant component which comprises one or more polydiorganosiloxane-polyoxyalkylene copolymers containing at least one polydiorganosiloxane segment consisting of siloxane units having the formula: R b SiO (4-b)/2 wherein b has a value of from 0 to 3 inclusive, there being an average of approximately two R radicals per silicon in the copolymer, and R denotes a radical selected from methyl, ethyl, vinyl, phenyl or a divalent radical of 2-6 carbons bonding a polyoxyalkylene segment to the polydiorganosiloxane segment, at least 95 percent of all R radicals being methyl; and containing at least one polyoxyalkylene segment having an average molecular weight of less than 5000 and consisting of from 0 to 50 mol percent polyoxypropylene units and from 50 to 100 mol percent polyoxyethylene units, at least one terminal portion of said polyoxyalkylene segment being bonded to said polydiorganosiloxane segment, any terminal portion of said polyoxyalkylene segment not bonded to said polydiorganosiloxane segment being satisfied by a terminating radical; and wherein said surfactant component is present in an amount effective to form a stable emulsion of said oil phase in said water phase.
Claim 3
Dependent Claim
20 words
A composition according to claim 1 wherein the coated pigment comprises about 2 to about 40 wt% of the emulsion.
Claim 4
Dependent Claim
21 words
A composition according to claim 1 or 2 wherein the aqueous phase comprises about 25 to 80 wt% of the composition.
Claim 5
Dependent Claim
22 words
A composition according to claim 1 or 2 wherein the oil phase comprises about 10 to about 80 wt% of the composition.
Claim 6
Dependent Claim
44 words
A composition according to any of claims 1 to 4 wherein the pigment is one or more substances selected from talc, mica, titanium dioxide, ferric oxide, ferrous oxide, kaolin, ultramarine, chromium oxide, chromium hydroxide, zinc oxide, silica, manganese violet, or organic pigments or fillers.
Claim 7
Dependent Claim
23 words
A composition according to any of claims 1 to 5 which includes one or more cosmetically acceptable components dissolved in the oil phase.
Claim 8
Dependent Claim
23 words
A composition according to any of claims 1 to 6 which includes one or more cosmetically acceptable components dissolved in the aqueous phase.
Claim 9
Dependent Claim
36 words
A composition according to any of claims 1 to 7 which includes a second organic surfactant which is silicone free and wherein the surfactants are present in a combined amount effective to form a stable emulsion.
Claim 10
Dependent Claim
59 words
A composition according to any of claims 1 to 8 wherein the coated pigment has the following formula P-[-O-Si-[-(OSiA₂) 0-100 -A]₃]1-100 wherein each of the oxygen atoms at the left end of the formula is attached to an atom P in the pigment surface; and each A is an alkyl or alkenyl group having up to 30 carbon atoms.
Claim 11
Dependent Claim
34 words
A composition according to any of claims 1 to 8 wherein the coated pigment has the following formula: P-O-(Si(CH₃)₂O) p -Si(CH₃)₃ wherein p is 1-100, and P is an atom in the pigment surface.
Claim 12
Dependent Claim
52 words
A composition according to any of claims 1 to 8 wherein the coated pigment has the following formula: (CH₃)₃SiO-[Si(CH₃)(-OP)-O-Si(CH₃)(-O-P)-O-] 1-50 -Si(CH₃)₃ wherein P is an atom in the pigment surface, and in which each of the up to 100 repeating (Si-O) units is bonded through an oxygen atom to the pigment surface.
References Cited (Backward Citations)
No citation records indexed.
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