EP0246602A2
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Device having a thin film of a polymer
Assignee: Kanegafuchi Chemical Industry Co Ltd
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Filing: 1987-05-19
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Granted: —
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Expires: 2007-05-19
Abstract
Abstract A thin film comprising a polymer having linear recurring units wherein an organic group R' is combined alternately with an organic group R 2 through a bivalent bonding group, wherein each of said group R' and said group R 2 has a valence of at least 2 and has at least 2 carbon atoms; each of said linear recurring units having at least one hydrocarbon-containing group R' having 10 to 30 carbon atoms bonded with covalent bond, and a device having the thin film. The thin film of the invention is formed by building-up layers of the above polymer by LB technique, and the obtained film can be subjected to ring closure and to elimination of a known LB compound added as occasion demand by heat treatment to provide a thin film having a thickness of not more than 10,000 A and excellent heat resistance, chemical resistance and mechanical properties, and the device having the thin film is useful particularly as electric and electronic devices.
Inventors
- 👤 Masakazu Uekita
- 👤 Hiroshi Awaji
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-11-02 13:02
CPC Classifications
H; H10; H10P; H10P14/00; H10P14/60; H10P14/63; H10P14/6326; H10P14/6342; H10P14/6344; B; B05; B05D; B05D1/00; B05D1/18; B05D1/20; B05D1/202; B82; B82Y; B82Y30/00; B82Y40/00; H10D; H10D64/00; H10D64/60; H10D64/66; H10D64/68; H10D64/691; H10P14/66; H10P14/668; H10P14/68; H10P14/683; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31721
Claims Analysis
Total Claims: 60
Claim 1
Independent Claim
79 words
A thin film comprising a polymer having linear recurring units wherein an organic group R 1 is combined alternately with an organic group R 2 through a bivalent bonding group, wherein each of said group R1 and said group R 2 has a valence of at least 2 and has at least 2 carbon atoms; each of said linear recurring units having at least one hydrocarbon-containing group R 3 having 10 to 30 carbon atoms bonded with covalent bond.
Claim 2
Dependent Claim
79 words
A thin film comprising a polymer having linear recurring units wherein an organic group R 1 is combined alternately with an organic group R 2 through a bivalent bonding group, wherein each of said group R1 and said group R 2 has a valence of at least 2 and has at least 2 carbon atoms; each of said linear recurring units having at least one hydrocarbon-containing group R 3 having 10 to 30 carbon atoms bonded with covalent bond.
Claim 3
Dependent Claim
14 words
The thin film of Claim 1, wherein said group R 3 has a substituent.
Claim 4
Dependent Claim
19 words
The thin film of Claim 1, wherein each of said recurring units has two said group R 3 .
Claim 5
Dependent Claim
84 words
A thin film comprising a polymer having linear recurring units wherein an organic group R 1 is combined alternately with an organic group R 2 through a bivalent bonding group, wherein each of said group R1 and said group R 2 has a valence of at least 2 and has at least 2 carbon atom; each of said linear recurring units having at least one hadrocarbon-containing group R 3 having 10 to 30 carbon atoms bonded with covalent bond, and a known Langmuir-Blodgett compound.
Claim 6
Dependent Claim
84 words
A thin film comprising a polymer having linear recurring units wherein an organic group R 1 is combined alternately with an organic group R 2 through a bivalent bonding group, wherein each of said group R1 and said group R 2 has a valence of at least 2 and has at least 2 carbon atom; each of said linear recurring units having at least one hadrocarbon-containing group R 3 having 10 to 30 carbon atoms bonded with covalent bond, and a known Langmuir-Blodgett compound.
Claim 7
Dependent Claim
14 words
The thin film of Claim 4, wherein said group R 3 has a substituent.
Claim 8
Dependent Claim
20 words
6 The thin film of Claim 4, wherein each of said recurring units has two said group R 3 .
Claim 9
Dependent Claim
31 words
The thin film of Claim 4, wherein said thin film is formed by building up layers of the mixture of said polymer and said known Langmuir-Blodgett compound according to Langmuir-Blodgett technique.
Claim 10
Dependent Claim
32 words
The thin film of Claim 1, wherein at least one said group R 1 and said group R 2 is a group characterized by benzenoid unsaturation having at least 6 carbon atoms.
Claim 11
Dependent Claim
31 words
The thin film of Claim 4, wherein at least one said group R1 and said group R 2 is a group characterized by benzenoid unsaturation having at least 6 carbon atoms.
