EP0262642A2
Expired / Lapsed
EP
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Process for producing epoxyorganoalkoxysilanes
Assignee: Union Carbide Corp
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Filing: 1987-09-29
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Granted: —
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Expires: 2007-09-29
Abstract
Abstract There is disclosed a process for producing certain epoxyorganoalkoxysilanes through the rhodium catalyzed hydrosilation of ethylenically unsaturated epoxides and alkoxysilanes in the presence of nitrogenous impurities.
Inventors
- 👤 Jennifer Maryann Quirk
- 👤 Bernard Kanner
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-11-09 03:36
CPC Classifications
C; C07; C07F; C07F7/00; C07F7/02; C07F7/08; C07F7/18; C07F7/1804; C07F7/1872; C07F7/1876
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
196 words
A process for producing epoxyorganoalkoxysilanes from reactants which contain nitrogenous impurities which comprises reacting a) an ethylenically unsaturated epoxide of the formula: wherein R can be a single bond, alkylene or oxyalkylene, optionally containing alkyl pendant groups; R¹ can be hydrogen, alkyl or oxyalkyl, straight, branched or cyclic; R² and R³ can individually be hydrogen, alkyl or oxyalkyl, straight, branched or cyclic, or both R² and R³ can be either alkylene or oxyalkylene and combine together to form a 5 to 12 carbon cyclic ring, optionally containing alkyl pendants; and the number of carbon atoms in R, R¹, R² and R³ are such that the total number of carbons in the epoxide is from 4 to 50; with b) an alkoxysilane of the formula: R - S -(OR⁵) 3-x ; wherein R⁴ and R⁵ are alkyl groups individually containing from 1 to 10 carbon atoms, and x is 0, 1 or 2; in the presence of a catalytically effective amount of a rhodium catalyst; wherein at least one of said epoxide and said alkoxysilane contain nitrogenous impurities; to produce an epoxyorganoalkoxysilane of the formula: wherein R, R¹, R², R³, R⁴, R⁵ and x are as defined.
Claim 2
Dependent Claim
196 words
A process for producing epoxyorganoalkoxysilanes from reactants which contain nitrogenous impurities which comprises reacting a) an ethylenically unsaturated epoxide of the formula: wherein R can be a single bond, alkylene or oxyalkylene, optionally containing alkyl pendant groups; R¹ can be hydrogen, alkyl or oxyalkyl, straight, branched or cyclic; R² and R³ can individually be hydrogen, alkyl or oxyalkyl, straight, branched or cyclic, or both R² and R³ can be either alkylene or oxyalkylene and combine together to form a 5 to 12 carbon cyclic ring, optionally containing alkyl pendants; and the number of carbon atoms in R, R¹, R² and R³ are such that the total number of carbons in the epoxide is from 4 to 50; with b) an alkoxysilane of the formula: R - S -(OR⁵) 3-x ; wherein R⁴ and R⁵ are alkyl groups individually containing from 1 to 10 carbon atoms, and x is 0, 1 or 2; in the presence of a catalytically effective amount of a rhodium catalyst; wherein at least one of said epoxide and said alkoxysilane contain nitrogenous impurities; to produce an epoxyorganoalkoxysilane of the formula: wherein R, R¹, R², R³, R⁴, R⁵ and x are as defined.
Claim 3
Dependent Claim
16 words
The process of claim 1 wherein R⁴ and R⁵ contain from 1 to 4 carbon atoms.
Claim 4
Dependent Claim
11 words
The process of claim 1 or 2 wherein X equals 0.
Claim 5
Dependent Claim
17 words
The process of any one of claims 1 to 3 wherein the alkoxysilane is trimethoxysilane or triethoxyilane.
Claim 6
Dependent Claim
23 words
The process of any one of claims 1 to 4 wherein the number of carbon in the epoxide is from 4 to 25.
Claim 7
Dependent Claim
19 words
The process of any one of claims 1 to 5 wherein the epoxide is allyl glycidyl ether or 1,2-epoxy-4-vinylcyclohexane.
Claim 8
Dependent Claim
23 words
The process of any one of claims 1 to 6 wherein the amount of nitrogenous impurities is above about 25 parts per million.
Claim 9
Dependent Claim
19 words
The process of any one of claims 1 to 7 wherein the rhodium catalyst is optionally supported rhodium metal.
Claim 10
Dependent Claim
20 words
The process of any one of claims 1 to 8 wherein the rhodium catalyst is a soluble compound of rhodium.
Claim 11
Dependent Claim
17 words
The process of claim 9 wherein the rhodium catalyst is rhodium trichloride, rhodium (III)-2,4-pentanedionate, or dicarbonylrhodium (I)-2,4-pentanedionate.
Claim 12
Dependent Claim
21 words
The process of any one of claims 1 to 8 wherein the rhodium catalyst is a complex of rhodium with phosphines.
Claim 13
Dependent Claim
24 words
The process of claim 11 wherein the rhodium catalyst is tris(triphenylphosphine) rhodium (I) chloride, tris (triphenylphosphine) rhodium (I) carbonylhydride, or triphenylphosphinecarbonyl rhodium (I) 2.4-pentanedionate.
Claim 14
Dependent Claim
20 words
The process of any one of claims 1 to 12 wherein the catalyst is bis-(chlorodicarbonylrhodium) or 1,5-cyclooctadienerhodium (I) chloride dimer.
References Cited (Backward Citations)
No citation records indexed.
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