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EP0170082A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Liquid crystalline isothiocyanates with a dioxane ring and liquid crystalline admixtures containing the same

Assignee: Military University of Technology in Warsaw
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Filing: 1985-07-02
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Granted: —
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Expires: 2005-07-02
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Abstract

Abstract New compounds of the general formula: wherein the symbols X stand for carbon atom bonded with two hydrogen atoms (-CH 2 - group) and the symbols Z stand for oxygen atom, or the symbols X stand for oxygen atom and the symbols Z stand for carbon atom bonded with two hydrogen atoms (-CH 2 - group), m is an integer of 1 to 2, R represents an alkyl (H 2n+1 C n ) or a 4-alkylphenyl (H 2n+1 C n -C e H 4 ) or an alkyl biphenyl (H 2n+1 C n -C 6 H 4 -C 6 H 4 ) or an alkylcyclohexylphenyl group (H 2n+1 C n -C 6 H 10 -C 6 H 4 ), the term alkyl group signifies an alkyl chain containing 1 to 15 carbon atoms or it also signifies a branched-chain alkyl group C 2 H 5 -CH(CH 3 )-(CH 2 ) k , where k is an integer of 1 to 3, have utility as liquid crystals. A process for manufacturing compounds of the general formula I. Liquid crystalline admixtures containing those compounds and a way of selection of their compositions to obtain the admixtures which exhibit smectic, smectic and nematic or only smectic properties as well as their use in electrooptical devices is described.

Inventors

  • 👤 Roman Dabrowski
  • 👤 Jerzy Dziaduszek
  • 👤 Jaroslaw Szulc
  • 👤 Zygfryd Witkiewicz
  • 👤 Zofia Stolarz
  • 👤 Krystyna Kenig
  • 👤 Gabriela Adamska

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-31 19:53
CPC Classifications
C; C09; C09K; C09K19/00; C09K19/04; C09K19/42; C07; C07D; C07D319/00; C07D319/04; C07D319/06; C09K19/06; C09K19/34; C09K19/3402; C09K2019/3422; C09K2019/3425

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 107 words
Compounds of the general formula : wherein the symbols X stand for carbon atom bonded with two hydrogen atoms (-CH 2 - group) and the symbols Z stand for oxygen atom or the symbols X stand for oxygen atom and the symbols Z stand for carbon atom bonded with two hydrogen atoms (-CH 2 - group), m is an integer of 1 to 2, R represents an alkyl (H 2n+1 C n -) or a 4-alkylphenyl (H 2n+1 C n C 6 H 4 -) group, the term alkyl group signifies an alkyl chain containing 1 to 15 carbon atoms and the chain is straight or branched.
Claim 2
Dependent Claim 107 words
Compounds of the general formula : wherein the symbols X stand for carbon atom bonded with two hydrogen atoms (-CH 2 - group) and the symbols Z stand for oxygen atom or the symbols X stand for oxygen atom and the symbols Z stand for carbon atom bonded with two hydrogen atoms (-CH 2 - group), m is an integer of 1 to 2, R represents an alkyl (H 2n+1 C n -) or a 4-alkylphenyl (H 2n+1 C n C 6 H 4 -) group, the term alkyl group signifies an alkyl chain containing 1 to 15 carbon atoms and the chain is straight or branched.
Claim 3
Dependent Claim 45 words
Compounds according to claim 1 wherein the symbols X stand for carbon atom bonded with two hydrogen atoms (-CH 2 - group) and the symbols Z stand for oxygen atom, m is the integer of 1 and R represents an alkyl or an alkylphenyl group.
Claim 4
Dependent Claim 12 words
Compounds according to claim 2, wherein R represents a normal alkyl group.
Claim 5
Dependent Claim 31 words
Compounds according to claim 2, wherein R represents a branched alkyl group, C 2 H 5 -CH(CH 3 )-(CH 2 ) k , k is an integer of 1 to 3.
Claim 6
Dependent Claim 15 words
Compounds according to anyone of claims 1 to 4 as components in liquid crystalline admixtures.
Claim 7
Dependent Claim 24 words
A liquid crystalline admixture containing at least two components, wherein at least one component is of the formula I as claimed in claim 1.
Claim 8
Dependent Claim 72 words
A liquid crystalline admixture according to claim 6, which contains one or more compounds of formula I defined in claim 1 and one or more compounds of the general formula: and/or and/or and/or and/or and/or and/or and/or and/or and/or wherein the symbols p and r are an integer of 1 to 2, Y represents N0 2 or CN group, R represents an alkyl, an alkoxy, an alkylcarboxy, an alkoxycarboxy, an alkylphenyl group.
Claim 9
Dependent Claim 52 words
A liquid crystalline admixture according to claim 7, which contains 50 to 90 % by weight compounds of the formulae II to XI defined in claim 7, wherein R 1 represents an alkyl or an alkoxy group having at least 5 carbon atoms in chain, and p is the integer of 1.
Claim 10
Dependent Claim 19 words
A liquid crystalline admixture according to claim 6, which contains an optically active compound and/or a pleo- chroic dye.
Claim 11
Dependent Claim 17 words
A liquid crystalline admixture containing as components only compounds of the formula I according to claim 2.
Claim 12
Dependent Claim 66 words
A liquid crystalline admixture according to claim 10 containing compounds of formula I, wherein R represents an alkyl group, in which the components are selected in such a way that one or several compounds with an alkyl group containing from 2 to 6 carbon atoms and one or several compounds with an alkyl group containing from 8 to 12 carbon atoms are simultaneously in the admixture.
Claim 13
Dependent Claim 16 words
The use of the compounds of the formula I defined in claim 1 for electro-optical purposes.

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