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EP0156148A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

High impact strength fiber resin matrix composites

Assignee: Wyeth Holdings LLC
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Filing: 1985-02-13
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Granted: —
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Expires: 2005-02-13
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Abstract

Abstract Improved fiber resin matrix prepreg fabrics are disclosed which are comprised of a first layer of reinforcing fabric coated with an epoxy resin composition and a discrete second layer of an epoxy resin modified with an elastomeric polymer. The discrete second layer is provided with a support comprising a gauze-like, lightweight fibrous mat or carrier of lightweight fibers that preserves the second "interleaf' layer during cure. Cured composites having the continuous interleaf layer intact exhibit high impact strength and resistance to j impact damage. In addition, high-performance fiber resin matrix composites are disclosed which are comprised of a first layer comprising reinforcing filaments coated with a thermosetting resin composition and a discrete second layer of a thermoplastic resin. When the composite layers are matched to provide certain minimum strength and elongation properties, composites of unusually high impact strength and resistance to impact damage are achieved which retain their high performance properties over a range of temperatures and environmental exposures.

Inventors

  • 👤 Kevin Richard Hirschbuehler
  • 👤 Bruce Allen Stern
  • 👤 Robert E. Evans

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-27 15:26
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/24; C08J5/241; C08J5/243; B; B29; B29C; B29C70/00; B29C70/04; B29C70/06; B29C70/08; B32; B32B; B32B27/00; B32B27/12; B29C70/086; B32B27/06; B32B27/08; B32B27/38; B32B38/00; B32B38/08; B32B5/00; B32B5/22; B32B5/24; B32B5/28; C08J5/249; B29K; B29K2101/00; B29K2101/10; B29K2101/12; B29K2105/00; B29K2105/06; B29K2105/08; B29K2105/0809; B29K2105/0854; B29K2105/10; B29K2105/101; C08J2363/00

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 99 words
A method for producing an interleafed fiber resin matrix prepreg fabric comprising (1) incorporating a non-woven or woven fibrous mat or carrier of lightweight supporting filaments into an interleaf resin composition comprising (a) a first thermosetting epoxy resin composition containing (b) about 8% to 70% by weight of a rubbery vinyl addition polymer to provide a supported interleaf resin layer; and (2) introducing said supported interleaf resin layer to at least one surface of a fiber resin matrix comprising (a) a fabric of high-strength reinforcing filaments and (b) a second thermosetting epoxy resin composition coating and impregnating said fabric.
Claim 2
Independent Claim 99 words
A method for producing an interleafed fiber resin matrix prepreg fabric comprising (1) incorporating a non-woven or woven fibrous mat or carrier of lightweight supporting filaments into an interleaf resin composition comprising (a) a first thermosetting epoxy resin composition containing (b) about 8% to 70% by weight of a rubbery vinyl addition polymer to provide a supported interleaf resin layer; and (2) introducing said supported interleaf resin layer to at least one surface of a fiber resin matrix comprising (a) a fabric of high-strength reinforcing filaments and (b) a second thermosetting epoxy resin composition coating and impregnating said fabric.
Claim 3
Dependent Claim 78 words
The method of Claim 1, wherein said first thermosetting epoxy resin composition exhibits shear modulus of at least 50,000 psi and yield strength of at least 3,000 psi at high temperatures, and shear strain to failure of at least 6% at -67°F and at least 15% at room temperature; and said second thermosetting epoxy resin composition exhibits shear modulus of at least 90,000 psi at high temperatures or at least 50,000 psi at high temperatures under wet conditions.
Claim 4
Dependent Claim 25 words
The method of Claim 1, wherein said supporting filaments are selected from the group consisting of lightweight glass, carbon, graphite, polyaramide, polyester, and cellulosic filaments.
Claim 5
Dependent Claim 22 words
The method of Claim 1, wherein said fabric is comprised of interwoven tows containing from about 1,000 to 12,000 high-strength reinforcing filaments.
Claim 6
Dependent Claim 34 words
The method of Claim 4, wherein said reinforcing filaments are selected from the group consisting of glass, carbon, graphite, silicon carbide, boron, polyaramide, polyester, polyamide, rayon, polybenzimidazole, and polybenzothiazole filaments, and metal-coated such filaments.
Claim 7
Independent Claim 60 words
The method of Claim I,'wherein said rubbery vinyl addition polymer comprises about 8% to 24% by weight of said interleaf resin composition, said second thermosetting epoxy resin composition comprises about 35% to 60% by weight of said fiber resin matrix, and said fibrous mat or carrier comprises less than 5% by weight of the interleafed fiber resin matrix prepreg fabric.
Claim 8
Dependent Claim 21 words
The method of Claim 6, wherein a crosslinked interface is formed between said interleaf resin layer and said fiber resin matrix.
Claim 9
Dependent Claim 57 words
The method of Claim 1, wherein said first and second thermosetting epoxy resin compositions are, independently, comprised of epoxy compounds selected from the group consisting of polyglycidyl ethers of polyfunctional phenols, polyglycidyl ethers of the chlorination or bromination products of polyvalent phenols, polyglycidyl ethers of novolacs, polyepoxy compounds deprived from aromatic amines and epichlorohydrin, and mixtures thereof.
Claim 10
Dependent Claim 24 words
The method of Claim 2, wherein said first and second thermosetting epoxy resin compositions both exhibit an ultimate shear stress above about 3,000 psi.
Claim 11
Dependent Claim 14 words
The method of Claim 8, wherein said epoxy resin compositions further include curing agents.

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