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EP0221046A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Modified polymeric surfaces and process for preparing same

Assignee: Monsanto Co
•
Filing: 1986-10-30
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Granted: —
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Expires: 2006-10-30
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Abstract

Abstract A process for surface modifying a variety of polymeric support surfaces is disclosed in which a predetermined modifying polymer is irreversibly absorbed onto essentially all the surfaces of the support polymer accessible to the modifying polymer. The modifying polymer is selected to impart the desired surface characteristics to the modified polymeric surface.

Inventors

  • 👤 Jay Myls Stuart Henis
  • 👤 Mary Kathryn Tripodi
  • 👤 Donald Irvine Stimpson

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-31 11:59
CPC Classifications
B; B01; B01D; B01D67/00; B01D67/0081; B01D67/0088; B01D67/0093; B01J; B01J20/00; B01J20/28; B01J20/28014; B01J20/28033; B01J20/30; B01J20/32; B01J20/3202; B01J20/3206; B01J20/3208; B01J20/321; B01J20/3212; B01J20/3231; B01J20/3242; B01J20/3268; B01J20/3272; B01J20/328; B01J20/3282; B05; B05D; B05D1/00; B05D1/18; B05D1/185; B82; B82Y; B82Y30/00; B82Y40/00; C; C08; C08J; C08J5/00; C08J5/20; C08J5/22; C08J5/2206; C08J5/2218; C08J5/2231; C08J5/2243; C08J5/2256; D; D06; D06M; D06M15/00; D06M15/19; D06M15/21; D06M15/227; D06M15/244; D06M15/256; D06M15/37; D06M15/63; D06M16/00; D06M23/00; D06M23/005; B01D2323/00; B01D2323/30; C08J2381/00; C08J2381/06; Y; Y10; Y10S; Y10S424/00; Y10S424/07; Y10S530/00; Y10S530/81; Y10S530/812; Y10S530/813; Y10S530/814; Y10S530/815