Claim 12
Dependent Claim
51 words
The thin film of Claim 1, wherein said group R 3 is a member selected from the group consisting of an aliphatic group, a group wherein an alicyclic group is combined with an aliphatic group, a group wherein an aromatic group is combined with an aliphatic group and substituted groups thereof.
Claim 13
Dependent Claim
51 words
The thin film of Claim 4, wherein said group R 3 is a member selected from the group consisting of an aliphatic group, a group wherein an alicyclic group is combined with an aliphatic group; a group wherein an aromatic group is combined with an aliphatic group and substituted groups thereof.
Claim 14
Dependent Claim
34 words
The thin film of Claim 1, wherein each of said recurring units has a precursor structure capable of forming a 5-membered ring having a hetero atom or a 6-membered ring having a hetero atom.
Claim 15
Dependent Claim
34 words
The thin film of Claim 4, wherein each of said recurring units has a precursor structure capable of forming a 5-membered ring having a hetero atom or a 6-membered ring having a hetero atom.
Claim 16
Dependent Claim
23 words
The thin film of Claim 12, wherein said precursor structure is converted into a structure having a hetero atom-containing 5-membered or 6-membered ring.
Claim 17
Dependent Claim
23 words
The thin film of Claim 13, wherein said precursor structure is converted into a structure having a hetero atom-containing 5-membered or 6-membered ring.
Claim 18
Dependent Claim
17 words
The thin film of Claim 1, wherein said group R 3 has 16 to 22 carbon atoms.
Claim 19
Dependent Claim
17 words
The thin film of Claim 4, wherein said group R 3 has 16 to 22 carbon atoms.
Claim 20
Dependent Claim
24 words
The thin film of Claim 4, wherein said Langmuir-Blodgett compound comprises a hydrocarbon group having 16 to 22 carbon atoms and a hydrophilic group.
Claim 21
Dependent Claim
84 words
A thin film comprising a heat resistant polymer having recurring units wherein an organic group R 1 is combined alternately with an organic group R 2 through bonding groups, at least one of said bonding groups having a 5-membered or 6-membered ring structure having a hetero atom, wherein-said group R 1 has a valence of at least 3 and has at least 2 carbon atoms, and said group R 2 has a valence of at least 2 and has at least 2 carbon atoms.
Claim 22
Dependent Claim
84 words
A thin film comprising a heat resistant polymer having recurring units wherein an organic group R 1 is combined alternately with an organic group R 2 through bonding groups, at least one of said bonding groups having a 5-membered or 6-membered ring structure having a hetero atom, wherein-said group R 1 has a valence of at least 3 and has at least 2 carbon atoms, and said group R 2 has a valence of at least 2 and has at least 2 carbon atoms.
Claim 23
Dependent Claim
30 words
The thin film of Claim 19, which has a thickness of not more than 1000 A and having a dielectric strength of not less than 1 x 10 6 V/cm.
Claim 24
Dependent Claim
16 words
The thin film of Claim 19, which has a heat resistance of not less than 300°C.
Claim 25
Dependent Claim
25 words
The thin film of Claim 19, wherein said heat resistant polymer is a member selected from the group consisting of polyamide-imide, polyimide-isoindroquinazolinedione, polyimidazopyrolone and polyoxadinone.
Claim 26
Dependent Claim
172 words
A thin film which is prepared by forming a built-up film from a precursor according to Langmuir-Blodgett technique and converting the built-up film of said precursor into a polymer having a hetero atom-containing 5-membered or 6-membered ring, said precursor being a polymeric material having linear recurring units wherein an organic group R 1 is combined alternately with an organic group R 2 through a bivalent bonding group, wherein said group R 1 has a valence of at least 3 and said group R 2 has a valence of at least 2, and each of said group R 1 and said group R 2 has at least 2 carbon atoms; each of said linear recurring units having at least one hydrocarbon-containing group R 3 having 10 to 30 carbon atoms bonded with covalent bond; and each of said recurring units has a precursor structure capable of forming a 5-membered ring having a hetero atom or a 6-membered ring having a hetero atom; or a mixture of said precursor and a known Langmuir-Blodgett compound.
Claim 27
Dependent Claim
172 words
A thin film which is prepared by forming a built-up film from a precursor according to Langmuir-Blodgett technique and converting the built-up film of said precursor into a polymer having a hetero atom-containing 5-membered or 6-membered ring, said precursor being a polymeric material having linear recurring units wherein an organic group R 1 is combined alternately with an organic group R 2 through a bivalent bonding group, wherein said group R 1 has a valence of at least 3 and said group R 2 has a valence of at least 2, and each of said group R 1 and said group R 2 has at least 2 carbon atoms; each of said linear recurring units having at least one hydrocarbon-containing group R 3 having 10 to 30 carbon atoms bonded with covalent bond; and each of said recurring units has a precursor structure capable of forming a 5-membered ring having a hetero atom or a 6-membered ring having a hetero atom; or a mixture of said precursor and a known Langmuir-Blodgett compound.
