EP0207794A2
Expired / Lapsed
EP
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Silver halide photographic material
Assignee: Konica Minolta Inc
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Filing: 1986-07-03
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Granted: —
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Expires: 2006-07-03
Abstract
Abstract A silver halide photographic material containing at least one of couplers represented by the general formula (I) and at least one of the compounds represented by the general formula [XII] is disclosed. Formula [I] wherein Z is a group of nonmetal atoms necessary to complete a nitrogen-containing heterocyclic ring where the ring formed by Z may be substituted; X is a hydrogen atom or a substituent capable of being released upon reaction with the oxidation product of a color developing agent and R is a hydrogen atom or substituent; wherein R 21 is a hydrogen atom or a group selected from the group consisting of an alkyl group, an alkenyl group, a cycloalkyl group and aryl group, R 22 and R 23 are independently selected from the group consisting of an alkyl group, an alkenyl group, a cycloalkyl group and an aryl group. The photographic material provides a dye-image highly stable against heat and light, and a formation of stain at a non-image area is prevented.
Inventors
- 👤 Shuji Kida
- 👤 Shinji Yoshimoto
- 👤 Yutaka Kaneko
- 👤 Kosaku Masuda
- 👤 Kenji Kadokura
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-10-29 23:36
CPC Classifications
G; G03; G03C; G03C7/00; G03C7/30; G03C7/3003; G03C7/3005; G03C7/3008; G03C7/301
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
145 words
A silver halide photographic material containing at least one of couplers represented by the general formula [I] and at least one of compounds represented by the general formula [XII]: Formula [I] wherein Z represents a group of nonmetal atoms necessary to complete a nitrogen-containing heterocyclic ring where the ring formed by Z may be substituted; X represents a hydrogen atom or a substituent capable of being released upon reaction with the oxidation product of a color developing agent and R represents a hydrogen atom or a substituent; Formula [XII] wherein R 21 represents a hydrogen atom or a group selected from the group consisting of an alkyl group, an alkenyl group, a cycloalkyl group and aryl group; R 22 and R 23 independently represent a group selected from the group consisting of an alkyl group, an alkenyl group, a cycloalkyl group and an aryl group.
Claim 2
Dependent Claim
145 words
A silver halide photographic material containing at least one of couplers represented by the general formula [I] and at least one of compounds represented by the general formula [XII]: Formula [I] wherein Z represents a group of nonmetal atoms necessary to complete a nitrogen-containing heterocyclic ring where the ring formed by Z may be substituted; X represents a hydrogen atom or a substituent capable of being released upon reaction with the oxidation product of a color developing agent and R represents a hydrogen atom or a substituent; Formula [XII] wherein R 21 represents a hydrogen atom or a group selected from the group consisting of an alkyl group, an alkenyl group, a cycloalkyl group and aryl group; R 22 and R 23 independently represent a group selected from the group consisting of an alkyl group, an alkenyl group, a cycloalkyl group and an aryl group.
Claim 3
Dependent Claim
136 words
The silver halide photographic material of claim i, wherein the substituent represented by R is selected from the group consisting of a halogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkenyl group, an alkynyl group, an aryl group, a heterocyclic group, an acyl group, a sulfonyl group, a sulfinyl group, a phosphonyl group, a carbamoyl group, a sulfamoyl group, a cyano group, a residue of a spyro compound, a residue of a bridged hydrocarbon compound, an alkoxy group, an aryloxy group, a heterocyclic oxy group, a siloxy group, an acyloxy group, a carbamoyloxy group, an amino group, an acylamino group, a sulfonamide group, an imide group, an ureido group, a sulfamoylamino group, an alkoxycarbonylamino group, an aryloxycarbonylamino group, an aryloxycarbonylamino group, an alkylthio group, an arylthio group and a heterocyclic thio group.
Claim 4
Dependent Claim
43 words
The silver nalide photographic material of claim 1 or 2, wherein said coupler is represented by the general formula [VIII]: Formula [VIII] wherein R 1 , X and Z 1 represent the same as R, X and Z of the formula [I], respectively.
Claim 5
Dependent Claim
36 words
The silver halide pnotographic material of claim 3, wherein said coupler is represented by the general formula [II]: Formula [II] wherein R 1 and R 2 represent the same as R of the formula [I], respectively.
Claim 6
Dependent Claim
40 words
The silver halide photographic material of any one of claims 1 to 4 wherein an amount of said coupler is from 1x10 -3 to 1 mole per mole of silver halide contained in a silver halide emulsion containing said coupler.
Claim 7
Dependent Claim
36 words
The silver halide photographic material of claim 5, wherein an amount of said coupler is from 1x10 -2 to 8x10 -1 mole per mole of silver halide contained in a silver halide emulsion containing said coupler.
Claim 8
Dependent Claim
41 words
The silver halide photographic material of any one of claims 1 to 6 wherein said alkyl group represented by R 21 , R 22 or R 23 is a straight chain or branched alkyl group containing 1 to 24 carbon atoms.
Claim 9
Dependent Claim
38 words
The silver halide photographic material of any one of claims 1 to 7 wherein said cycloalkyl group represented by R2 1 , R 22 or R 23 is a cycloalkyl group containing 5 to 24 of carbon atoms.
