Patent EP0734144A2 successfully refreshed from Google Patents.
EP0230871A2
Expired / Lapsed
EP
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Haloacyl 1-substituted-1,2,3,4-tetrahydroisoquinolines as herbicide antidotes
Assignee: Monsanto Co
•
Filing: 1986-12-29
•
Granted: —
•
Expires: 2006-12-29
Abstract
Abstract Haloacyl 1-substituted-1,2,3,4-tetrahydroisoquinoline compounds are antidotes for thiocarbamate, triazine- type and acetamide herbicides. These antidote compounds are especially effective in safening acetamide herbicides used to control grassy and broadleaf weeds in corn.
Inventors
- 👤 Gerhard Horst Alt
- 👤 Harrison Ross Hakes
- 👤 Ronald Joseph Brinker
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-11-02 07:10
CPC Classifications
A; A01; A01N; A01N25/00; A01N25/32; C; C07; C07D; C07D217/00; C07D217/02; C07D217/06; C07D217/12; C07D217/14
Claims Analysis
Total Claims: 121
Claim 1
Independent Claim
70 words
A compound having the structural formula: wherein X is haloacyl; wherein each of Y,, Y 2 , Z, and Z 2 is independently selected from hydrido, alkyl, aryl and haloalkyl, with the proviso that at least one of Y, and Y 2 must be a group other than hydrido; and wherein each of R,, R 2 , R, and R 4 is independently selected from hydrido, alkyl, alkoxy and haloalkyl.
Claim 2
Dependent Claim
70 words
A compound having the structural formula: wherein X is haloacyl; wherein each of Y,, Y 2 , Z, and Z 2 is independently selected from hydrido, alkyl, aryl and haloalkyl, with the proviso that at least one of Y, and Y 2 must be a group other than hydrido; and wherein each of R,, R 2 , R, and R 4 is independently selected from hydrido, alkyl, alkoxy and haloalkyl.
Claim 3
Dependent Claim
45 words
Compound of Claim 1 wherein X is selected from monochloroacetyl, dichloroacetyl, dibromoacetyl, bromochloroacetyl, monochloropropionyl and dichloropropionyl; wherein each of Y,, Y 2 , Z, and Z 2 is independently selected from hydrido, linear of branched alkyl of one to ten carbon atoms, phenyl and perfluoroalkyl.
Claim 4
Dependent Claim
43 words
Compound of Claim 2 wherein X is selected from monochloroacetyl dichloroacetyl, 2-chloropropionyl and 2,2-dichloropropionyl; wherein each of Y,, Y 2 , Z, and Z 2 is independently selected from hydrido, linear or branched alkyl of one to five Carbon atoms, phenyl and trifluoromethyl.
Claim 5
Dependent Claim
7 words
Compound of Claim 3 which is 2-(dichloroacetyl)-1-methyl-t,2,3,4-tetrahydroisoquinoline.
Claim 6
Dependent Claim
7 words
Compound of Claim 3 which is 2-(2-chloroacetyl)-1-methyl-1,2,3,4-tetrahydroisoquinoline.
Claim 7
Dependent Claim
7 words
Compound of Claim 3 which is 2-(dichloroacetyl)-1-methyl-6,7-dimethoxy-1,2,3,4-tetrahydroisoquinoline.
Claim 8
Dependent Claim
7 words
Compound of Claim 3 which is 2-(dichloroacetyl)-i-ethyl-1,2,3,4-tetrahydroisoquinoline.
Claim 9
Dependent Claim
7 words
Compound of Claim 3 which is 2-(dichloroacetyl)-1-propyl-1,2,3,4-tetrahydroisoquinoline.
Claim 10
Dependent Claim
7 words
Compound of Claim 3 which is 2-(2-chloropropionyl)-1-methyl-1,2.3,4-tetrahydroisoquinoline.
Claim 11
Dependent Claim
7 words
Compound of Claim 3 which is 2-(2,2-dichloropropionyl)-1-methyl-1,2,3,4-tetrahydroisoquinoline.
Claim 12
Dependent Claim
7 words
Compound of Claim 3 which is 2-(dichloroacetyl)-1-(1-methylethyl)-1,2,3,4-tetrahydroisoquinoline.
