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EP0260038A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Polymer compositions based on linear low density polyethylene and propylene copolymer

Assignee: BP Chemicals Ltd
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Filing: 1987-08-27
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Granted: —
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Expires: 2007-08-27
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Abstract

Abstract A polymer composition comprising (a) 99 to 75 weight percent of LLDPE and (b) 1 to 25 weight percent of a copolymer of propylene (CP) with 7 to 40 weight % of one or more C₄ to C₁₂ alpha-olefins and 0 to 10 weight % of ethylene. The propylene copolymer (CP) has a fusion enthalpy not more than 75 J/g. The composition is readily converted into uniform thickness film by extrusion blowing, and exhibits good hot tack strength during heat-sealing operations.

Inventors

  • 👤 Alain Senez

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-09 09:04
CPC Classifications
C; C08; C08L; C08L23/00; C08L23/02; C08L23/04; C08L23/08; C08L23/0807; C08L23/0815; C08L23/10; C08L23/14

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 105 words
A polymer composition comprising; (a) from 99 to 75 weight percent of linear low density polyethylene having a density in the range 0.891 to 0.940, and (b) from 1 to 25 weight percent of a copolymer (CP) of propylene with 7 to 40 weight percent (based on total weight of copolymer CP) of one or more C₄ to C₁₂ alpha olefins and 0 to 10 weight percent of ethylene, the weight content of the ethylene, if any, in copolymer CP being less than the weight of the C₄ to C₁₂ alpha olefin therein, said copolymer having a fusion enthalpy of not more than 75 J/g.
Claim 2
Dependent Claim 105 words
A polymer composition comprising; (a) from 99 to 75 weight percent of linear low density polyethylene having a density in the range 0.891 to 0.940, and (b) from 1 to 25 weight percent of a copolymer (CP) of propylene with 7 to 40 weight percent (based on total weight of copolymer CP) of one or more C₄ to C₁₂ alpha olefins and 0 to 10 weight percent of ethylene, the weight content of the ethylene, if any, in copolymer CP being less than the weight of the C₄ to C₁₂ alpha olefin therein, said copolymer having a fusion enthalpy of not more than 75 J/g.
Claim 3
Dependent Claim 41 words
A composition according to claim 1 wherein the content of the linear low density polyethylene is in the range 95 to 80 weight percent, and the content of the propylene copolymer CP is in the range 5 to 20 weight percent.
Claim 4
Dependent Claim 41 words
A composition according to claim 1 characterised in that the linear low density polyethylene is obtained by copolymerisation of ethylene and at least 1 alpha olefin containing 3 to 12 carbon atoms in the presence of a Ziegler-Natta type catalytic system.
Claim 5
Dependent Claim 28 words
A composition according to claim 3 characterised in that the alpha olefin in the linear low density polyethylene is selected from propylene, 1-butene, 1-pentene, hexene-1, 4-methyl-1-pentene or 1-octene.
Claim 6
Dependent Claim 45 words
A composition according to claim 1 wherein the propylene copolymer (CP) is a copolymer of propylene and butene, a copolymer of propylene and hexene, a copolymer of propylene and 4-methyl-1-pentene, a terpolymer of propylene, 1-butene and ethylene, or a terpolymer of propylene, 4-methyl-1-pentene and ethylene.
Claim 7
Dependent Claim 26 words
A composition according to claim 1 wherein the propylene copolymer is a copolymer of propylene and 1-butene containing from 10 to 35 weight percent of 1-butene.
Claim 8
Dependent Claim 49 words
A composition according to claim 1 characterised in that the propylene copolymer (CP) is obtained by copolymerisation of a mixture of propylene and at least one alpha olefin containing 4-12 carbon atoms optionally with ethylene in the presence of a Ziegler-Natta type catalytic system adapted to polymerise propylene stereospecifically.
Claim 9
Dependent Claim 28 words
A composition according to claim 7 characterised in that the alpha olefin used to make the propylene copolymer CP is selected from 1-butene, 1-pentene, 1-hexene, 4-methyl-1-pentene or 1-octene.
Claim 10
Dependent Claim 39 words
A composition according to claim 3 or claim 7 characterised in that the low linear density polyethylene and/or the propylene copolymer are obtained by a process of copolymerisation in the gaseous phase using a fluidised and/or mechanically stirred bed.
Claim 11
Dependent Claim 23 words
A process for the preparation of a composition according to claim 1 characterised in that the constituents are mixed in the molten condition.
Claim 12
Dependent Claim 36 words
A process according to claim 10 characterised in that the mixture in the molten condition is produced from the mixture of powders or pellets of the constituents, directly in the machines for conversion into finished articles.

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