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EP0184846A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Three-stage process for burning fuel containing sulfur to reduce emission of particulates and sulfur-containing gases

Assignee: Alcoa Corp
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Filing: 1985-12-12
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Granted: —
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Expires: 2005-12-12
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Abstract

Abstract @ A three-stage combustion process is disclosed for burning a fuel containing sulfur characterized by low sulfur emission and good ash removal. The process comprises mixing the sulfur containing fuel with an additive capable of reacting with sulfur; burning the mixture in a first combustion stage with less than 75% theoretical air and at a temperature below the melting point of the ash but sufficiently high to cause reaction between the additive and any sulfur in the fuel to facilitate removal of the sulfur compounds formed; removing at least a portion of the sulfur compounds formed in the first stage; passing combustible gases from the first stage to a second stage; burning the gases in the second stage with less than 100% theoretical air at a temperature above the melting point of the ash to form a liquid slag which is removable from the second stage; and burning combustible gases from the second stage in a third stage with an excess of air to ensure complete combustion of the fuel.

Inventors

  • 👤 Melvin H. Brown
  • 👤 David H. Deyoung

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-06 16:09
CPC Classifications
F; F23; F23C; F23C6/00; F23C6/04; C; C10; C10L; C10L1/00; C10L1/32; C10L1/326

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 168 words
A three-stage combustion process for burning a fuel containing sulfur having low sulfur emission and good ash removal comprising: (a) mixing the sulfur containing fuel with an additive capable of reacting with sulfur; characterized by: (b) burning the mixture in a first combustion stage with less-than 75% theoretical air and at a temperature below the melting point of the ash but sufficiently high to cause reaction between said additive and any sulfur in said fuel to facilitate removal of the sulfur compounds formed; (c) passing combustible fuel gases from said first stage to a second combustion stage; (d) burning said gases in said second stage with less than 100X theoretical air, based on theoretical air for products from the first stage, at a temperature above the melting point of the ash to form a liquid slag which is removable from said second stage; and (e) burning combustible gases from said second stage in a third stage with an excess of air to ensure complete combustion of said fuel.
Claim 2
Dependent Claim 168 words
A three-stage combustion process for burning a fuel containing sulfur having low sulfur emission and good ash removal comprising: (a) mixing the sulfur containing fuel with an additive capable of reacting with sulfur; characterized by: (b) burning the mixture in a first combustion stage with less-than 75% theoretical air and at a temperature below the melting point of the ash but sufficiently high to cause reaction between said additive and any sulfur in said fuel to facilitate removal of the sulfur compounds formed; (c) passing combustible fuel gases from said first stage to a second combustion stage; (d) burning said gases in said second stage with less than 100X theoretical air, based on theoretical air for products from the first stage, at a temperature above the melting point of the ash to form a liquid slag which is removable from said second stage; and (e) burning combustible gases from said second stage in a third stage with an excess of air to ensure complete combustion of said fuel.
Claim 3
Dependent Claim 64 words
The process of claim 1 wherein said additive is first mixed with water prior to mixing said additive with said sulfur containing fuel, or said fuel comprises a particulate carbonaceous fuel and said water and said water and additive are mixed with said particulate carbonaceous fuel to form a slurry whereby said additive may come in intimate contact with said sulfur in said fuel.
Claim 4
Dependent Claim 53 words
The process of claim 1 wherein said particulate carbonaceous fuel comprises coal and said temperature in said first stage is maintained below 1100°C to prevent ash formed by said burning coal from melting whereby reaction between said additive and sulfur in said fuel in said first stage to form sulfur compounds is facilitated.
Claim 5
Dependent Claim 64 words
The process of claim - 3 including the further step of removing at least a portion of the sulfur compounds formed in said first stage prior to passage into the second stage whereby said sulfur compounds formed in said first stage will not be exposed to the higher temperatures of the second stage which might decompose said sulfur compounds to form undesirable sulfur gases.
Claim 6
Dependent Claim 49 words
The process of claim 4 wherein at least a portion of said ash formed in said first stage is passed to said second stage with combustible fuel from said first stage whereby said ash may be melted into a recoverable form at the higher temperature of said second stage.
Claim 7
Dependent Claim 42 words
The process of claim 4 wherein the temperature in said first stage is maintained below 1100 C, or more specifically at 850 to 1050°C and/or the temperature in said second stage is maintained above 1100°C, or more specifically at 1100 to 1400°C.
Claim 8
Dependent Claim 61 words
The process of claim 1 wherein said additive capable of reacting with sulfur consists of a metal in metallic form, a metal oxide or a metal salt, and/or said additive being an alkali metal, an alkaline earth metal or mixtures thereof, or being an alkali metal capable of reacting with sulfur to form a compound removable from said first combustion stage.
Claim 9
Dependent Claim 162 words
A process according to claim 1 comprising: (a) forming a slurry of said particulated carbonaceous fuel, water and an additive capable of reacting with said sulfur to form one or more removable compounds; characterized by: (b) burning said slurry in a first combustion stage with less than 75% theoretical air at a temperature below the melting temperature of ash in said fuel to form said removable sulfur-containing compounds; (c) removing said sulfur-containing compounds; (d) burning combustible materials from said first stage in a second combustion stage with less than 100% of the theoretical air needed for the combustible materials from said first stage, at a temperature above the melting point of ash in said combustible materials from said first stage; (e) removing said ash as a slag; and (f) burning combustible materials from said second stage in a third combustion stage with an excess of air whereby the emissions from said third stage of sulfur-containing gases and particulates will be substantially lowered.
Claim 10
Dependent Claim 189 words
A process according to claim 1, comprising: (a) forming a slurry of said particulated carbonaceous fuel, water and an additive capable of reacting with said sulfur to form one or more removable compounds; characterized by: (b) burning said slurry in a first combustion stage with less than 751 theoretical air at a temperature below the melting temperature of ash in said fuel to form said removable sulfur-containing compounds; (c) removing at least a portion of said sulfur-containing compounds from said first combustion stage; (d) passing the remainder of the materials from said first combustion stage to a second combustion stage; (e) burning combustible materials from said first stage in a second combustion stage with less than 100% of the theoretical air needed for the combustible materials from said first stage at a temperature above the melting point of ash in said combustible materials from said first stage; (f) removing said ash as a slag; and (g) burning combustible materials from said second stage in a third combustion stage with an excess of air whereby the emissions from said third stage of sulfur-containing gases and particulates will be substantially lowered.
Claim 11
Dependent Claim 28 words
A process according to any of the preceding claims, wherein a binding agent is added to said carbonaceous fuel to reduce the particulate emission from said combustion process.

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