Claim 13
Dependent Claim
7 words
Compound of Claim 3 which is 2-(dichloroacetyl)-1,4-dimethyl-1,2,3,4-tetrahydroisoquinoline.
Claim 14
Dependent Claim
7 words
Compound of Claim 3 which is 2-(dichloroacetyl)-1-ethyl-4-methyl-1,2,3,4-tetrahydroisoquinoline.
Claim 15
Dependent Claim
7 words
Compound of Claim 3 which is 2-(dichloroacetyl)-1-(1-methylethyl)-1,2,3,4-tetrahydroisoquinoline.
Claim 16
Dependent Claim
7 words
Compound of Claim 3 which is 2-(dichloroacetyl)-1-trifluoromethyl-1,2,3,4-tetrahydroisoquinoline.
Claim 17
Dependent Claim
7 words
Compound of Claim 3 which is 2-(dichloroacetyl)-1-phenyl-1,2,3,4-tetrahydroisoquinoline.
Claim 18
Dependent Claim
7 words
Compound of Claim 3 which is 2-(2-chloropropionyl)-1-phenyl-1,2,3,4-tetrahydroisoquinoline.
Claim 19
Dependent Claim
7 words
Compound of Claim 3 which is 2-(dichloroacetyl)-1-phenyl-4-methyl-1,2,3,4-tetrahydroisoquinoline.
Claim 20
Dependent Claim
7 words
Compound of Claim 3 which is 2-(2-chloropropionyl)-1-phenyl-4-methyl-1,2,3,4-tetrahydromethyl-1-phenylisoquinoline.
Claim 21
Dependent Claim
7 words
Compound of Claim 3 which is 2-(dichloroacetyl)-1,7-dimethyl-1,2,3,4-tetrahydroisoquinoline.
Claim 22
Dependent Claim
7 words
Compound of Claim 3 which is 2-(dichloroacetyl)-1-ethyl-7-methyl-1,2,3,4-tetrahydroisoquinoline.
Claim 23
Dependent Claim
7 words
Compound of Claim 3 which is 2-(dichloroacetyl)-1,4,4-trimethyl-1,2,3,4-tetrahydroisoquinoline.
Claim 24
Dependent Claim
7 words
Compound of Claim 3 which is 2-(dichloroacetyl)-1-(2,2-dimethylethyl)-1,2,3,4-tetrahydroisoquinoline.
Claim 25
Dependent Claim
7 words
Compound of Claim 3 which is 2-(dichloroacetyl)-1-(1,1-dimethylethyl)-1,2,3,4-tetrahydroisoquinoline.
Claim 26
Independent Claim
111 words
A method for reducing herbicide injury to a crop plant due to the application of a herbicidally-effective amount of a herbicide compound to the crop plant locus, which method comprises applying to the crop plant locus a safening-effective amount of at least one antidote compound of the formula wherein X is haloacyl; wherein each of Y,, Y 2 , Z, and Z 2 is independently selected from hydrido, alkyl, aryl and haloalkyl, with the proviso that at least one of Y, and Y 2 must be a group other than hydrido; and wherein each of R,, R 2 , R, and R, is independently selected from hydrido, alkyl, alkoxy and haloalkyl.
Claim 27
Independent Claim
111 words
A method for reducing herbicide injury to a crop plant due to the application of a herbicidally-effective amount of a herbicide compound to the crop plant locus, which method comprises applying to the crop plant locus a safening-effective amount of at least one antidote compound of the formula wherein X is haloacyl; wherein each of Y,, Y 2 , Z, and Z 2 is independently selected from hydrido, alkyl, aryl and haloalkyl, with the proviso that at least one of Y, and Y 2 must be a group other than hydrido; and wherein each of R,, R 2 , R, and R, is independently selected from hydrido, alkyl, alkoxy and haloalkyl.
Claim 28
Dependent Claim
46 words
The method of Claim 25 wherein X is selected from monochloroacetyl, dichloroacetyl, dibromoacetyl, bromochloroacetyl, monochloropropionyl and dichloropropionyl; wherein each of Y,, Y 2 , Z, and Z 2 is independently selected from hydrido, linear of branched alkyl of one to ten carbon atoms, phenyl and perfluoroalkyl.
