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EP0271657A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Fe-base soft magnetic alloy and method of producing same

Assignee: Proterial Ltd
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Filing: 1987-10-06
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Granted: —
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Expires: 2007-10-06
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Abstract

Abstract An Fe-base soft magnetic alloy having the composition represented by the general formula: [Fe 1-a M a ] 100-x-y-z-α-β-γ Cu x Si y B z Mʹ α Mʺ β X γ wherein M is Co and/or Ni, Mʹ is at least one element selected from the group consisting of Nb, W, Ta, Zr, Hf, Ti and Mo, M" is at least one element selected from the group consisting of V, Cr, Mn, Aℓ, elements in the platinum group, Sc, Y, rare earth elements, Au, Zn, Sn and Re, X is at least one element selected from the group consisting of C, Ge, P, Ga, Sb, In, Be and As, and a, x, y, z, α, β and γ respectively satisfy 0≦a≦0.5, 0.1≦x≦3, 0≦y≦30, 0≦z≦25, 5≦y+z≦30, 0.1≦α≦30, β≦10 and γ≦10, at least 50% of the alloy structure being fine crystalline particles having an average particle size of 1000Å or less. This alloy has low core loss, time variation of core loss, high permeability and low magnetostriction.

Inventors

  • 👤 Yoshihito Yoshizawa
  • 👤 Kiyotaka Yamauchi
  • 👤 Shigeru Oguma

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-24 17:36
CPC Classifications
C; C22; C22C; C22C38/00; C22C38/18; C22C38/40; C22C38/54; C22C45/00; C22C45/02; C21; C21D; C21D1/00; C21D1/04; H; H01; H01F; H01F1/00; H01F1/01; H01F1/03; H01F1/12; H01F1/14; H01F1/147; H01F1/153; H01F1/15308