Claim 10
Dependent Claim
38 words
The silver halide photographic material of any one of claims 1 to 8 wherein said alkenyl group represented by R 21 , R 22 or R 23 is an alkenyl group containing 3 to 24 of carbon atoms.
Claim 11
Dependent Claim
35 words
The silver halide photographic material of any one of claims 1 to 9 wherein said aryl group represented by R 21 , R 22 or R 23 is a phenyl group or a naphtyl group.
Claim 12
Dependent Claim
49 words
The silver halide photographic material of any one of claims 1 to 10 wherein the amount of the compound represented by the formula [XII] to be contained in said photographic material is 5 to 400 mole% with respect to 100 mole% of the coupler represented by the formula [I].
Claim 13
Dependent Claim
44 words
The silver halide photographic material of claim 11, wherein the amount of the compound represented by the formula [XII] to be contained in said photographic material is 10 to 300 mole% with respect to 100 mole% of the coupler represented by the formula [I].
Claim 14
Dependent Claim
43 words
The silver halide photographic material of any one of claims 1 to 12 wherein the coupler represented by the formula [I] and the compound represented by the formula [XII] are contained in the same silver halide emulsion layer comprised in said photographic material.
Claim 15
Dependent Claim
166 words
A silver halide photographic material comprising a support and provided thereupon at least one photosensitive silver halide emulsion layer, at least one of said silver halide emulsion layer containing a coupler of the general formula [I] and said photographic material containing at least one compound of the general Formula [XII]: Formula [I] wherein Z represents a group of nonmetal atoms necessary to complete a nitrogen-containing heterocyclic ring where the ring formed by Z may be substituted; X represents a hydrogen atom or a substituent capable of being released upon reaction with the oxidation product of a color developing agent and R represents a hydrogen atom or a substituent; Formula [XII] wherein R 21 represents a hydrogen atom or a group selected from the group consisting of an alkyl group, an alkenyl group, a cycloalkyl group and aryl group; R 22 and R 23 independently represent a group selected from the group consisting of an alkyl group, an alkenyl group, a cycloalkyl group and an aryl group.
Claim 16
Dependent Claim
166 words
A silver halide photographic material comprising a support and provided thereupon at least one photosensitive silver halide emulsion layer, at least one of said silver halide emulsion layer containing a coupler of the general formula [I] and said photographic material containing at least one compound of the general Formula [XII]: Formula [I] wherein Z represents a group of nonmetal atoms necessary to complete a nitrogen-containing heterocyclic ring where the ring formed by Z may be substituted; X represents a hydrogen atom or a substituent capable of being released upon reaction with the oxidation product of a color developing agent and R represents a hydrogen atom or a substituent; Formula [XII] wherein R 21 represents a hydrogen atom or a group selected from the group consisting of an alkyl group, an alkenyl group, a cycloalkyl group and aryl group; R 22 and R 23 independently represent a group selected from the group consisting of an alkyl group, an alkenyl group, a cycloalkyl group and an aryl group.
Claim 17
Dependent Claim
198 words
A multi-layered silver halide color photographic material comprising a support and a plurality of photosensitive silver halide emulsion layers provided on said support, said plurality of emulsion layers comprising at least one blue-sensitive silver halide emulsion layer containing a yellow dye-forming coupler, at least one green-sensitive silver halide emulsion layer containing a magenta dye-forming coupler of the general formula [I] and a compound of the general formula [XII] and at least one red-sensitive silver halide emulsion layer containing a cyan dye-forming coupler: Formula [I] wherein Z represents a group of nonmetal atoms necessary to complete a nitrogen-containing heterocyclic ring where the ring formed by Z may be substituted; X represents a hydrogen atom or a substituent capable of being released upon reaction with the oxidation product of a color developing agent and R represents a hydrogen atom or a substituent; Formula [XII] wherein R 21 represents a hydrogen atom or a group selected from the group consisting of an alkyl group, an alkenyl group, a cycloalkyl group and aryl group; R 22 and R 23 independently represent a group selected from the group consisting of an alkyl group, an alkenyl group, a cycloalkyl group and an aryl group.
Claim 18
Dependent Claim
198 words
A multi-layered silver halide color photographic material comprising a support and a plurality of photosensitive silver halide emulsion layers provided on said support, said plurality of emulsion layers comprising at least one blue-sensitive silver halide emulsion layer containing a yellow dye-forming coupler, at least one green-sensitive silver halide emulsion layer containing a magenta dye-forming coupler of the general formula [I] and a compound of the general formula [XII] and at least one red-sensitive silver halide emulsion layer containing a cyan dye-forming coupler: Formula [I] wherein Z represents a group of nonmetal atoms necessary to complete a nitrogen-containing heterocyclic ring where the ring formed by Z may be substituted; X represents a hydrogen atom or a substituent capable of being released upon reaction with the oxidation product of a color developing agent and R represents a hydrogen atom or a substituent; Formula [XII] wherein R 21 represents a hydrogen atom or a group selected from the group consisting of an alkyl group, an alkenyl group, a cycloalkyl group and aryl group; R 22 and R 23 independently represent a group selected from the group consisting of an alkyl group, an alkenyl group, a cycloalkyl group and an aryl group.
References Cited (Backward Citations)
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