Claim 29
Dependent Claim
44 words
The method of Claim 26 wherein X is selected from monochloroacetyl dichloroacetyl, 2-chloropropionyl and 2,2-dichloropropionyl; wherein each of Y,, Y 2 , Z, and Z 2 is independently selected from hydrido, linear or branched alkyl of one to five Carbon atoms, phenyl and trifluoromethyl.
Claim 30
Dependent Claim
11 words
The method of Claim 27 wherein said antidote compound is 2-(dichloroacetyl)-1-methyl-1,2,3,4-tetrahydroisoquinolinyl.
Claim 31
Dependent Claim
11 words
The method of Claim 27 wherein said antidote compound is 2-(2-chloropropionyl)-1-methyl-1,2,3,4-tetrahydroisoquinoline.
Claim 32
Dependent Claim
13 words
The method of Claim 27 wherein said antidote compound is ° 2-(dichloroacetyl)-1-methyl-6, 7-dimethoxy-1,2,3,4-tetrahydroisoquinoline.
Claim 33
Dependent Claim
11 words
The method of Claim 27 wherein said antidote compound is 2-(dichloroacetyl)-1-ethyl-1,2,3,4-tetrahydroisoquinoline.
Claim 34
Dependent Claim
11 words
The method of Claim 27 wherein said antidote compound is 2-(dichloroacetyl)-1-propyl-1,2,3,4-tetrahydroisoquinoline.
Claim 35
Dependent Claim
11 words
The method of Claim 27 wherein said antidote compound is 2-(2-chloropropionyl)-1-methyl-1,2,3,4-tetrahydroisoquinoline.
Claim 36
Dependent Claim
11 words
The method of Claim 27 wherein said antidote compound is 2-(2,2-dichloropropionyl)-1-methyl-1,2,3,4-tetrahydroisoquinoline.
Claim 37
Dependent Claim
13 words
The method of Claim 27 wherein said antidote compound is 2-(dichloroacetyl)-1-(1-methylethyl) - 1,2,3,4-tetrahydroisoquinoline.
Claim 38
Dependent Claim
11 words
The method of Claim 27 wherein said antidote compound is 2-(dichloroacetyl)-1,4-dimethyl-1,2,3,4-tetrahydroisoquinoline,
Claim 39
Dependent Claim
11 words
The method of Claim 27 wherein said antidote compound is 2-(dichloroacetyl)-1-ethyl-4-methyl-1,2,3,4-tetrahydroisoquinoline.
Claim 40
Dependent Claim
11 words
The method of Claim 27 wherein said antidote compound is 2-(dichloroacetyl)-1-ethyl-4-methyl-1,2,3,4-tetrahydroisoquinoline.
Claim 41
Dependent Claim
11 words
The method of Claim 27 wherein said antidote compound is 2-(dichloroacetyl)-1-trifluoromethyl-1,2,3,4-tetrahydroisoquinoline.
Claim 42
Dependent Claim
11 words
The method of Claim 27 wherein said antidote compound is 2-(dichloroacetyl)-1-phenyl-1,2,3,4-tetrahydroisoquinoline.
Claim 43
Dependent Claim
11 words
The method of Claim 27 wherein said antidote compound is 2-(2-chloropropionyl)-1-phenyl-1,2,3,4-tetrahydroisoquinoline.
Claim 44
Dependent Claim
11 words
The method of Claim 27 wherein said antidote compound is 2-(dichloroacetyl)-1-phenyl-4-methyl-1,2,3,4-tetrahydroisoquinoline.
Claim 45
Dependent Claim
11 words
The method of Claim 27 wherein said antidote compound is 2-(2-chloropropionyl-1-phenyl-4-methyl-1,2,3,4-tetrahydromethylisoquinoline.
Claim 46
Dependent Claim
11 words
The method of Claim 27 wherein said antidote compound is 2-(dichloroacetyl)-1,7-dimethyl-1,2,3,4-tetrahydroisoquinoline.
Claim 47
Dependent Claim
11 words
The method of Claim 27 wherein said antidote compound is 2-(dichloroacetyl)-1-ethyl-7-methyl-1,2,3,4-tetrahydroisoquinoline.
Claim 48
Dependent Claim
11 words
The method of Claim 27 wherein said antidote compound is 2-(dichloroacetyl)-1,4,4-trimethyl-1,2,3,4-tetrahydroisoquinoline.
