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EP0238024A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Depositing tungsten on a semiconductor substrate

Assignee: Fujitsu Ltd
•
Filing: 1987-03-16
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Granted: —
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Expires: 2007-03-16
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Abstract

Abstract A method of selectively depositing tungsten upon a silicon semiconductor substrate (1), on which a masking film (2) of PSG or SiO₂ is coated and patterned to provide an opening (3) for forming an electrode or wiring therein. On a portion of the substrate in the opening (3), approximately 2000 Angstroms thickness of tungsten (4) is deposited by a CVD method, in which tungsten hexafluoride gas and hydrogen gas are used and the substrate is heated. As a result of this processing, some tungsten nucleii are deposited on the surface of the masking film (2). Before the nucleii form a film, the deposition processing is discontinued and a hydrogen gas is fed in to produce hydrofluoric acid, which etches the surface of the masking film (2), thus to remove the tungsten nucleii thereon. The above-described processings, i.e. deposition and removal of tungsten, are repeated several times until the heights of the deposited tungsten (4+4ʹ+4ʺ..) and the masking film (2) become practically equal, forming a flat surface.

Inventors

  • 👤 Yoshimi Fujitsu Limited Shioya
  • 👤 Yasushi Fujitsu Limited Oyama
  • 👤 Norihisa Fujitsu Limited Tsuzuki
  • 👤 Mamoru Fujitsu Limited Maeda
  • 👤 Masaaki Fujitsu Limited Ichikawa
  • 👤 Fumitake Fujitsu Limited Mieno
  • 👤 Shin-Ichi Fujitsu Limited Inoue
  • 👤 Yasuo Fujitsu Limited Uo-Ochi
  • 👤 Akira Fujitsu Limited Tabuchi
  • 👤 Atsuhiro Fujitsu Limited Tsukune
  • 👤 Takuya Fujitsu Limited Watanabe
  • 👤 Takayuki Fujitsu Limited Ohba

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-02 13:33
CPC Classifications
H; H10; H10P; H10P14/00; H10P14/40; H10P14/42; H10P14/43; H10P14/432; H10P14/412; H10W; H10W20/00; H10W20/01; H10W20/031; H10W20/056; H10W20/057

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 60 words
A method of selectively depositing tungsten upon a semiconductor substrate, comprising the steps of: forming a patterned mask on the substrate; depositing tungsten upon a part of the substrate not covered by the patterned mask; removing tungsten deposited upon the surface of the patterned mask; and depositing further tungsten, after the removing step, upon the tungsten deposited upon the substrate.
Claim 2
Independent Claim 60 words
A method of selectively depositing tungsten upon a semiconductor substrate, comprising the steps of: forming a patterned mask on the substrate; depositing tungsten upon a part of the substrate not covered by the patterned mask; removing tungsten deposited upon the surface of the patterned mask; and depositing further tungsten, after the removing step, upon the tungsten deposited upon the substrate.
Claim 3
Dependent Claim 21 words
A method as claimed in claim 1, wherein the patterned mask is formed of a phospho-silicate glass or of silicon dioxide.
Claim 4
Dependent Claim 34 words
A method as claimed in claim 1 or 2, wherein the depositing of tungsten is carried out using a chemical vapour deposition method, using an atmosphere which contains tungsten hexafluoride gas and hydrogen gas.
Claim 5
Dependent Claim 38 words
A method as claimed in claim 1, 2 or 3, wherein the removing of tungsten deposited upon the surface of the patterned mask is carried out by heating the patterned mask in an atmosphere containing a hydrogen gas.
Claim 6
Dependent Claim 38 words
A method as claimed in claim 1, 2 or 3, wherein the removing of tungsten deposited upon the surface of the patterned mask is carried out by a wet etching in which a hydrofluoric acid solution is used.
Claim 7
Dependent Claim 43 words
A method as claimed in claim 1, 2 or 3, wherein the removing of tungsten deposited upon the surface of the patterned mask is carried out by a dry etching using an atmosphere which contains a nitrogen trifluoride gas and a hydrogen gas.

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