Claim 28
Dependent Claim
30 words
The thin film of Claim 23, which has a thickness of not more than 1000 A and having a dielectric strength of not less than 1 x 10 6 V/cm.
Claim 29
Dependent Claim
16 words
The thin film of Claim 23, which has a heat resistance of not less than 300°C.
Claim 30
Dependent Claim
23 words
The thin film of Claim 23, wherein said polymer is a member selected from the group consisting of polyamide-imide, polyimide-isoindroquinazolinedione, polyimidazopyrolone and polyoxadinone.
Claim 31
Independent Claim
84 words
A device which has a thin film comprising a polymer having linear recurring units wherein an organic group R 1 is combined alternately with an organic group R 2 through a bivalent bonding group, wherein each of said group R 1 and said group R 2 has a valence of at least 2 and has at least 2 carbon atom; each of said linear recurring units having at least one hydrocarbon-containing group R 3 having 10 to 30 carbon atoms bonded with covalent bond.
Claim 32
Independent Claim
84 words
A device which has a thin film comprising a polymer having linear recurring units wherein an organic group R 1 is combined alternately with an organic group R 2 through a bivalent bonding group, wherein each of said group R 1 and said group R 2 has a valence of at least 2 and has at least 2 carbon atom; each of said linear recurring units having at least one hydrocarbon-containing group R 3 having 10 to 30 carbon atoms bonded with covalent bond.
Claim 33
Dependent Claim
13 words
The device of Claim 27, wherein said group R 3 has a substituent.
Claim 34
Dependent Claim
18 words
The device of Claim 27, wherein each of said recurring units has two said group R 3 .
Claim 35
Independent Claim
86 words
A device which has a thin film comprising a polymer having linear recurring units wherein an organic group R 1 is combined alternately with an organic group through a bivalent bonding group, wherein each of said group R1 and said group R 2 has a valence of at least 2 and has at least 2 carbon atoms; each of said linear recurring units having at least one hadrocarbon-containing group R 3 having 10 to 30 carbon atoms bonded with covalent bond, and a known Langmuir-Blodgett compound.
Claim 36
Independent Claim
86 words
A device which has a thin film comprising a polymer having linear recurring units wherein an organic group R 1 is combined alternately with an organic group through a bivalent bonding group, wherein each of said group R1 and said group R 2 has a valence of at least 2 and has at least 2 carbon atoms; each of said linear recurring units having at least one hadrocarbon-containing group R 3 having 10 to 30 carbon atoms bonded with covalent bond, and a known Langmuir-Blodgett compound.
Claim 37
Dependent Claim
13 words
The device of Claim 30, wherein said group R 3 has a substituent..
Claim 38
Dependent Claim
18 words
The device of Claim 30, wherein each of said recurring units has two said group R 3 .
Claim 39
Dependent Claim
28 words
The device of Claim 30, wherein said thin film is formed by building-up layers of the mixture of said polymer and said Langmuir-Blodgett compound according tr Langmuir-Blodgett technique.
Claim 40
Dependent Claim
32 words
The device of Claim 27, wherein at least one said group R 1 and said group R 2 is a group characterized by a benzenoid unsaturation having at least 6 carbon atoms.
Claim 41
Dependent Claim
30 words
The device of Claim 30, wherein at least one said group R1and said group R 2 is a group characterized by a benzenoid unsaturation having at least 6 carbon atoms.
Claim 42
Dependent Claim
50 words
The device of Claim 27, wherein said group R 3 is a member selected from the group consisting of an aliphatic group, a group wherein an alicyclic group is combined with an aliphatic group, a group wherein an aromatic group is combined with an aliphatic group and substituted groups thereof.
Claim 43
Dependent Claim
50 words
The device of Claim 30, wherein said group R 3 is a member selected from the group consisting of an aliphatic group, a group wherein an alicyclic group is combined with an aliphatic group, a group wherein an aromatic group is combined with an aliphatic group and substituted groups thereof.
Claim 44
Dependent Claim
33 words
The device of Claim 27, wherein each of said recurring units has a precursor structure capable of forming a 5-membered ring having a hetero atom or a 6-membered ring having a hetero atom.
Claim 45
Dependent Claim
33 words
The device of Claim 30, wherein each of said recurring units has a precursor structure capable of forming a 5-membered ring having a hetero atom or a 6-membered ring having a hetero atom.
