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EP0169640A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Oriented film comprising at least five layers

Assignee: WR Grace and Co Conn
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Filing: 1985-05-29
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Granted: —
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Expires: 2005-05-29
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Abstract

Abstract The invention provides a multilayered thermoplastic film which may be utilized to form storm windows or packaging material. The film comprises a core layer consisting essentially of either (a) a copolymer of ethylene and vinyl acetate or (b) a three component blend of (a) a linear low density polyethylene, (b) a linear medium density polyethylene and (c) an ethylene vinyl acetate copolymer. The film also comprises two intermediate layers each consisting essentially of a linear low density polyethylene, and two surface layers each consisting essentially of either of a four component blend of (1) a linear low density polyethylene, (2) a linear medium density polyethylene, (3) a copolymer of ethylene and vinyl acetate and (4) one or more light stabliizers, or a three component blend in which light stabilizers are not present.

Inventors

  • 👤 Julian Harry Schoenberg

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-09 09:13
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/32; B32B27/322; G; G02; G02B; G02B6/00; G02B6/44; G02B6/4439; G02B6/4471; G02B6/4476; B29; B29K; B29K2995/00; B29K2995/0018; B29K2995/0022; Y; Y10; Y10T; Y10T428/00; Y10T428/26; Y10T428/269; Y10T428/31504; Y10T428/31855; Y10T428/31909; Y10T428/31913; Y10T428/31928