Claim 49
Dependent Claim
11 words
The method of Claim 27 wherein said antidote compound is 2-(dichloroacetyl)-1-(2,2-dimethylethyl)-1,2,3,4-tetrahydroisoquinoline.
Claim 50
Dependent Claim
11 words
The method of Claim 27 wherein said antidote compound is 2-(dichloroacetyl)-1-(1,1-dimethylethyl)-1,2.3,4-tetrahydroisoquinoiine.
Claim 51
Dependent Claim
17 words
The method of Claim 25 wherein said herbicide compound is selected from thiocarbamate, triazine, and acetamide compounds.
Claim 52
Dependent Claim
17 words
The method of Claim 49 wherein siad herbicide compound is selected from triallate, atrazine and acetamide compounds.
Claim 53
Dependent Claim
12 words
The method of Claim 50 wherin said herbicide compound is 2,3,3-trichloroallyldiisopropylthiocar- bamate.
Claim 54
Dependent Claim
11 words
The method of Claim 50 wherein said herbice compound is 2-chloro-4-ethylamino-6-isopropylamino-1,3,5-triazine.
Claim 55
Dependent Claim
14 words
The method of Claim 50 wherein said herbicide compound is an acetamide herbicide compound.
Claim 56
Dependent Claim
12 words
The method of Claim 53 wherein said acetamide herbicide compound is 2-chloro-2'6'-diethyl-N-(methoxymethyl)acetanilide.
Claim 57
Dependent Claim
13 words
The method of Claim 53 wherein said acetamide herbicide compound is 2-chloro-2',6'-diethyl-N-(butoxymethyl) acetanilide.
Claim 58
Dependent Claim
14 words
The method of Claim 53 wherein said acetamide herbicide compound is 2-chloro-N-(ethoxymethyl) - 6'-ethyl-o-acetotoluidide.
Claim 59
Dependent Claim
12 words
The method of acetamide Claim 53 wherein said herbicide compound is 2-chloro-N-(2,6-dimethylphenyl)-N-(2-methoxyethyl)acetamide.
Claim 60
Dependent Claim
12 words
The method of Claim 53 wherin said acetamide herbicide compound is 2-chloro-N-(2-methoxy-1-methylethyl)-6'-ethyl-o-acetotoluidide.
Claim 61
Dependent Claim
13 words
The method of Claim 53 wherein said acetamide herbicide compound is 2-chloro-2'-methyl-6' methoxy-n-(isopropoxymethyl)acetanilide.
Claim 62
Dependent Claim
12 words
The method of Claim 53 wherein said acetamide herbicide compound is 2-chloro-2',6'-dimethyl-N-(1-pyrazol-1-ylmethyl)acetanilide.
Claim 63
Dependent Claim
12 words
The method of Claim 53 wherein said acetamide herbicide compound is 2-chloro-2'-methyl-6'-trifluoromethyl-N-(ethoxymethyl)acetanilide.
Claim 64
Independent Claim
12 words
The method ofclaim 53 wherein said acetamide herbicide compound is 2-chloro-N-isopropyl-1-(3,5,5-trimethylcyclohexen-1-yl)acetam ide.
Claim 65
Dependent Claim
83 words
A combination comprising (a) a herbicidally effective amount of a herbicide compound a safening effective amount of an antidote compound of the formula wherein X is haloacyl; wherein each of Y,, Y 2 , Z, and Z 2 is independently selected from hydrido, alkyl, aryl and haloalkyl, with the proviso that at least one of Y, and Y2 must be a group other than hydrido; and wherein each of R R2, R, and R, is independently selected from hydrido, alkyl, alkoxy and haloalkyl.
Claim 66
Dependent Claim
83 words
A combination comprising (a) a herbicidally effective amount of a herbicide compound a safening effective amount of an antidote compound of the formula wherein X is haloacyl; wherein each of Y,, Y 2 , Z, and Z 2 is independently selected from hydrido, alkyl, aryl and haloalkyl, with the proviso that at least one of Y, and Y2 must be a group other than hydrido; and wherein each of R R2, R, and R, is independently selected from hydrido, alkyl, alkoxy and haloalkyl.
