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EP0199403B1
Expired / Lapsed
EP
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Stable liquid detergent compositions
Assignee: Procter and Gamble Co
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Filing: 1986-04-07
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Granted: 1993-12-15
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Expires: 2006-04-07
Abstract
Abstract Heavy-duty liquid detergents containing an essential block polyester soil release agent; anionic surfactant; ethoxylated non-ionic surfactant; optional quaternary ammonium, amine, amide, or amine oxide surfactant; preferably fatty acid and/or poly-carboxylate builders; a neutralization system preferably comprising sodium, potassium and/or low levels of alkanolamines; and a solvent system comprising ethanol, polyol and/or water. The compositions are isotropic liquids providing a high level of detergency performance.
Inventors
- 👤 Eugene Paul Gosselink
- 👤 Larry James Hughes
- 👤 Antoinette Louise Larrabee
- 👤 Robert Mermelstein
- 👤 Nodie Monroe Washington
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-10-25 06:46
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/16; C11D3/37; C11D3/3703; C11D3/3715; C11D1/00; C11D1/86; C11D3/0005; C11D3/0036; C11D1/02; C11D1/12; C11D1/14; C11D1/22; C11D1/29; C11D1/38; C11D1/42; C11D1/44; C11D1/52; C11D1/521; C11D1/523; C11D1/62; C11D1/66; C11D1/72; C11D1/75
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
448 words
A heavy-duty liquid detergent composition comprising, by weight: (a) from 10% to 35%, of an anionic surfactant on an acid basis; (b) from 0% to 15% of an ethoxylated nonionic surfactant of the formula R¹ (OC₂H₄) n OH, wherein R¹ is a C₁₀-C₁₆ alkyl group or a C₈-C₁₂ alkyl phenyl group, n averages from 3 to 9, and said nonionic surfactant has an HLB of from 10 to 13; (c) from 0% to 15% of a cosurfactant selected from the group consisting of: (i) quaternary ammonium surfactants having the formula: [R²(OR³) y ][R⁴(OR³) y ]₂R⁵N⁺X⁻ wherein R² is an alkyl or alkyl benzyl group having from 6 to 16 carbon atoms in the alkyl chain; each R³ is selected from the group consisting of -CH₂CH₂-, -CH₂CH(CH₃)-, -CH₂CH(CH₂OH)-, -CH₂CH₂CH₂-, and mixtures thereof; each R⁴ is selected from the group consisting of C₁-C₄ alkyl, C₁-C₄ hydroxyalkyl, benzyl, and hydrogen when y is not 0; R⁵ is the same as R⁴ or is an alkyl chain wherein the total number of carbon atoms of R² plus R⁵ is from 8 to 16; each y averages from 0 to 10 and the sum of the y values is from 0 to 15; and X is any compatible anion; (ii) amine surfactants having the formula: [R²(OR³) y ][R⁴(OR³) y ]R⁵N wherein R², R³, R⁴, R⁵ and y are as defined above; (iii) amine oxide surfactants having the formula: [R²(OR³) y ][R⁴(OR³) y ]R⁵N → 0 wherein R², R³, R⁴, R⁵ and y are as defined above; (iv) an amide surfactant of the formula: wherein R⁶ is an alkyl, hydroxyalkyl or alkenyl radical containing from 8 to 20 carbon atoms, and R⁷ and R⁸ are each selected from the group consisting of hydrogen, methyl, ethyl, propyl, isopropyl, 2-hydroxyethyl, 2-hydroxypropyl, 3-hydroxypropyl, and wherein said radicals additionally contain up to 5 ethylene oxide units; and (v) mixtures thereof; (d) from 5% to 30% of detergent builder; (e) a neutralization system; (f) an aqueous solvent system, said system not consisting of water only; (g) from 0.25% to 4% of a soil release component which is a compound having the formula: wherein each R¹ moiety is a 1,4-phenylene moiety, each R² is an ethylene or a 1,2-propylene moiety; each n averages from 10 to 50; each X is H, an alkyl radical having from 1 to 4 carbon atoms or an acyl radical containing from 2 to 4 carbon atoms; wherein less than 10 mol% of said soil release compound has a u greater than 5, at least 20 mol% of said soil release compound has a u in the range of from 3 to 5 and wherein the average value of u is from 3 to 5.
Claim 2
Dependent Claim
27 words
The composition of Claim 1 wherein in component (g), n ranges from 10 to 25 and from 90% to 100% of the R² moieties are 1,2-propylene moieties.
Claim 3
Dependent Claim
18 words
The composition of Claim 2 wherein X is an alkyl radical containing from 1 to 2 carbon atoms.
Claim 4
Dependent Claim
25 words
The composition of Claim 2 wherein component (g) is a fraction of polymers soluble in absolute ethanol at a temperature of from 10°C to 15°C.
Claim 5
Dependent Claim
25 words
The composition of Claim 1 wherein component (g) is a fraction of polymers soluble in absolute ethanol at a temperature of from 10°C to 15°C.
