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EP0248612A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Thickeners for emulsion paints

Assignee: Akzo Nobel Decorative Coatings Ltd
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Filing: 1987-06-01
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Granted: —
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Expires: 2007-06-01
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Abstract

Abstract The thickener comprises: (a) 25 - 45% of methacrylic acid, acrylic acid or a mixture thereof; (b) 25 - 65% of alkyl acrylate such as methyl acrylate, ethyl acrylate, butyl acrylate, alkyl methacrylate such as methyl methacrylate, ethyl methacrylate, butyl methacrylate, lauryl meth­acrylate or a mixture thereof; (c) 1 - 40% of an ester of composition; in which R is a C₁₂ - C₂₅ alkyl group, n = at least 10; m = at least 5 A = H, -(CH₂CH₂O) n - R, C₁ - C₂₀ alkyl, -(CH₂CH₂O)m-H or -(CH₂CH₂O) m -CH₃ (d) 0 - 1% of a polyethylenically unsaturated monomer effective for chain branching or crosslinking such as diallyl maleate, diallyl phthalate, divinyl benzene, allyl methacrylate, ethylene glycol dimethacrylate, or trimethylol propane triacrylate.

Inventors

  • 👤 Christopher James Tonge

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-28 20:12
CPC Classifications
C; C08; C08F; C08F220/00; C08F220/02; C08F220/10; C08F220/12; C09; C09D; C09D7/00; C09D7/40; C09D7/43; C08L; C08L33/00; C08L33/02; C08L33/04

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 144 words
A thickener comprising a polymer prepared from the following components: (a) 25 - 45% of methacrylic acid, acrylic acid or a mixture thereof; (b) 25 - 65% of alkyl acrylate such as methyl acrylate, ethyl acrylate, butyl acrylate, alkyl methacrylate such as methyl methacrylate, ethyl methacrylate, butyl methacrylate, lauryl meth­acrylate or a mixture thereof; (c) 1 - 40% of an ester of composition; in which R is a C₁₂ - C₂₅ alkyl group, n = at least 10; m = at least 5 A = H, -(CH₂CH₂O) n - R, C₁ - C₂₀ alkyl, -(CH₂CH₂O)m-H or -(CH₂CH₂O) m -CH₃ (d) 0 - 1% of a polyethylenically unsaturated monomer effective for chain branching or crosslinking such as diallyl maleate, diallyl phthalate, divinyl benzene, allyl methacrylate, ethylene glycol dimethacrylate, or trimethylol propane triacrylate. The total of components (a), (b), (c) and (d) being in substance 100%.
Claim 2
Dependent Claim 144 words
A thickener comprising a polymer prepared from the following components: (a) 25 - 45% of methacrylic acid, acrylic acid or a mixture thereof; (b) 25 - 65% of alkyl acrylate such as methyl acrylate, ethyl acrylate, butyl acrylate, alkyl methacrylate such as methyl methacrylate, ethyl methacrylate, butyl methacrylate, lauryl meth­acrylate or a mixture thereof; (c) 1 - 40% of an ester of composition; in which R is a C₁₂ - C₂₅ alkyl group, n = at least 10; m = at least 5 A = H, -(CH₂CH₂O) n - R, C₁ - C₂₀ alkyl, -(CH₂CH₂O)m-H or -(CH₂CH₂O) m -CH₃ (d) 0 - 1% of a polyethylenically unsaturated monomer effective for chain branching or crosslinking such as diallyl maleate, diallyl phthalate, divinyl benzene, allyl methacrylate, ethylene glycol dimethacrylate, or trimethylol propane triacrylate. The total of components (a), (b), (c) and (d) being in substance 100%.
Claim 3
Dependent Claim 31 words
According to Claim 1 but containing not more than 10% of an ethylenically unsaturated hydrophylic monomer (e). The total of components (a), (b), (c), (d) and (e) being in substance 100%.
Claim 4
Dependent Claim 40 words
A polymer composition according to Claim 1 in which (a) is 30 - 40%, (b) is 40 - 60%, (c) is 3 - 12%, (d) is 0.05 - 0.5% and the total of (a), (b), (c) and (d) is 100%.
Claim 5
Dependent Claim 46 words
A polymer composition according to Claim 2 in which (a) is 30 - 40%, (b) is 30 - 60%, (c) is 3 - 12%, (d) is 0.05 - 0.5%, (e) is 0.5 to 10% and the total of (a), (b), (c), (d) and (e) is 100%.
Claim 6
Dependent Claim 33 words
A polymer composition according to any of the preceding claims in which the formula of (c) is determined by: A = H, n = 15-25 and R is a C₁₆ - C₂₀ alkyl.
Claim 7
Dependent Claim 10 words
A polymer composition according to either of the above examples.
Claim 8
Dependent Claim 10 words
A polymer composition according to either of the above examples.
Claim 9
Independent Claim 16 words
A method of thickening an emulsion paint utilising the composition of any of the preceding claims.
Claim 10
Dependent Claim 14 words
Emulsion paint including a thickener according to any one of claims 1 to 7.

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