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EP0166144A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Homogeneous low melting temperatures brazing filler metal for joining ferrous and non-ferrous alloys

Assignee: Honeywell International Inc
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Filing: 1985-05-10
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Granted: —
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Expires: 2005-05-10
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Abstract

Abstract Most of the low melting brazing filler alloys for brazing of various steels and alloys in the range of 550°-850°C are silver-base. These alloys (BAg-series according to the American Welding Society) contain from 30 to 93wt% of silver and substantial amounts of melting temperature depressing elements like zinc and cadmium. Both zinc and cadmium increase wettability and flow during brazing. However, the presence of precious silver and carcinogenic cadmium in BAg-series alloys has always been a stimulus to develop new low-silver or silver and cadmium free alloys with brazing performance at least similar to those of BAg-series. For these purposes, copper-base alloys particularly those derived from the Cu-Mn-Si system, seem to be a natural choice. This system has a ternary eutectic with melting temperature in the vicinity of 800°C and it consists of elements which dissolve readily in both iron and copper. Low melting temperature copper-base brazing filler metals, which have low silver concentration and are cadmium free, are disclosed here. These filler metals contain (at%): 0-10 silver, 4-16 manganese, 4-16 silicon, 0-20 zinc, 0-16 tin and 0-10 indium, the balance being copper and incidental impurities. These alloys are produced in a homogeneous ductile, metastable foil shape or as a homogeneous metastable powder by rapid solidification processing. A successful brazing is achieved for any combinations of steels, copper and its alloys, cemented carbides and various composite materials.

Inventors

  • 👤 Anatol Rabinkin
  • 👤 Amitava Datta

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-28 13:42
CPC Classifications
B; B23; B23K; B23K35/00; B23K35/02; B23K35/0222; B23K35/0233; B23K35/22; B23K35/24; B23K35/30; B23K35/302; B23K35/0244; Y; Y10; Y10T; Y10T428/00; Y10T428/12; Y10T428/12431

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 59 words
A metal alloy having a composition consisting essentially of about 4 to 16 atom percent manganese, about 4 to 16 atom percent silicon, about 0 to 16 atom percent tin, about 0 to 20 atom percent zinc, about 0 to 10 atom percent silver and about 0 to 10 atom percent indium, the balance being copper and incidental impurities.
Claim 2
Dependent Claim 59 words
A metal alloy having a composition consisting essentially of about 4 to 16 atom percent manganese, about 4 to 16 atom percent silicon, about 0 to 16 atom percent tin, about 0 to 20 atom percent zinc, about 0 to 10 atom percent silver and about 0 to 10 atom percent indium, the balance being copper and incidental impurities.
Claim 3
Dependent Claim 19 words
A metal alloy composition as recited in claim 1, wherein said composition is in the form of a foil.
Claim 4
Dependent Claim 14 words
A metal alloy composition as recited in claim 2, wherein said foil is ductile.
Claim 5
Dependent Claim 16 words
A metal alloy composition as recited in claim 2, wherein said foil has a metastable structure.
Claim 6
Dependent Claim 14 words
A metal alloy composition as recited in claim 4, wherein said structure is homogeneous.
Claim 7
Dependent Claim 19 words
A metal alloy composition as recited in claim 1, wherein said composition is in the form of a powder.
Claim 8
Dependent Claim 65 words
A metal alloy composition as recited in claim 1, having a composition consisting essentially of about 10 to 12 atom percent manganese, about 10 to 12 atom percent silicon, about 3 to 5 atom percent tin, about 4 to 10 atom percent zinc, about 2 to 5 atom percent silver, about 1 to 5 atom percent indium and about 51 to 70 atom percent copper.
Claim 9
Dependent Claim 61 words
A homogeneous, ductile brazing foil having a composition consisting essentially of about 4 to 16 atom percent manganese, about 4 to 16 atom percent silicon, about 0 to 16 atom percent tin, about 0 to 20 atom percent zinc, about 0 to 10 atom percent silver and about 0 to 10 atom percent indium, the balance being copper and incidental impurities.
Claim 10
Dependent Claim 61 words
A homogeneous, ductile brazing foil having a composition consisting essentially of about 4 to 16 atom percent manganese, about 4 to 16 atom percent silicon, about 0 to 16 atom percent tin, about 0 to 20 atom percent zinc, about 0 to 10 atom percent silver and about 0 to 10 atom percent indium, the balance being copper and incidental impurities.
Claim 11
Dependent Claim 91 words
A process for fabricating homogeneous ductile foil having a composition consisting essentially of about 4 to 16 atom percent manganese, about 4 to 16 atom percent silicon, about 0 to 16 atom percent tin, about 0 to 20 atom percent zinc, about 0 to 10 atom percent silver and about 0 to 10 atom percent indium, the balance being copper and incidental impurities, which process comprises forming a melt of the composition and quenching the melt on a rotating chill block at a rate of at least about 10 5 °C/sec.
Claim 12
Dependent Claim 91 words
A process for fabricating homogeneous ductile foil having a composition consisting essentially of about 4 to 16 atom percent manganese, about 4 to 16 atom percent silicon, about 0 to 16 atom percent tin, about 0 to 20 atom percent zinc, about 0 to 10 atom percent silver and about 0 to 10 atom percent indium, the balance being copper and incidental impurities, which process comprises forming a melt of the composition and quenching the melt on a rotating chill block at a rate of at least about 10 5 °C/sec.
Claim 13
Dependent Claim 129 words
A process for joining together two or more metal parts which comprises: a) interposing a filler metal between the metal parts to form an assembly, the filler metal having a melting point less than that of any of the parts; b) heating the assembly to at least the melting temperature of the filler metal; and c) cooling the assembly; wherein the improvement comprises employing, as the filler metal, a homogeneous, ductile copper based foil having a composition consisting essentially of about 4 to 16 atom percent manganese, about 4 to 16 atom percent silicon, about 0 to 16 atom percent tin, about 0 to 20 atom percent zinc, about 0 to 10 atom percent silver, about 0 to 10 atom percent indium, the balance being copper and incidental impurities.
Claim 14
Dependent Claim 129 words
A process for joining together two or more metal parts which comprises: a) interposing a filler metal between the metal parts to form an assembly, the filler metal having a melting point less than that of any of the parts; b) heating the assembly to at least the melting temperature of the filler metal; and c) cooling the assembly; wherein the improvement comprises employing, as the filler metal, a homogeneous, ductile copper based foil having a composition consisting essentially of about 4 to 16 atom percent manganese, about 4 to 16 atom percent silicon, about 0 to 16 atom percent tin, about 0 to 20 atom percent zinc, about 0 to 10 atom percent silver, about 0 to 10 atom percent indium, the balance being copper and incidental impurities.

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