Claim 6
Dependent Claim
122 words
The composition of Claim 5 wherein the detergent composition comprises by weight: (a) from 5% to 15%, on an acid basis, of a sulfonate surfactant containing a C₁₀-C₁₆ alkyl or alkenyl group; (b) from 8% to 18%, on an acid basis, of an alcohol ethoxylate sulfate surfactant of the formula RO(C₂H₄O) m SO₃M wherein R is a C₁₀-C₁₆ alkyl or hydroxyalkyl group, m is from 0.5 to 4, and M is a compatible cation; and (c) from 2% to 15% of an ethoxylated nonionic surfactant of the formula R¹(OC₂H₄) n OH, wherein R¹ is a C₁₀-C₁₆ alkyl group or a C₈-C₁₂ alkyl phenyl group, n is from 3 to 9, and said nonionic surfactant has an HLB of from 10 to 13.
Claim 7
Dependent Claim
94 words
The composition of Claim 5 wherein the detergent composition comprises by weight: (a) from 5% to 15%, on an acid basis, of a sulfonate surfactant containing a C₁₀-C₁₆ alkyl or alkenyl group; (b) from 1% to 4%, on an acid basis, of a C₁₀-C₁₆ alkyl sulfate; and (c) from 2% to 15% of an ethoxylated nonionic surfactant of the formula R¹(OC₂H₄) n OH, wherein R¹ is a C₁₀-C₁₆ alkyl group or a C₈-C₁₂ alkyl phenyl group, n is from 3 to 9, and said nonionic surfactant has an HLB of from 10 to 13.
Claim 8
Dependent Claim
53 words
The composition of Claim 6 wherein the sulfonate surfactant is a C₁₁-C₁₃ linear alkylbenzene sulfonate; in the alcohol ethoxylate sulfate surfactant, R is a C₁₂-C₁₅ alkyl group and m is from 1.5 to 3; and in the ethoxylated nonionic surfactant, R is a C₁₂-C₁₄ alkyl group and n is from 3 to 7.
Claim 9
Dependent Claim
25 words
The composition of Claim 8 comprising from 0.5% to 3% by weight of the cosurfactant, which is a C₁₀-C₁₄ alkyl trimethylammonium chloride, bromide or methylsulfate.
Claim 10
Dependent Claim
12 words
The composition of Claim 8 wherein the builder comprises a polycarboxylate builder.
Claim 11
Dependent Claim
53 words
The composition of Claim 8 comprising by weight from 6% to 10% of the sulfonate surfactant, from 9% to 14% of the alcohol ethoxylate sulfate surfactant, from 4% to 10% of the ethoxylated nonionic surfactant, and from 0.5% to 1.5% of the cosurfactant, which is a C₁₀-C₁₄ alkyl trimethylammonium chloride, bromide or methylsulfate.
Claim 12
Dependent Claim
31 words
The composition of Claim 11 in which the builder comprises by weight of the composition from 10% to 16% of saturated fatty acid and from 3% to 6% of citric acid.
Claim 13
Dependent Claim
22 words
The composition of Claim 12 comprising from 0 to 0.035 moles per 100 grams of composition of an alkanolamine, which is monoethanolamine.
Claim 14
Dependent Claim
32 words
The composition of Claim 13 comprising by weight from 5% to 9% of ethanol, from 3% to 10% of a polyol, which is propylene glycol, and from 28% to 37% of water.
Claim 15
Dependent Claim
26 words
The composition of Claim 14 having an initial pH of from 7.8 to 9.0 at a concentration of 10% by weight in water at 68°F (20°C).
Claim 16
Dependent Claim
152 words
The process of preparing a soil release component having the formula: wherein each R₁ is a 1,4-phenylene moiety, each R₂ is an ethylene or a 1,2-propylene moiety; each X is selected from the group consisting of hydrogen, alkyl groups containing from one to four carbon atoms and acyl groups containing from 2 to four carbon atoms; n averages from 10 to 50; wherein less than 10 mol% of said soil release component has a u greater than 5, at least 20 mol% of said soil release component has a u in the range of from 3 to 5 and wherein the average value of u is from 3 to 5; comprising the step of dissolving a soil release component comprising the desired material and a substantial amount of material in which u is greater than five in absolute ethanol at a temperature of from 10°C to 15°C and separating the precipitating material.
Claim 17
Dependent Claim
127 words
An ethanol soluble soil release component having the formula : wherein each R¹ moiety is a 1,4-phenylene moiety, each R² is an ethylene or a 1,2-propylene moiety; each n averages from 10 to 50; each X is H, an alkyl radical having from 1 to 4 carbon atoms or an acyl radical containing from 2 to 4 carbon atoms, wherein from 90% to 100% of the R² moieties are 1,2-propylene moieties; and wherein less than 10 mol% of said soil release compound has a u greater than 5, at least 20 mol% of said soil release compound has a u in the range of from 3 to 5 and wherein the average value of u is from 3 to 5; obtainable by the process of Claim 16.
Claim 18
Dependent Claim
19 words
The component of Claim 17 wherein each X is an alkyl group containing from 1 to 2 carbon atoms.
References Cited (Backward Citations)
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