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EP0160957A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Adherent ultraviolet cured coatings

Assignee: DeSoto Inc
•
Filing: 1985-05-04
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Granted: —
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Expires: 2005-05-04
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Abstract

Abstract An ultraviolet-curable liquid coating composition is disclosed which exhibits improved adhesion to metal and plastic surfaces. This composition comprises, in admixture: (1) from 10% to 60% of the mixture of an organic solvent- soluble solution copolymer of monoethylenically unsaturated monomers free of amine functionality and including from 5% to 20% of an amide of a monoethylenically unsaturated monocarboxylic acid, especially dimethyl acrylamide; and (2) from 40% to 90% of the mixture of radiation-curable ethylenically unsaturated liquid, preferably including a polyacrylate, such as pentaerythritol polyacrylate, said coating composition including photoinitiators and/or photosensitizers, and especially ketonic photoin- i tiators, rendering the composition sensitive to ultraviolet light. These components are usually present in solution in an organic solvent. The copolymer desirably contains from 0.5% to 10% of a monoethylenically unsaturated carboxylic acid, like acrylic or methacrylic acid, and may contain at least 2% of an alkanol ether of N-methylol acrylamide or N-methylol methacrylamide and a strong acid catalyst may be present to enable a low temperature cure following the ultraviolet cure. A polyepoxide may also be present in the composition to aid intercoat adhesion.

Inventors

  • 👤 Edward J. Murphy
  • 👤 Elias P. Moschovis

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-26 21:13
CPC Classifications
C; C09; C09D; C09D4/00; C09D4/06

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 82 words
An ultraviolet-curable liquid coating composition exhibiting improved adhesion to metal and plastic surfaces comprising, in admixture; (1) from 10% to 60% of the mixture of an organic solvent- soluble solution copolymer of monoethylenically unsaturated monomers free of amine functionality and including from 5% to 20% of an amide of a monoethylenically unsaturated monocarboxylic acid; and (2) from 40% to 90% of the mixture of radiation-curable ethylenically unsaturated liquid, said coating composition including photoinitiators and/or photosensitizers rendering the composition sensitive to ultraviolet light.
Claim 2
Dependent Claim 82 words
An ultraviolet-curable liquid coating composition exhibiting improved adhesion to metal and plastic surfaces comprising, in admixture; (1) from 10% to 60% of the mixture of an organic solvent- soluble solution copolymer of monoethylenically unsaturated monomers free of amine functionality and including from 5% to 20% of an amide of a monoethylenically unsaturated monocarboxylic acid; and (2) from 40% to 90% of the mixture of radiation-curable ethylenically unsaturated liquid, said coating composition including photoinitiators and/or photosensitizers rendering the composition sensitive to ultraviolet light.
Claim 3
Dependent Claim 36 words
A coating composition as recited in claim 1 in which said ethylenically unsaturated liquid includes polyethylenically unsaturated material and the named components are present in solution in at least about 10% of inert volatile organic solvent.
Claim 4
Dependent Claim 46 words
A coating composition as recited in claim 2 in which said solution contains from 25% to 50% of said solvent which contains at least 30% of a c 1 to C 4 alkanol. said copolymer includes from 0.5% to 10% of copolymerized monoethylenically unsaturated carboxylic acid.
Claim 5
Dependent Claim 20 words
A coating composition as recited in claim 2 in which said amide is an amide of acrylic or methacrylic acid.
Claim 6
Dependent Claim 45 words
A coating composition as recited in claim 4 in which at least 40% of said copolymer is copolymerized methyl methacrylate, at least 15% of the copolymer is copolymerized C 2 -C 12 alkyl ester of acrylic or methacrylic acid, and said amide is dimethyl acrylamide.
Claim 7
Dependent Claim 32 words
A coating composition as recited in claim 4 in which said composition further includes from 2% to 20% of a polyepoxide having a molecular weight of from about 500 to about 5,000.
Claim 8
Dependent Claim 25 words
A coating composition as recited in claim 2 in which said components (1) and (2) are present in a weight ratio of 40:60 to 60:40.
Claim 9
Dependent Claim 18 words
A coating composition as recited in claim 1 in which said polyethylenically unsaturated liquid is an hydroxy-functional polyacrylate.
Claim 10
Dependent Claim 43 words
- 9. A coating composition as recited in claim 1 in which said coating composition includes from 3% to 30% of the weight of said mixture of ethylenically unsaturated liquid selected from the group consisting of triallyl cyanurate, N-vinyl pyrrolidone and dimethyl acrylamide.
Claim 11
Dependent Claim 22 words
A coating composition as recited in claim 1 in which said composition is rendered sensitive to ultraviolet light using a ketonic photoinitiator.

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