Claim 67
Dependent Claim
46 words
The combination of Claim 63 wherein X is selected from monochloroacetyl, dichloroacetyl, dibromoacetyl, bromochloroacetyl, monochloropropionyl and dichloropropionyl; wherein each of Y,, Y 2 , Z, and Z 2 is independently selected from hydrido, linear of branched alkyl of one to ten carbon atoms, phenyl and perfluoroalkyl.
Claim 68
Dependent Claim
44 words
The combination of Claim 64 wherein X is selected from monochloroacetyl dichloroacetyl, 2-chloropropionyl and 2,2-dichloropropionyl; wherein each of Y,, Y 2 , Z, and Z 2 is independently selected from hydrido, linear or branched alkyl of one to five Carbon atoms, phenyl and trifluoromethyl.
Claim 69
Dependent Claim
17 words
The combination of Claim 63 wherein said herbicide compound is selected from thiocarbamate, triazine, and acetamide compounds.
Claim 70
Dependent Claim
17 words
The combination of Claim 65 wherein siad herbicide compound is selected from triallate, atrazine and acetamide compounds.
Claim 71
Dependent Claim
12 words
The combination of Claim 67 wherein said herbicide compound is 2,3,3-trichloroallyldiisopropyl- thiocarbamate.
Claim 72
Dependent Claim
11 words
The combination of Claim 67 wherein said herbicide compound is 2-chloro-4-ethylamino-6-isopropyl-amino-1,3,5-triazine.
Claim 73
Dependent Claim
14 words
The combination of Claim 67 wherein said herbicide compound is an acetamide herbicide compound.
Claim 74
Dependent Claim
12 words
The combination of Claim 70 wherein said acetamide herbicide compound is 2-chloro-2',6'-diethyl-N-(methoxymethyl)acetanilide.
Claim 75
Dependent Claim
12 words
The combination of Claim 70 wherein said acetamide herbicide compound is 2-chloro-2',6'-diethyl-N-(butoxymethyl)acetanilide.
Claim 76
Dependent Claim
12 words
The combination of Claim 70 wherein said acetamide herbicide compound is 2-chloro-N-(ehtoxymethyl)-6'-ethyl-o-acetotoluidide.
Claim 77
Dependent Claim
12 words
The combination of Claim 70 wherein said acetamide herbicide compound is 2-chloro-N-(2,6-dimethylphenyl)-N-(2-methoxyethyl)acetamide.
Claim 78
Dependent Claim
12 words
The combination of Claim 70 wherein said acetamide herbicide compound is 2-chloro-N-(2-methoxy-1-methylethyl)-6'-ethyl-o-acetotoluidide.
Claim 79
Dependent Claim
12 words
The combination of Claim 70 wherein said acetamide herbicide compound is 2-chloro-2'-methyl-6'-methoxy-N-(isopropoxymethyl)acetanilide.
Claim 80
Dependent Claim
12 words
The combination of Claim 70 wherein said acetamide herbicide compound is 2-chloro-2',6'-dimethyl-N-(1-pyrazol-1-ylmethyl)acetanilide.
Claim 81
Dependent Claim
13 words
The combination of Claim 70 wherein said acetamide herbicide compound is 2-chloro-2'-methyl-6' trifluoromethyl-N-(ethoxymethyl)acetanilide.
Claim 82
Dependent Claim
13 words
The combination of Claim 70 wherein said acetamide herbicide compound is 2-chloro-N-isopropyl-1 -(3,5,5-trimethylcyclohexen-1-yl)acetamide.
Claim 83
Dependent Claim
11 words
The combination of Claim 65 wherein said antidote compound is 2-(2-chloropropionyl)-1-methyl-1,2,3,4-tetrahydroisoquinoline.
Claim 84
Dependent Claim
11 words
The combination of Claim 65 wherein said antidote compound is 2-(2-chloropropionyl)-1-methyl-1,2,3,4-tetrahydroisoquinoline.
Claim 85
Dependent Claim
11 words
The combination of Claim 65 wherein said antidote compound is 2-(dichloroacetyl)-1-methyl-6,7-dimethoxy-1,2,3,4-tetrahydroisoquinoline.
Claim 86
Dependent Claim
11 words
The combination of Claim 65 wherein said antidote compound is 2-(dichloroacetyl)-1-ethyl-1,2,3,4-tetrahydroisoquinoline.