Claims Analysis

Total Claims: 26
Claim 1
Independent Claim 82 words
An Fe-base soft magnetic alloy having the composition represented by the general formula: [Fe 1-a M a ] 100-x-y-z-α Cu x Si y B z Mʹ α wherein M is Co and/or Ni, Mʹ is at least one element selected from the group consisting of Nb, W, Ta, Zr, Hf, Ti and Mo, and a, x, y, z and α respectively satisfy 0≦a≦0.5, 0.1≦x≦3, 0≦y≦30, 0≦z≦25, 5≦y+z≦30 and 0.1≦α≦30, at least 50% of the alloy structure being occupied by fine crystalline particles.
Claim 2
Dependent Claim 82 words
An Fe-base soft magnetic alloy having the composition represented by the general formula: [Fe 1-a M a ] 100-x-y-z-α Cu x Si y B z Mʹ α wherein M is Co and/or Ni, Mʹ is at least one element selected from the group consisting of Nb, W, Ta, Zr, Hf, Ti and Mo, and a, x, y, z and α respectively satisfy 0≦a≦0.5, 0.1≦x≦3, 0≦y≦30, 0≦z≦25, 5≦y+z≦30 and 0.1≦α≦30, at least 50% of the alloy structure being occupied by fine crystalline particles.
Claim 3
Dependent Claim 58 words
The Fe-base soft magnetic alloy according to claim 1, wherein said a, x, y, z and α respectively satisfy 0≦a≦0.1, 0.1≦x≦3, 6≦y≦25, 2≦z≦25, 14≦y+z≦30 and 0.1≦α≦10, and at least 50% of the alloy structure consists of fine crystalline particles having an average particle size of 1000Å or less when measured on their maximum sizes, thus having low magnetostriction.
Claim 4
Dependent Claim 26 words
The Fe-base soft magnetic alloy according to claim 1, wherein said a, x, y, z and α respectively satisfy 0≦a≦0.1, 0.5≦x≦2, 10≦y≦25, 3≦z≦18, 18≦y+z≦28 and 2≦α≦8.
Claim 5
Dependent Claim 30 words
The Fe-base soft magnetic alloy having a low magnetostriction according to claim 3, wherein said a, x, y, z and α respectively satisfy 0≦a≦0.05, 0.5≦x≦2, 11≦y≦24, 3≦z≦9, 18≦y+z≦27 and 2≦α≦8.
Claim 6
Dependent Claim 18 words
The Fe-base soft magnetic alloy having a low magnetostriction according to claim 3, wherein said Mʹ is Nb.
Claim 7
Dependent Claim 31 words
6 . The Fe-base soft magnetic alloy having a low magnetostriction according to claim 3, wherein said crystalline particles are mainly composed of an iron solid solution having a bcc structure.
Claim 8
Dependent Claim 24 words
7 . The Fe-base soft magnetic alloy having a low magnetostriction according to claim 3, having a saturation magnetostriction λs between -5×10⁻⁶ and +5×10⁻⁶.
Claim 9
Dependent Claim 23 words
The Fe-base soft magnetic alloy according to claim 7 , wherein said saturation magnetostriction λs is in the range of -1.5×10⁻⁶ - +1.5×10⁻⁶.
Claim 10
Dependent Claim 150 words
An Fe-base soft magnetic alloy having the composition represented by the general formula: [Fe 1-a M a ] 100-x-y-z-α-β-γ Cu x Si y B z E >Mʹ α Mʺ β X γ wherein M is Co and/or Ni, Mʹ is at least one element selected from the group consisting of Nb, W, Ta, Zr, Hf, Ti and Mo, Mʺ is at least one element selected from the group consisting of V, Cr, Mn, Aℓ, elements in the platinum group, Sc, Y, rare earth elements, Au, Zn, Sn and Re, X is at least one element selected from the group consisting of C, Ge, P, Ga, Sb, In, Be and As, and a, x, y, z, α, β and γ respectively satisfy 0≦a≦0.5, 0.1≦x≦3, 0≦y≦30, 0≦z≦25, 5≦y+z≦30, 0.1≦α≦30, β≦10 and γ≦10, at least 50% of the alloy structure being fine crystalline particles having an average particle size of 1000Å or less.
Claim 11
Dependent Claim 150 words
An Fe-base soft magnetic alloy having the composition represented by the general formula: [Fe 1-a M a ] 100-x-y-z-α-β-γ Cu x Si y B z E >Mʹ α Mʺ β X γ wherein M is Co and/or Ni, Mʹ is at least one element selected from the group consisting of Nb, W, Ta, Zr, Hf, Ti and Mo, Mʺ is at least one element selected from the group consisting of V, Cr, Mn, Aℓ, elements in the platinum group, Sc, Y, rare earth elements, Au, Zn, Sn and Re, X is at least one element selected from the group consisting of C, Ge, P, Ga, Sb, In, Be and As, and a, x, y, z, α, β and γ respectively satisfy 0≦a≦0.5, 0.1≦x≦3, 0≦y≦30, 0≦z≦25, 5≦y+z≦30, 0.1≦α≦30, β≦10 and γ≦10, at least 50% of the alloy structure being fine crystalline particles having an average particle size of 1000Å or less.
Claim 12
Dependent Claim 30 words
The Fe-base soft magnetic alloy according to claim 9 , wherein said a, x, y, z, α, β and γ respectively satisfy 0≦a≦0.1, 0.1≦x≦3, 6≦y≦25, 2≦z≦25, 14≦y+z≦30, 0.1≦α≦10, β≦5 γ≦5.
Claim 13
Dependent Claim 30 words
The Fe-base soft magnetic alloy according to claim 9, wherein said a, x, y, z, α, β and γ respectively satisfy 0≦a≦0.1, 0.5≦x≦2, 10≦y≦25, 3≦z≦18, 18≦y+z≦28, 2≦α≦8, β≦5 and γ≦5.
Claim 14
Dependent Claim 31 words
The Fe-base soft magnetic alloy according to claim 9 , wherein said a, x, y, z, α, β and γ respectively satisfy 0≦a≦0.05 0.5≦x≦2, 11≦y≦24 3≦z≦9, 18≦y+z≦27, 2≦α≦8, β≦5 and γ≦5.
Claim 15
Dependent Claim 24 words
The Fe-base soft magnetic alloy according to any of the claims 1 to 12, wherein the balance of said alloy structure is substantially amorphous.
Claim 16
Dependent Claim 23 words
The Fe-base soft magnetic alloy according to any of the claims 1 to 13,wherein said alloy structure substantially consists of fine crystalline particles.
Claim 17
Dependent Claim 28 words
The Fe-base soft magnetic alloy according to any of the claims 1 to 14, wherein said crystalline particles have an average particle size of 1000 Å or less.
Claim 18
Dependent Claim 21 words
The Fe-base soft magnetic alloy according to any of the claims 9 to 15, wherein said Mʹ is Nb and/or Mo.
Claim 19
Dependent Claim 22 words
The Fe-base soft magnetic alloy according to any of the claims 9 to 16, wherein y and z satisfy 5≦y+z≦10 when 10≦α≦30.
Claim 20
Dependent Claim 20 words
The Fe-base soft magnetic alloy according to any of the claims 9 to 16, wherein y and z satisfy 0≦z/y<1.
Claim 21
Dependent Claim 23 words
The Fe-base soft magnetic alloy according to any of the claims 9 to 18, wherein X is C and y+z+γ satisfy 15≦y+z+γ≦35 (γ=0).
Claim 22
Dependent Claim 34 words
The Fe-base soft magnetic alloy according to any of the claims 1 to 19, wherein said crystalline particles have an average particle size of 500Å or less, more preferably of 200 Å or less.
Claim 23
Dependent Claim 20 words
The Fe-base soft magnetic alloy according to claim 19, wherein said crystalline particles have an average particle size of 50-200Å.
Claim 24
Independent Claim 56 words
A method of producing an Fe-base soft magnetic alloy according to any of the claims 1 to 21; comprising the steps of [a] rapidly quenching a melt of the above composition to form an amorphous alloy; and [b] heat-treating said amorphous alloy to generate fine crystalline particles having an average particle size of 1000Å or less.
Claim 25
Dependent Claim 26 words
The method according to claim 22, wherein said heat treatment is carried out by heating said amorphous alloy at 450-700°C for 5 minutes to 24 hours.
Claim 26
Dependent Claim 19 words
The method according to claim 22 or 23, wherein said heat treatment is carried out in a magnetic field.

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