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EP0218397A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Thermal transfer printing

Assignee: Imperial Chemical Industries Ltd
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Filing: 1986-09-17
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Granted: —
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Expires: 2006-09-17
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Abstract

Abstract A thermal transfer printing sheet comprising a substrate having a coating comprising an azo dye of the formula: wherein: A is the residue of a diazotisable phenylamine or naphthylamine, A-NH 2 , carrying nor more than one unsaturated electron-withrawing group; B is an optionally substituted thiophen-2,5-yiene or thiazol--2-ylene group; and E is the residue of an aromatic coupling component having group displaceable by a diazotised aromatic amine, suitable use in a thermal transfer printing process of the type in which the transfer sheet is placed in contact with a material to be printed and selectively heated in accordance with a pattern information signal whereby dye from the selectively heated regions of the transfer sheet is transferred to the material to be printed and forms a pattern thereon the shape and density of which is in accordance with the pattern and intensity of heat applied to the transfer sheet.

Inventors

  • 👤 Peter Gregory

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-27 23:09
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/26; B41M5/382; B41M5/385; B41M5/388; Y; Y10; Y10S; Y10S428/00; Y10S428/913; Y10S428/914

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 71 words
A thermal transfer printing sheet comprising a substrate having a coating comprising an azo dye of the formula: wherein: A is the residue of a diazotisable phenylamine or naphthylamine, A-NH 2 , carrying not more than one unsaturated electron-withrawing group; B is an optionally substituted thiophen-2,5-ylene or thiazol-2,5-ylene group; and E is the residue of an aromatic coupling component E-X wherein X is a group displaceable by a diazotised aromatic amine.
Claim 2
Dependent Claim 71 words
A thermal transfer printing sheet comprising a substrate having a coating comprising an azo dye of the formula: wherein: A is the residue of a diazotisable phenylamine or naphthylamine, A-NH 2 , carrying not more than one unsaturated electron-withrawing group; B is an optionally substituted thiophen-2,5-ylene or thiazol-2,5-ylene group; and E is the residue of an aromatic coupling component E-X wherein X is a group displaceable by a diazotised aromatic amine.
Claim 3
Dependent Claim 112 words
A thermal transfer printing shetter according to Claim 1 wherein A is of the formula: wherein R is selected from H, CN, SCN, NO 2 , -CONT 2 -, -SO 2 NT 2 , -COT 1 , -SO 2 T 1 , -COOT 2 , -SO 2 OT 2 , COF, -COC1, -SO 2 F, -SO 2 Cl; each R is independently selected from H; C 1-4 -alkyl; C 1-4 -alkoxy; F; Cl; Br; CF 3 and - NT 2 . n is 1, 2 or 3. each T is independently H, C 1-4 -alkyl or phenyl; T 1 is C 1-4 -alkyl or phenyl; and T 2 is C 1-4 -alkyl.
Claim 4
Dependent Claim 52 words
A transfer printing sheet according to Claim 1 or Claim 2 wherein B is a group of the formula: wherein R 2 is selected from CN, -COOT 1 , -COT 1 and -CONT 2 ; R3is H or C 1-4 -alkyl; & T & T 1 are as defined in Claim 2.
Claim 5
Dependent Claim 93 words
A transfer printing sheet according to any one of Claims 1 to 3 wherein E is a group of the formula: wherein R4& R 5 are independently selected from H, C 1-4 -alkyl, aryl, C 4-8 -cycloalkyl and C 1-4 -alkyl substituted by a group selected from OH, CN, halogen, aryl, C 1-4 -alkoxy, C 1-4 -alkoxy-C 1-4 -alkoxy, C 1-4 -alkyl-CO-, C 1-4 -alkoxy-CO-, C 1-4 -alkyl-COO-, C 1-4 -alkoxy-C 1-4 -alkoxy-CO-, 6 C 1-4 -alkoxy-COO-; R 6 is selected from H, C 1-4 -alkyl, C 1-4 -alkoxy and -NHCOT 1 ;
Claim 6
Dependent Claim 8 words
and T is as defined in Claim 2.
Claim 7
Dependent Claim 180 words
A transfer sheet according to Claim 1 wherein the dye is of the formula: wherein R is selected from H; -CN; -NO 2 ; -CONT 2 -; -SO 2 NT 2 ; -COT 1 ; -SO 2 T 1 ; COOT 2 and SO 2 OT 2 ; each R is independently selected from H; halogen; C 1-4 -alkyl; C 1-4 -alkoxy; -NT 2 and CF 3 ; n is 1, 2 or 3; R 2 is selected from CN, -COT 1 , -CONT 2 and COOT 1 ; R 3 is H or C 1-4 -alkyl; R & R are independently selected from H, C 1-4 -alkyl, phenyl, C 4-8 -cycloalkyl and C 1-4 -alkyl substituted by a group selected from OH, CN, C 1-4 -alkoxy, C 1-4 -alkoxy-C 1-4 -alkoxy, C 1-4 -alkyl-CO-, C 1-4 -alkoxy-CO-, C 1-4 -alkyl-COO-, halogen, C 1-4 -alkoxy-C 1-4 -alkoxy-CO-, C 1-4 -alkoxy-COO- and phenyl; R 6 is selected from H, C 1-4 -alkyl, C 1-4 -alkoxy and -NHCOT 1 ; and T, T and T 2 are as defined in Claim 1.
Claim 8
Dependent Claim 36 words
A transfer sheet according to Claim 5 wherein R & R 3 are H, n is 2 and each R 1 is independently selected from H; halogen; C 1-4 -alkyl; CF 3 and C 1-4 -alkoxy.
Claim 9
Dependent Claim 73 words
A transfer printing process which comprises contacting a transfer sheet coated with a dye of Formula I with a receiver sheet, so that the dye is adjacent to the receiver sheet, and selectively heating an area of the transfer sheet at a temperature from 200°C to 400°C for a period of 0.5 to 20 milliseconds whereby dye in the heated area of the transfer sheet may be selectively transferred to the receiver sheet.
Claim 10
Dependent Claim 73 words
A transfer printing process which comprises contacting a transfer sheet coated with a dye of Formula I with a receiver sheet, so that the dye is adjacent to the receiver sheet, and selectively heating an area of the transfer sheet at a temperature from 200°C to 400°C for a period of 0.5 to 20 milliseconds whereby dye in the heated area of the transfer sheet may be selectively transferred to the receiver sheet.

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