Claim 87
Dependent Claim
11 words
The combination of Claim 65 wherein said antidote compound is 2-(dichloroacetyl)-1-propyl-1,2,3,4-tetrahydroisoquinoline.
Claim 88
Dependent Claim
11 words
The combination of Claim 65 wherein said antidote compound is 2-(2-chloropropionyl)-1,2,3,4-tetrahydroisoquinoline.
Claim 89
Dependent Claim
11 words
The combination of Claim 65 wherein said antidote compound is 2-(2,2-dichloropropionyl)-1-methyl-1,2,3,4-tetrahydroisoquinoline.
Claim 90
Dependent Claim
11 words
The combination of Claim 65 wherein said antidote compound is 2-(dichloroacetyl)-1-(1-methylethyl)-1,2,3,4-tetrahydroisoquinoline.
Claim 91
Dependent Claim
11 words
The combination of Claim 65 wherein said antidote compound is 2-(dichloroacetyl)-1,4-dimethyl-1,2,3,4-tetrahydroisoquinoline.
Claim 92
Dependent Claim
13 words
. 89. The combination of Claim 65 wherein said antidote compound is 2-(dichloroacetyl)-1-ethyl-4-methyl-1,2,3,4-tetrahydroisoquinoline.
Claim 93
Dependent Claim
11 words
The combination of Claim 65 wherein said antidote compound is 2-(dichloroacetyl)-1-(1-methylethyl)-1,2,3,4-tetrahydroisoquinoline.
Claim 94
Dependent Claim
11 words
The combination of Claim 65 wherein said antidote compound is 2-(dichloroacetyl)-l-trifluoromethyl-1.2,3,4-tetrahydroisoquinoline.
Claim 95
Dependent Claim
11 words
The combination of Claim 65 wherein said antidote compound is 2-(dichloroacetyl)-1-phenyl-1,2,3,4-tetrahydroisoquinoline.
Claim 96
Dependent Claim
11 words
The combination of Claim 65 wherein said antidote compound is 2-(2-chloropropionyl)-l-phenyl-1,2,3,4-tetrahydroisoquinoline.
Claim 97
Dependent Claim
11 words
The combination of Claim 65 wherein said antidote compound is 2-(dichloroacetyl)-1-phenyl-4-methyl-1,2,3,4-tetrahydroisoquinoline.
Claim 98
Dependent Claim
11 words
The combination of Claim 65 wherein said antidote compound is 2-(2-chloropropionyl)-1-phenyl-4-methyl-1,2,3,4-tetrahydroisoquinoline.
Claim 99
Dependent Claim
11 words
The combination of Claim 65 wherein said antidote compound is 2-(dichloroacetyl)-1,7-dimethyl-1-2,3,4-tetrahydroisoquinoline.
Claim 100
Dependent Claim
12 words
The combination of Claim 65 wherein said antidote compound is 2-(dichloroacetyl)-1-ethyl-7 methyl-1,2,3,4-tetrahydroisoquinoline.
Claim 101
Dependent Claim
11 words
The combination of Claim 65 wherein said antidote compound is 2-(dichloroacetyl)-1,4,4-trimethyl-1-2,3,4-tetrahydroisoquinoline.
Claim 102
Dependent Claim
11 words
The combination of Claim 65 wherein said antidote compound is 2-(dichloroacetyl)-1-(2,2-dimethylethyl)-1,2,3,4-tetrahydroisoquinoline.
Claim 103
Dependent Claim
11 words
The combination of Claim 65 wherein said antidote compound is 2-(dichloroacetyl)-1-(1,1-dimethylethyl)-1,2,3,4-tetrahydroisoquinoline.
Claim 104
Dependent Claim
6 words
A combination comprising: 2-(dichloroacetyl)-1-methyl-1,2,3,4-tetrahydroisoquinoline and 2-chloro-2',6'-diethyl-N-(methoxymethyl)-acetanilide.
Claim 105
Dependent Claim
6 words
A combination comprising: 2-(dichloroacetyl)-1-methyl-1,2,3,4-tetrahydroisoquinoline and 2-chloro-2',6'-diethyl-N-(methoxymethyl)-acetanilide.
Claim 106
Dependent Claim
8 words
A combination comprising: 2-(dichloroacetyl)-1-methyl-1,2,3,4-tetrahydroisoquinoline and 2-chloro-N-(isobutoxymethyl)-2', 6'-acetox- ylidide.