Claim 46
Dependent Claim
26 words
The device of Claim 38, wherein said precursor is converted into a 5-membered ring having a hetero atom or a 6-membered ring having a hetero atom.
Claim 47
Dependent Claim
23 words
The device of Claim 39, wherein said precursor structure is converted into a structure having a hetero atom containing 5-membered or 6-membered ring.
Claim 48
Dependent Claim
15 words
The device of Claim 27, wherein said group R has 16 to 22 carbon atoms.
Claim 49
Dependent Claim
16 words
The device of Claim 30, wherein said group R 3 has 16 to 22 carbon atoms.
Claim 50
Dependent Claim
23 words
The device of Claim 30, wherein said Lanmuir-Blodgett compound comprises a hydrocarbon group having 16 to 22 carbon atoms and a hydrophilic group.
Claim 51
Independent Claim
88 words
A device which has a thin film comprising a heat resistant polymer having recurring units wherein an organic group R 1 is combined alternately with an organic group R 2 through bonding groups, at least one of said bonding groups having a 5-membered or 6-membered ring structure having a hetero atom, wherein said group R has a valence of at least 3 and has at least 2 carbon atoms, and said group R 2 has a valence of at least 2 and has at least 2 carbon atoms.
Claim 52
Independent Claim
88 words
A device which has a thin film comprising a heat resistant polymer having recurring units wherein an organic group R 1 is combined alternately with an organic group R 2 through bonding groups, at least one of said bonding groups having a 5-membered or 6-membered ring structure having a hetero atom, wherein said group R has a valence of at least 3 and has at least 2 carbon atoms, and said group R 2 has a valence of at least 2 and has at least 2 carbon atoms.
Claim 53
Dependent Claim
33 words
The device of Claim 45, wherein said thin film has a thickness of not more than 1000 A and has a dielectric strength of not less than 1 x 10 6 V/ cm.
Claim 54
Dependent Claim
18 words
The device of Claim 45, wherein said thin film has a heat resistance of not less than 300°C.
Claim 55
Dependent Claim
22 words
The device of Claim 45, wherein said polymer is a member selected from the group consisting of polyamide-imide, polyimide-isoindroquinazolinedione, polyimidazopyrolone and polyoxadinone.
Claim 56
Independent Claim
174 words
A device which has a thin film prepared by forming a built-up film from a precursor according to Langmuir-Blodgett technique and converting the built-up film of said precursor into a polymer having a hetero atom-containing 5-membered or 6-membered ring, said precursor being a polymeric material having linear recurring units wherein an organic group R 1 is combined alternately with an organic group R 2 through a bivalent bonding group, wherein said group R 1 has a valence of at least 3 and said group R 2 has a valence of at least 2, and each of said group R 1 and said group R 2 has at least 2 carbon atoms; each of said linear recurring units having at least one hydrocarbon-containing group R 3 having 10 to 30 carbon atoms bonded with covalent bond; and each of said recurring units has a precursor structure capable of forming a 5-membered ring having a hetero atom or a 6-membered ring having a hetero atom; or a mixture of said precursor and a known Langmuir-Blodgett compound.
Claim 57
Independent Claim
174 words
A device which has a thin film prepared by forming a built-up film from a precursor according to Langmuir-Blodgett technique and converting the built-up film of said precursor into a polymer having a hetero atom-containing 5-membered or 6-membered ring, said precursor being a polymeric material having linear recurring units wherein an organic group R 1 is combined alternately with an organic group R 2 through a bivalent bonding group, wherein said group R 1 has a valence of at least 3 and said group R 2 has a valence of at least 2, and each of said group R 1 and said group R 2 has at least 2 carbon atoms; each of said linear recurring units having at least one hydrocarbon-containing group R 3 having 10 to 30 carbon atoms bonded with covalent bond; and each of said recurring units has a precursor structure capable of forming a 5-membered ring having a hetero atom or a 6-membered ring having a hetero atom; or a mixture of said precursor and a known Langmuir-Blodgett compound.
Claim 58
Dependent Claim
34 words
The device of Claim 49, wherein said 0 thin film has a thickness of not more than 1000 A and has a dielectric strength of not less than 1 x 10 6 V/ cm.
Claim 59
Dependent Claim
18 words
The device of Claim 49, wherein said thin film has a heat resistance of not less than 300°C.
Claim 60
Dependent Claim
22 words
The device of Claim 49, wherein said polymer is a member selected from the group consisting of polyamide-imide, polyimide-isoindroquinazolinedione, polyimidazopyrolone and polyoxadinone.
References Cited (Backward Citations)
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