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EP0267765A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Oxygen gas concentration-detecting apparatus

Assignee: Hitachi Ltd
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Filing: 1987-11-09
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Granted: —
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Expires: 2007-11-09
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Abstract

Abstract Disclosed is an oxygen gas concentration-detecting apparatus in an internal combustion engine using an alcohol fuel comprising a ceramic substrate having one surface falling in contact with a reference gas and the other surface falling in contact with an exhaust gas of the engine and generating an electromotive force according to oxygen gas concentrations of both the gases, a pair of electrode members arranged on the ceramic substrate to take out the electromotive force, a first oxidation catalyst layer formed on the outer surface of the ceramic substrate to promote oxidation reaction of unburnt components, a laminate of a protecting layer of a metal oxide and a reduction catalyst layer of promoting reduction reaction of nitrogen oxides, which laminate is formed on the outer surface of the first oxidation catalyst layer, and a second oxidation catalyst layer arranged on the outer side face of the laminate to promote oxidation reaction of hydrogen gas. According to this apparatus, hydrogen gas is oxidized in the first oxidation catalyst layer and a bad influences by the difference of the diffusion speed between hydrogen gas and oxygen gas in the protecting layer are eliminated, the time of inversion of the concentration of oxygen gas inclusive of oxygen gas generated by reduction of nitrogen oxides can be precisely detected and discharge of nitrogen oxides is controlled with omission of a so-called EGR control device.

Inventors

  • 👤 Akira Japan Electronic Uchikawa

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-25 16:52
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/26; G01N27/403; G01N27/406; G01N27/407; G01N27/4075; F; F02; F02D; F02D41/00; F02D41/02; F02D41/14; F02D41/1438; F02D41/1473; F02D41/1475

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 172 words
An oxygen concentration-detecting apparatus comprising a ceramic substrate for generating an electromotive force between a first surface contacted with a reference gas and a second surface contacted with a gas to be detected according to the ratio of the concentration of oxygen gas O₂ between said two gases, a pair of electrode members formed at parts of said first and second surfaces, respectively, of said ceramic substrate, to take out said electromotive force as a detection signal, a first oxidation catalyst layer for promoting mainly oxidation reaction of unburnt components, which is arranged to cover said second surface of said ceramic substrate and an outer surface of the electrode member on the second surface, a laminate of a protecting layer of a metal oxide covering the outer surface of said ceramic substrate and a reduction catalyst layer for promoting mainly reduction reaction of nitrogen oxides NOx, and a second oxidation catalyst layer for promoting mainly oxidation reaction of hydrogen gas H₂, which is arranged to cover an outer surface of said laminate.
Claim 2
Dependent Claim 172 words
An oxygen concentration-detecting apparatus comprising a ceramic substrate for generating an electromotive force between a first surface contacted with a reference gas and a second surface contacted with a gas to be detected according to the ratio of the concentration of oxygen gas O₂ between said two gases, a pair of electrode members formed at parts of said first and second surfaces, respectively, of said ceramic substrate, to take out said electromotive force as a detection signal, a first oxidation catalyst layer for promoting mainly oxidation reaction of unburnt components, which is arranged to cover said second surface of said ceramic substrate and an outer surface of the electrode member on the second surface, a laminate of a protecting layer of a metal oxide covering the outer surface of said ceramic substrate and a reduction catalyst layer for promoting mainly reduction reaction of nitrogen oxides NOx, and a second oxidation catalyst layer for promoting mainly oxidation reaction of hydrogen gas H₂, which is arranged to cover an outer surface of said laminate.
Claim 3
Dependent Claim 35 words
An oxygen gas concentration-detecting apparatus as set forth in claim 1, wherein said ceramic substrate is constructed by incorporating a small amount of yttria Y₂O₃ or calcia CaO into zirconia ZrO₂ and calcining the mixture.
Claim 4
Dependent Claim 25 words
An oxygen gas concentration-detecting apparatus as set forth in claim 1, wherein said ceramic substrate has a shape resembling the shape of a test tube.
Claim 5
Dependent Claim 34 words
An oxygen gas concentration-detecting apparatus as set forth in claim 1, wherein a reference stable gas is the air and the gas to be detected is an exhaust gas of an internal combustion engine.
Claim 6
Dependent Claim 48 words
An oxygen gas concentration-detecting apparatus as set forth in claim 1, wherein said ceramic substrate has a shape resembling the shape of a test tube, said first surface is an inner surface of the ceramic substrate, and said second surface is an outer surface of said ceramic substrate.
Claim 7
Dependent Claim 39 words
An oxygen gas concentration-detecting apparatus as set forth in claim 1, wherein said first oxidation catalyst layer is formed by vacuum-depositing platinum Pt on said ceramic substrate, the electrode member on the surface thereof and the outer surface threrof.
Claim 8
Dependent Claim 21 words
An oxygen gas concentration-detecting apparatus as set forth in claim 1, wherein said protecting layer is formed by flame-spraying magnesium spinel.
Claim 9
Dependent Claim 35 words
An oxygen gas concentration-detecting apparatus as set forth in claim 1, wherein said the second oxidation catalyst layer is an oxidation catalyst comprising Al₂O₃ as a carrier and platinum Pt or palladium Pd supported thereon.
Claim 10
Dependent Claim 29 words
An oxygen gas concentration-detecting apparatus as set forth in claim 1, wherein said reduction catalyst layer is a reduction catalyst layer having rhodium Rh or ruthenium Ru incorporated therein.
Claim 11
Dependent Claim 31 words
An oxygen gas concentration-detecting appratus as set forth in claim 1, wherein said reduction catalyst layer comprises a carrier of TiO₂ and rhodium Rh or ruthenium Ru incorporated in the carrier.
Claim 12
Dependent Claim 33 words
An oxygen gas concentration-detecting apparatus as set forth in claim 1, wherein said reduction catalyst layer comprises a carrier of lanthanum oxide La₂O₃ and rhodium Rh or ruthenium Ru incorporated in the carrier.
Claim 13
Dependent Claim 45 words
An oxygen gas concentration-detecting apparatus as set forth in claim 1, wherein said reduction catalyst layer is constructed by supporting particles of a reduction catalyst for promoting reduction reaction of nitrogen oxides NOx on cerium oxide and incorporating the supported particles in a porous layer.
Claim 14
Dependent Claim 26 words
An oxygen gas concentration-detecting apparatus as set forth in claim 1, wherein said reduction catalyst layer is laminated on the outer side of the protecting layer.
Claim 15
Dependent Claim 26 words
An oxygen gas concentration-detecting apparatus as set forth in claim 1, wherein said protecting layer is laminated on the outer side of the reduction catalyst layer.

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