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EP0239080A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Elastomeric fibers, fibrous webs, composite elastomeric webs and an extrudable composition on the basis of ethylene-vinyl copolymers

Assignee: Kimberly Clark Corp
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Filing: 1987-03-24
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Granted: —
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Expires: 2007-03-24
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Abstract

Abstract Elastomeric melt-blown fibers comprising a copolymer of ethylene and at least one vinyl monomer selected from the group including vinyl ester monomers, unsaturated aliphatic monocarboxylic acids and alkyl esters of these monocarboxylic acids disclosed. Elastomeric nonwoven webs formed from such fibers are also disclosed.

Inventors

  • 👤 Diego H. Daponte

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-02 10:37
CPC Classifications
D; D01; D01F; D01F6/00; D01F6/44; D01F6/46; D01F6/28; D01F6/30; D04; D04H; D04H1/00; D04H1/40; D04H1/54; D04H1/56

Claims Analysis

Total Claims: 33
Claim 1
Independent Claim 28 words
Elastomeric fibers formed from a composition comprising a copolymer of ethylene and at least one vinyl monomer selected from the group including vinyl ester monomers obtainable by melt--blowing.
Claim 2
Dependent Claim 28 words
Elastomeric fibers formed from a composition comprising a copolymer of ethylene and at least one vinyl monomer selected from the group including vinyl ester monomers obtainable by melt--blowing.
Claim 3
Dependent Claim 30 words
Elastomeric fibers formed from a composition comprising a copolymer selected from the group consisting of ethylene vinyl acetate copolymer, ethylene-ethyl acrylate copolymer, ethylene-methylacrylate copolymer and ethylene-methylmethacrylate copolymer obtainable by melt-blowing.
Claim 4
Dependent Claim 30 words
Elastomeric fibers formed from a composition comprising a copolymer selected from the group consisting of ethylene vinyl acetate copolymer, ethylene-ethyl acrylate copolymer, ethylene-methylacrylate copolymer and ethylene-methylmethacrylate copolymer obtainable by melt-blowing.
Claim 5
Dependent Claim 38 words
The elastomeric fibers of claim 1, wherein said fibers are formed from a blend of at least about 10% by weight of said copolymer and from greater than 0% by weight of at least one compatible modifying polymer.
Claim 6
Dependent Claim 31 words
The elastomeric fibers of claim 3, wherein said modifying polymer is selected from the group consisting of one or more of polyethylene, polypropylene, polybutene, ethylene copolymers, propylene copolymers and butene copolymers.
Claim 7
Dependent Claim 18 words
The elastomeric fibers of claim 3 or 4, wherein said modifying polymer is a linear low density polyethylene.
Claim 8
Dependent Claim 40 words
The elastomeric fibers of claim 3 , wherein said modifying polymer is an ABA' block copolymer, where A ' and A' are each a thermoplastic polymer endblock that includes a styrenic moiety and where B is an elastomeric poly(ethylene-butene) midblock.
Claim 9
Dependent Claim 122 words
The elastomeric fibers of one of claims 3-6, wherein said fibers are formed from a blend of at least about 10% by weight to about 95% by weight of said copolymer and from at least about 5% by weight to about 90% by weight of said'modifying polymer, more preferably from a blend of at least about 20% by weight to about 95% by weight of said copolymer and from at least about 5% by weight to about 80% by weight of said modifying polymer, and most preferably from a blend of at least about 50% by weight to about 90% by weight of said copolymer and from at least about 10% by weight to about 50% by weight of said modifying polymer.
Claim 10
Dependent Claim 51 words
Elastomeric fibers formed from an ethylene-vinyl acetate copolymer having a melt index of from about 32 to about 500 grams per ten minutes, preferably from about 50 to about 200 grams per ten minutes, and most preferably from about 150 to about 200 grams per ten minutes and obtainable by melt-blowing.
Claim 11
Dependent Claim 51 words
Elastomeric fibers formed from an ethylene-vinyl acetate copolymer having a melt index of from about 32 to about 500 grams per ten minutes, preferably from about 50 to about 200 grams per ten minutes, and most preferably from about 150 to about 200 grams per ten minutes and obtainable by melt-blowing.
Claim 12
Dependent Claim 37 words
The elastomeric fibers of claim 8, wherein said ethylene-vinyl acetate copolymer comprises from about 10% by weight to about 50% by weight, preferably from about 18% by weight to about 36% by weight of vinyl acetate monomer.
Claim 13
Dependent Claim 14 words
The elastomeric fibers of one of the preceding claims, wherein said fibers are microfibers.
Claim 14
Dependent Claim 16 words
A fibrous nonwoven coherent elastomeric web comprising fibers as described in one of the preceding claims.
Claim 15
Dependent Claim 29 words
A composite elastomeric web comprising: (a) elastomeric fibers according to one of the preceding claims; and (b) at least one type of secondary fiber uniformly distributed throughout said web.
Claim 16
Dependent Claim 37 words
A composite fibrous nonwoven elastomeric web comprising: (a) elastomeric fibers according to claim 8 or 9; and (b) from greater than 0% by weight to about 80% by weight of at least one type of secondary fiber.
Claim 17
Dependent Claim 13 words
The composite elastomeric web of claim 13, wherein said elastomeric fibers are microfibers.
Claim 18
Dependent Claim 28 words
The composite elastomeric web of claim 13 or 14, wherein said secondary fiber comprises from about 30% by weight to about 70% by weight of said elastomeric web.
Claim 19
Dependent Claim 18 words
The composite elastomeric web of one of claims 13 to 15, wherein said secondary fiber comprises polyolefin fibers.
Claim 20