Claims Analysis

Total Claims: 40
Claim 1
Independent Claim 67 words
A process for surface modifying a predetermined polymeric support material which comprises irreversibly adsorbing a modifying polymer onto substantially the entire surface of said support material accessible to said modifying polymer, said modifying polymer having a molecular weight of at least 10,000 and containing an effective number of binding groups which partition onto or into the support material and adhere the modifying polymer to the support material.
Claim 2
Dependent Claim 67 words
A process for surface modifying a predetermined polymeric support material which comprises irreversibly adsorbing a modifying polymer onto substantially the entire surface of said support material accessible to said modifying polymer, said modifying polymer having a molecular weight of at least 10,000 and containing an effective number of binding groups which partition onto or into the support material and adhere the modifying polymer to the support material.
Claim 3
Dependent Claim 14 words
A process of Claim 1 in which the support material is a support membrane.
Claim 4
Dependent Claim 25 words
A process of Claim 2 in which the irreversible adsorption is brought about by contacting said support membrane with a solution containing said modifying polymer.
Claim 5
Dependent Claim 18 words
A process of Claim 3 in which the solution contains between about 0.1 and 10 wt% modifying polymer.
Claim 6
Dependent Claim 33 words
A process of Claim 2 in which partitioning of the binding groups of the modifying polymer onto or into the support membrane is promoted by increasing the chain mobility of the support membrane.
Claim 7
Dependent Claim 19 words
A process of Claim 5 in which chain mobility is increased by increase in temperature of the support membrane.
Claim 8
Dependent Claim 15 words
A process of Claim 6 in which the temperature is between about 60°C and 80°C.
Claim 9
Dependent Claim 17 words
A process of Claim 2 further comprising crosslinking the modifying polymer following adsorption onto the support membrane.
Claim 10
Dependent Claim 29 words
A process of Claim 2 in which the hydrodynamic radius of the modifying polymer is less than or equal to about one-fifth the pore size of the support membrane.
Claim 11
Dependent Claim 46 words
A surface modified membrane which com­prises a polymeric support membrane having a modifying polymer irreversibly adsorbed thereon, said modifying polymer having a molecular weight of at least 10,000 and being disposed in a substantially monomolecular layer on essentially the entire surface area of said support membrane.
Claim 12
Dependent Claim 46 words
A surface modified membrane which com­prises a polymeric support membrane having a modifying polymer irreversibly adsorbed thereon, said modifying polymer having a molecular weight of at least 10,000 and being disposed in a substantially monomolecular layer on essentially the entire surface area of said support membrane.
Claim 13
Dependent Claim 13 words
A modified membrane of Claim 10 in which the modifying polymer is crosslinked.
Claim 14
Dependent Claim 29 words
A membrane of Claim 10 in which the support membrane is made of a polymer selected from the group consisting of polysulfone, polyethersulfone, polyetherimide, polypropylene, polyethylene and polyvinylidene fluoride.
Claim 15
Dependent Claim 20 words
The membrane of Claim 10 in which the support membrane is made of polysulfone and the modifying polymer is hydroxypropylcellulose.
Claim 16
Dependent Claim 12 words
The membrane of Claim 13 in which the modifying polymer is crosslinked.
Claim 17
Dependent Claim 24 words
The membrane of Claim 10 in which the support membrane is made of polysulfone and the modifying polymer is about 88 wt% hydrolyzed polyvinyl­acetate.
Claim 18
Dependent Claim 12 words
The membrane of Claim 15 in which the modifying polymer is crosslinked.
Claim 19
Dependent Claim 20 words
The membrane of Claim 10 in which the support membrane is made of polyethylene and the modifying polymer is polyvinylalcohol.
Claim 20
Dependent Claim 12 words
The membrane of Claim 17 in which the modifying polymer is crosslinked.
Claim 21
Dependent Claim 20 words
The membrane of Claim 10 in which the support membrane is made of polypropylene and the modifying polymer is polyvinylalcohol.
Claim 22
Dependent Claim 12 words
The membrane of Claim 19 in which the modifying polymer is crosslinked.
Claim 23
Dependent Claim 25 words
A membrane of Claim 10 in which the support membrane is made of polypropylene and the modifying polymer is dextran having hydrophobic reactive groups thereon.
Claim 24
Dependent Claim 12 words
A membrane of Claim 21 in which the modifying polymer is crosslinked.
Claim 25
Dependent Claim 25 words
A membrane of Claim 10 in which the support membrane is made of polysulfone and the modifying polymer is dextran having hydrophobic reactive groups thereon.
Claim 26
Dependent Claim 12 words
A membrane of Claim 23 in which the modifying polymer is crosslinked.
Claim 27
Dependent Claim 19 words
A membrane of Claim 10 which is further modified by binding a biologically active material to the modifying polymer.
Claim 28
Dependent Claim 12 words
A membrane of Claim 25 in which the modifying polymer is crosslinked.
Claim 29
Dependent Claim 14 words
A membrane of Claim 25 in which the modifying polymer is crosslinked ionic polymer.
Claim 30
Dependent Claim 14 words
A membrane of Claim 27 in which the biologically active material is a polypeptide.
Claim 31
Dependent Claim 13 words
A membrane of Claim 27 in which the ionic polymer is DEAE dextran.
Claim 32
Dependent Claim 14 words
A membrane of Claim 29 in which the support membrane is made of polysulfone.
Claim 33
Dependent Claim 12 words
A membrane of Claim 11 in which the modifying polymer is ionic.
Claim 34
Dependent Claim 13 words
A membrane of Claim 11 in which the modifying polymer is DEAE dextran.
Claim 35
Dependent Claim 12 words
The membrane of Claim 32 in which the support membrane is polysulfone.
Claim 36
Dependent Claim 15 words
The membrane of Claim 33 in which the polysulfone support membrane is substantially macro-­void free.
Claim 37
Dependent Claim 12 words
A membrane of Claim 32 in which the support membrane is polyethersulfone.
Claim 38
Dependent Claim 27 words
A membrane of Claim 10 in which the support membrane is made of a polymer selected from the group consisting of polysulfone, polyethersul­fone, polyetherimide, polypropylene and polyethylene.
Claim 39
Dependent Claim 13 words
A membrane of Claim 36 in which the modifying polymer is blue dextran.
Claim 40
Dependent Claim 14 words
A membrane of Claim 10 in which the support polymer is substantially macro-void free.

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