Claim 107
Dependent Claim
8 words
A combination comprising: 2-(dichloroacetyl)-1-methyl-1,2,3,4-tetrahydroisoquinoline and 2-chloro-N-(isobutoxymethyl)-2', 6'-acetox- ylidide.
Claim 108
Dependent Claim
7 words
A combination comprising: 2-(dichloroacetyl)-1-methyl-1,2,3,4-tetrahydroisoquinoline and 2-chloro-N-(ethoxymethyl)-6'-ethyl-o-ac- etotoluidide.
Claim 109
Dependent Claim
7 words
A combination comprising: 2-(dichloroacetyl)-1-methyl-1,2,3,4-tetrahydroisoquinoline and 2-chloro-N-(ethoxymethyl)-6'-ethyl-o-ac- etotoluidide.
Claim 110
Dependent Claim
6 words
A combination comprising: 2-(dichloroacetyl)-1-methyl-1,2,3,4-tetrahydroisoquinoline and 2-chloro-N-(2,6-dimethyl-phenyl)-N-(2-methoxyethyl)acetamide.
Claim 111
Dependent Claim
6 words
A combination comprising: 2-(dichloroacetyl)-1-methyl-1,2,3,4-tetrahydroisoquinoline and 2-chloro-N-(2,6-dimethyl-phenyl)-N-(2-methoxyethyl)acetamide.
Claim 112
Dependent Claim
6 words
A combination comprising: 2-(dichloroacetyl)-1-methyl-1,2,3,4-tetrahydroisoquinoline and 2-chloro-N-(2-methoxy-1-methylethyl)-6'-ethyl-Q-acetotoluidide.
Claim 113
Dependent Claim
6 words
A combination comprising: 2-(dichloroacetyl)-1-methyl-1,2,3,4-tetrahydroisoquinoline and 2-chloro-N-(2-methoxy-1-methylethyl)-6'-ethyl-Q-acetotoluidide.
Claim 114
Dependent Claim
6 words
A combination comprising: 2-(dichloroacetyl)-1-methyl-1,2,3,4-tetrahydroisoquinoline and 2-chloro-2'-methyl-6'-methoxy-N-(isopropoxymethyl)acetanilide.
Claim 115
Dependent Claim
6 words
A combination comprising: 2-(dichloroacetyl)-1-methyl-1,2,3,4-tetrahydroisoquinoline and 2-chloro-2'-methyl-6'-methoxy-N-(isopropoxymethyl)acetanilide.
Claim 116
Dependent Claim
7 words
A combination comprising: 2-(dichloroacetyl)-1-methyl-1,2,3,4-tetrahydroisoquinoline and 2-chloro-2',6'-dimethyl-N-(1-pyrazol-1-yl- methyl)acetanilide.
Claim 117
Dependent Claim
7 words
A combination comprising: 2-(dichloroacetyl)-1-methyl-1,2,3,4-tetrahydroisoquinoline and 2-chloro-2',6'-dimethyl-N-(1-pyrazol-1-yl- methyl)acetanilide.
Claim 118
Dependent Claim
6 words
A combination comprising: 2-(dichloroacetyl)-1-methyl-1,2,3,4-tetrahydroisoquinoline and 2-chloro-2'-methyl-6'-trifluoromethyl-N-(ethoxymethyl)acetanilide.
Claim 119
Dependent Claim
6 words
A combination comprising: 2-(dichloroacetyl)-1-methyl-1,2,3,4-tetrahydroisoquinoline and 2-chloro-2'-methyl-6'-trifluoromethyl-N-(ethoxymethyl)acetanilide.
Claim 120
Dependent Claim
6 words
A combination comprising: 2-(dichloroacetyl)-1-methyl-1,2,3,4-tetrahydroisoquinoline and 2-chloro-N-isopropyl-1-(3,5,5-trimethylcyclohexen-1-yl)acetamide.
Claim 121
Dependent Claim
6 words
A combination comprising: 2-(dichloroacetyl)-1-methyl-1,2,3,4-tetrahydroisoquinoline and 2-chloro-N-isopropyl-1-(3,5,5-trimethylcyclohexen-1-yl)acetamide.
References Cited (Backward Citations)
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