Dependent Claim 34 words
The composite elastomeric web of one of claims 13 to 15, wherein said secondary fiber is selected from the group consisting of wood pulp fiber, staple natural fiber, staple artificial fiber, and mixtures thereof.
Claim 21
Dependent Claim 74 words
A composite elastomeric web comprising: (a) meltblown elastomeric fibers formed from a blend of: (i) at least about 10% by weight of a copolymer of ethylene and at least one vinyl monomer selected from the group including vinyl ester monomers; and (ii) from greater than 0% by weight to about 90% by weight of at least one compatible modifying polymer, and (b) at least one type of secondary fiber uniformly distributed throughout said web.
Claim 22
Dependent Claim 74 words
A composite elastomeric web comprising: (a) meltblown elastomeric fibers formed from a blend of: (i) at least about 10% by weight of a copolymer of ethylene and at least one vinyl monomer selected from the group including vinyl ester monomers; and (ii) from greater than 0% by weight to about 90% by weight of at least one compatible modifying polymer, and (b) at least one type of secondary fiber uniformly distributed throughout said web.
Claim 23
Dependent Claim 76 words
A composite elastomeric web comprising: (a) meltblown elastomeric fibers formed from a blend of: (i) at least about 10% by weight of a copolymer selected from the group consisting of ethylene vinyl acetate copolymer, ethylene-ethyl acrylate copolymer, ethylene-methylacrylate copolymer and ethylene-methylmethacrylate copolymer; and (ii) from greater than 0% by weight to about 90% by weight of at least one compatible modifying polymer, and (b) at least one type of secondary fiber uniformly distributed throughout said web.
Claim 24
Dependent Claim 76 words
A composite elastomeric web comprising: (a) meltblown elastomeric fibers formed from a blend of: (i) at least about 10% by weight of a copolymer selected from the group consisting of ethylene vinyl acetate copolymer, ethylene-ethyl acrylate copolymer, ethylene-methylacrylate copolymer and ethylene-methylmethacrylate copolymer; and (ii) from greater than 0% by weight to about 90% by weight of at least one compatible modifying polymer, and (b) at least one type of secondary fiber uniformly distributed throughout said web.
Claim 25
Dependent Claim 76 words
A composite elastomeric web comprising: (a) meltblown elastomeric fibers formed from a blend of: (i) at least about 10% by weight of an ethylene vinyl acetate copolymer having a melt index of from about 32 to about 500 grams per ten minutes; and (ii) from greater than 0% by weight to about 90% by weight of at least one compatible modifying polymer, and (b) at least one type of secondary fiber uniformly distributed throughout said web.
Claim 26
Dependent Claim 76 words
A composite elastomeric web comprising: (a) meltblown elastomeric fibers formed from a blend of: (i) at least about 10% by weight of an ethylene vinyl acetate copolymer having a melt index of from about 32 to about 500 grams per ten minutes; and (ii) from greater than 0% by weight to about 90% by weight of at least one compatible modifying polymer, and (b) at least one type of secondary fiber uniformly distributed throughout said web.
Claim 27
Dependent Claim 28 words
The composite elastomeric web of claim 2.0 wherein said ethylene vinyl acetate copolymer has a melt index of from about 50 to about 200 grams per ten minutes.
Claim 28
Dependent Claim 35 words
The composite elastomeric web of one of claims 18 to 21, wherein said modifying polymer is at least one polymer selected from the group including polyethylene, polypropylene, polybutene, ethylene copolymers, propylene copolymers and butene copolymers.
Claim 29
Dependent Claim 45 words
The composite elastomeric web of one of claims 18 to 21, wherein said modifying polymer is at least one ABA' block copolymer, where A and A' are each a thermoplastic polymer endblock that includes a styrenic moiety and where B is an elastomeric poly(ethylene-butene) midblock.
Claim 30
Dependent Claim 65 words
The composite elastomeric web of one of claims 18 to 23, wherein said secondary fiber is present in an amount of from greater than 0% by weight to about 80% by weight, preferably in an amount of from about 30% by weight to about 70%, and most preferably in an amount of from about 50% by weight to about 70% by weight of said web.
Claim 31
Dependent Claim 34 words
The composite elastomeric web of one of claims 18 to 24, wherein said secondary fiber is selected from the group consisting of wood pulp fiber, staple natural fiber, staple artificial fiber, and mixtures thereof.
Claim 32
Dependent Claim 100 words
An extrudable composition comprising: from about 10% by weight to about 95% by weight of a copolymer of ethylene and vinyl acetate having a melt index in the range from about 32 to about 500 grams per ten minutes and from about 10% by weight to about 50% by weight of vinyl acetate, and from at least about 5% by weight to about 90% by weight of at least one other compatible modifying polymer selected from the group consisting of at least one polymer selected from the group consisting of polyethylene, polypropylene, polybutene, ethylene copolymers, propylene copolymers, and butene copolymers.
Claim 33
Dependent Claim 100 words
An extrudable composition comprising: from about 10% by weight to about 95% by weight of a copolymer of ethylene and vinyl acetate having a melt index in the range from about 32 to about 500 grams per ten minutes and from about 10% by weight to about 50% by weight of vinyl acetate, and from at least about 5% by weight to about 90% by weight of at least one other compatible modifying polymer selected from the group consisting of at least one polymer selected from the group consisting of polyethylene, polypropylene, polybutene, ethylene copolymers, propylene copolymers, and butene copolymers.

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