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EP0157212A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Articles coated with adherent diamondlike carbon films

Assignee: Wyeth Holdings LLC
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Filing: 1985-03-07
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Granted: —
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Expires: 2005-03-07
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Abstract

Abstract Substrates, especially highly thermally expandable materials, such as plastics are adherently coated with a relatively soft layer comprising carbon and thereafter with a relatively harder layer of diamondlike carbon to provide coated articles that are abrasion resistant, electrically insulating, and resistant to chemical attack. If the substrate is transparent, the protectively coated article is transparent too.

Inventors

  • 👤 Robert Domenico Giglia
  • 👤 Richard Howard Clasen

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-26 12:49
CPC Classifications
C; C23; C23C; C23C16/00; C23C16/02; C23C16/0272; C08; C08J; C08J7/00; C08J7/04; C08J7/043; C08J7/046; C08J7/06; C23C14/00; C23C14/06; C23C14/0605; C23C16/22; C23C16/26; Y; Y10; Y10T; Y10T428/00; Y10T428/24; Y10T428/24942; Y10T428/2495; Y10T428/24967; Y10T428/24975; Y10T428/30; Y10T428/31504; Y10T428/31507; Y10T428/31678; Y10T428/31721; Y10T428/31725; Y10T428/31786; Y10T428/31855; Y10T428/31931; Y10T428/31938

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 40 words
An article comprising: (i) a solid substrate; (ii) an intermediate, relatively soft, layer adjacent at least one surface of said substrate, said layer comprising carbon; and (iii) adjacent said intermediate layer an outer, relatively hard, protective layer, comprising diamondlike carbon.
Claim 2
Dependent Claim 40 words
An article comprising: (i) a solid substrate; (ii) an intermediate, relatively soft, layer adjacent at least one surface of said substrate, said layer comprising carbon; and (iii) adjacent said intermediate layer an outer, relatively hard, protective layer, comprising diamondlike carbon.
Claim 3
Dependent Claim 33 words
An article as defined in Claim 1 wherein said intermediate layer (ii) comprises carbon and hydrogen, is approximately 100 to 5000 Angstroms in thickness and can be scratched by rubbing with steel wool.
Claim 4
Dependent Claim 32 words
An article as defined in Claim 1 wherein said outer, protective layer (iii) comprises carbon, is approximately 1000 to 20,000 Angstroms in thickness and cannot be scratched by rubbing with steel wool.
Claim 5
Dependent Claim 78 words
An article as defined in Claim 1, wherein said intermediate layer (ii) comprises carbon and hydrogen, is approximately 100 to 5000 Angstroms in thickness, and can be scratched by steel wool, and said outer protective layer (iii) comprises carbon and hydrogen, is approximately 1000 to 20,000 Angstroms in thickness, and which cannot be scratched by rubbing with steel wool, the amount of hydrogen relative to carbon being nil or substantially less in layer (iii) than in layer (ii).
Claim 6
Dependent Claim 15 words
An article as defined in Claim 1, wherein said substrate (i) is comprised of plastic.
Claim 7
Dependent Claim 35 words
An article as defined in Claim 5, wherein said plastic is a synthetic organic polymer selected from the group consisting of acrylics, polycarbonates, polyesters, polyamides, polyimides, styrene-acrylonitril E copolymers, styrene-acrylonitrile-butadiene terpolymers, and vinyl halide polymers.
Claim 8
Dependent Claim 14 words
An article as defined in Claim 6, wherein said synthetic organic polymer is transparent.
Claim 9
Dependent Claim 25 words
An article as defined in Claim 7, wherein said synthetic organic polymer is selected from the group consisting of poly(methyl methacrylate), polycarbonate, and polyvinyl chloride.
Claim 10
Dependent Claim 66 words
A protectively coated article comprising: (i) a solid substrate having a coefficient of thermal expansion substantially greater than diamondlike carbon; (ii) an intermediate layer of relatively soft carbon adjacent at least one surface of said substrate; and (iii) an outer, relatively hard, protective layer of diamondlike carbon adjacent said intermediate bonding layer, wherein said outer layer is adherently bonded to said substrate by said intermediate layer.
Claim 11
Dependent Claim 66 words
A protectively coated article comprising: (i) a solid substrate having a coefficient of thermal expansion substantially greater than diamondlike carbon; (ii) an intermediate layer of relatively soft carbon adjacent at least one surface of said substrate; and (iii) an outer, relatively hard, protective layer of diamondlike carbon adjacent said intermediate bonding layer, wherein said outer layer is adherently bonded to said substrate by said intermediate layer.
Claim 12
Dependent Claim 33 words
An article as defined in Claim 9 wherein said intermediate layer (ii) comprises carbon and hydrogen, is approximately 100 to 5000 Angstroms in thickness and can be scratched by rubbing with steel wool.

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