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 85 words
An oriented multilayer film comprising: a cross-linked core layer comprising either (a) an ethylene vinyl acetate copolymer or (b) a three component blend of (1) a linear low density polyethylene, (2) a linear medium density polyethylene and (3) an ethylene vinyl acetate copolymer; two cross-linked interior layers each comprising a linear low density polyethylene; and two cross-linked surface layers each comprising a three component blend cf (1) a linear low density polyethylene, (2) a linear medium density polyethylene, and (3) an ethylene vinyl acetate copolymer.
Claim 2
Dependent Claim 85 words
An oriented multilayer film comprising: a cross-linked core layer comprising either (a) an ethylene vinyl acetate copolymer or (b) a three component blend of (1) a linear low density polyethylene, (2) a linear medium density polyethylene and (3) an ethylene vinyl acetate copolymer; two cross-linked interior layers each comprising a linear low density polyethylene; and two cross-linked surface layers each comprising a three component blend cf (1) a linear low density polyethylene, (2) a linear medium density polyethylene, and (3) an ethylene vinyl acetate copolymer.
Claim 3
Dependent Claim 153 words
An oriented multilayer film according to claim 1 having 5 layers and comprising: a cross-linked core layer comprising either (a) an ethylene vinyl acetate copolymer or (b) a three component blend of (1) from about 40%, by weight, to about 60%, by weight, of a linear low density polyethylene, (2) from about 20%, by weight, to about 30%, by weight, of a linear medium density polyethylene and (3) from about 20%, by weight, to about 30%, by weight, of an ethylene vinyl acetate copolymer; two cross-linked intermediate layers each comprising a linear low density polyethylene; and two cross-linked surface layers each comprising a three component blend of (1) from about 40% to about 60%, by weight, of a linear low density polyethylene, (2) from about 20% to about 30%, by weight, of a linear medium density polyethylene, and (3) from about 20% to about 30%, by weight, of an ethylene vinyl acetate copolymer.
Claim 4
Dependent Claim 295 words
An oriented multilayer film according to claim 1 having 5 layers and comprising: a cross-linked core layer consisting essentially of either (a) about 100%, by weight, of an ethylene vinyl acetate copolymer comprising from about 3.3% to about 4.1% vinyl acetate derived units, said ethylene vinyl acetate copolymer having a density of from about 0.9232 to about 0.9250 grams per cubic centimeter at 23°C or (b) a three component blend of (1) about 55%, by weight, of a linear low density polyethylene having a density of about 0.920 grams per cubic centimeter at 23°C, (2) about 28%, by weight, of a linear medium density polyethylene having a density of about 0.935 grams per cubic centimeter at 23°C and (3) about 17%, by weight, of an ethylene vinyl acetate copolymer comprising from about 3.3% to about 4.1% vinyl acetate derived units, said ethylene vinyl acetate copolymer having a density of from about 0.9232 to about 0.9250 grams per cubic centimeter at 23°C; two cross-linked intermediate layers each consisting essentially of about 100%, by weight, of a linear low density polyethylene having a density of about 0.920 grams per cubic centimeter at 23°C; and two cross-linked surface layers each consisting essentially of a three component blend of (1) about 50%, by weight, of a linear low density polyethylene having a density of about 0.920 grams per cubic centimeter at 23°C, (2) about 25%, by weight, of a linear medium density polyethylene having a density of about 0.935 grams per cubic centimeter at 23°C, and (3) about 25%, by weight, of an ethylene vinyl acetate copolymer comprising fran about 3.3% to about 4.1% vinyl acetate derived units, said ethylene vinyl acetate compolymer having a density of from about 0.9232 to about 0.9250 grams per cubic centimeter at 23°C.
Claim 5
Dependent Claim 25 words
An oriented multilayer film according to claim 1 in which the two cross-linked surface layers each also comprise (4) at least one ultraviolet light stabilizer.
Claim 6
Dependent Claim 43 words
An oriented multilayer film according to claim 2 adapted for use as a storm window in which the two cross-linked surface layers each also comprise (4) from about 500 ppm to about 3,000 ppm of at least one hindered amine ultraviolet light stabilizer.
Claim 7
Dependent Claim 40 words
A multilayer film according to claim 3 adapted for use as an exterior storm window in which the two cross-linked surface layers each also contain (4) about 1,500 parts per million of at least one hindered amine ultraviolet light stabilizer.
Claim 8
Dependent Claim 22 words
A multilayer film according to claim 4 comprising from about 500 to about 3,000 parts per million of said ultraviolet light stabilizer.
Claim 9
Dependent Claim 23 words
A multilayer film according to claim 4 or 5 comprising about 1,000 to about 2,000 parts per million of said ultraviolet light stabilizer.
Claim 10
Dependent Claim 23 words
A multilayer film according to-claim 5 or 6 which has been cross-linked with from about 3 MR to about 8 MR of irradiation.
Claim 11
Dependent Claim 22 words
A multilayer film according to claim 9 which has been cross-linked with from about 5 MR to about 7 MR of irradiation.
Claim 12
Dependent Claim 38 words
A multilayer film according to any one of claims 5, 6, 9 or 10 which has been oriented by racking at a racking ratio of from about 3.0 to about 4.0 in both the longitudinal and transverse directions.
Claim 13
Dependent Claim 31 words
A multilayer film according tc claim 11 which has been oriented by racking at a racking ratio of fran about 3.0 to about 3.5 in both the longitudinal and transverse directions.
Claim 14
Dependent Claim 24 words
A multilayer film according to claim 2 or 3 which has been cross-linked with from about 1 MR to about 5 MR of irradiation.
Claim 15
Dependent Claim 22 words
A multilayer film according to claim 13 which has been cross-linked with fran about 2 MR to about 4 MR of irradiation.
Claim 16
Dependent Claim 37 words
A multilayer film according to any of claims 2, 3, 13 or 14 which has been oriented by racking at a racking ratio of from about 4.0 to about 6.0 in both the longitudinal and transverse directions.
Claim 17
Dependent Claim 31 words
A multilayer film according to claim 15 which has been oriented by racking at a racking ratio of from about 4.5 to about 5.5 in both the longitudinal and transverse directions.
Claim 18
Dependent Claim 32 words
A multilayer film according to claim 2 or 5 in which said ethylene vinyl acetate copolymer comprises from about 2%, by weight, to about 18%, by weight, of vinyl acetate derived units.
Claim 19
Dependent Claim 29 words
A multilayer film according to claim 17 in which said vinyl acetate copolymer comprises fran about 2%, by weight, to about 10%, by weight, of vinyl acetate derived units.
Claim 20
Dependent Claim 23 words
A multilayer film according to any of claims 1 to 18 further comprising a colorant additive to at least one of said layers.
Claim 21
Dependent Claim 19 words
-20. A multilayer film according to claim 19 in which the colorant additive is solely in said core layer.
Claim 22
Dependent Claim 123 words
2 1. A multilayer film according to any of claims 1 to 20 in which the two surface layers are substantially equal to each other and the sum of the thicknesses of the two surface layers comprise fran about 40% to about 60% of the total thickness of the film, (b) the thicknesses of the two intermediate layers are substantially equal to each other and the sum of the thicknesses of the two intermediate layers comprises fran about 40% to about 60% of the total thickness of the film, (c) the thickness of the core layer comprises from about 10% to about 30% of the total film thickness and (d) the total film thickness is from about 50 gauge to about 200 gauge.

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