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EP0135348A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Improvements in or relating to radiation sensitive compounds

Assignee: Agfa Gevaert NV
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Filing: 1984-08-09
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Granted: —
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Expires: 2004-08-09
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Abstract

Abstract A radiation-sensitive compound has the general formula wherein A represents the ring members required to complete a 5-or 6-membered heterocyclic ring which may optionally be fused to an optionally substituted aromatic nucleus, B represents H, acyl, aroyl, heterocyclyl carbonyl or R represents an optionally substituted alkyl group, E and G, which may be the same or different, each represents H or CH p X 3-p , J and K, which may be the same or different, each represents an aryl or heterocyclic group, which may optionally include a substituent additional to E or G, X represents CI or Br, and m, n and p, which may be the same or different, each represents an integer equal to 0, 1 or 2. The compound can be used to form radiation sensitive compositions for the production of radiation sensitive plates in lithographic printing plate manufacture.

Inventors

  • 👤 John Robert Wade

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-31 02:07
CPC Classifications
C; C07; C07D; C07D409/00; C07D409/02; C07D409/06; C07D209/00; C07D209/02; C07D209/04; C07D209/10; C07D209/12; C07D215/00; C07D215/02; C07D215/12; C07D215/14; C07D277/00; C07D277/60; C07D277/62; C07D277/64; C07D277/84; C07D293/00; C07D293/10; C07D293/12; C07D417/00; C07D417/02; C07D417/06; G; G03; G03C; G03C1/00; G03C1/675; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/028; G03F7/029; G03F7/0295; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/114; Y10S430/117; Y10S430/12; Y10S430/121; Y10S430/124; Y10S430/125; Y10S430/126; Y10S430/127

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 177 words
A method of manufacturing a radiation-sensitive compound having the general formula wherein A represents the ring members required to complete a 5- or 6-membered heterocyclic ring which may optionally be fused to an optionally substituted aromatic nucleus, B represents H, acyl, aroyl, heterocyclyl carbonyl or R represents an optionally substituted alkyl group, E and G, which may be the same or different, each represents H or CH p X 3-p , J and K, which may be the same or different, each represents an aryl or heterocyclic group, which may optionally include a substituent additional to E or G, X represents Cl or Br, and m,n and p, which may be the same or different, each represents an integer equal to 0, 1 or 2, which comprises reacting an acid halide having the formula with either a quaternary heterocyclic salt having the formula or a methylene base derivative of a quaternary heterocyclic compound having the formula where Z is halogen and A,B, R ,E,J, X and m have the meanings given above, to obtain the desired compound.
Claim 2
Independent Claim 177 words
A method of manufacturing a radiation-sensitive compound having the general formula wherein A represents the ring members required to complete a 5- or 6-membered heterocyclic ring which may optionally be fused to an optionally substituted aromatic nucleus, B represents H, acyl, aroyl, heterocyclyl carbonyl or R represents an optionally substituted alkyl group, E and G, which may be the same or different, each represents H or CH p X 3-p , J and K, which may be the same or different, each represents an aryl or heterocyclic group, which may optionally include a substituent additional to E or G, X represents Cl or Br, and m,n and p, which may be the same or different, each represents an integer equal to 0, 1 or 2, which comprises reacting an acid halide having the formula with either a quaternary heterocyclic salt having the formula or a methylene base derivative of a quaternary heterocyclic compound having the formula where Z is halogen and A,B, R ,E,J, X and m have the meanings given above, to obtain the desired compound.
Claim 3
Dependent Claim 35 words
A method according to claim 1 wherein the reactants are sucn that tne radiation sensitive compound is 3-methyl-2-(4'- trichloromethylbenzoylmethylene)-benzothiazoline; 3-methyl- 2-(4'-trichloromethylbenzoyl methylene)-benzoselenazoline;3-ethyl-2-(4'-trichloro -methylbenzoylmethylene)-naphtho(1,2-d)thiazoline; 3-methyl- 2,2- bis-(4'-trichloromethylbenzoyl- methylene)-benzothiazoline; 1,3,3-trimethyl-2-(4'-trichloromethylbenzoyl)methylene indoline; 1,3,3-trimethyl-2-(4'-trichloromethyl benzoyl)methylene-5-chloro-indoline; or l-methyl-2-(4'- trichloromethyl benzoylmethylene)-quinoline.
Claim 4
Dependent Claim 33 words
A method according to claim 1 or 2 and comprising the additional step of forming a radiation sensitive composition by admixing the radiation sensitive compound with a photopolymerisable compound activated by free radicals.
Claim 5
Dependent Claim 19 words
A method according to claim 3 wherein the photopolymerisable compound is an addition polymerisable compound containing ethylenic unsaturation .
Claim 6
Dependent Claim 30 words
A method according to claim 1 or 2 and comprising the additional step of forming a radiation sensitive composition by admixing the radiation sensitive compound with an acid hardenable material.
Claim 7
Dependent Claim 40 words
A method according to claim 1 or 2 and comprising the additional step of forming a radiation sensitive composition by admixing the radiation sensitive compound with a substance which undergoes a colour change when said compound is exposed to radiation.
Claim 8
Dependent Claim 18 words
A method according to claim 6 wherein said substance is a dye, a dye precursor, or an indicator.
Claim 9
Dependent Claim 30 words
A method according to claim 1 or 2 and comprising the additional step of forming a radiation sensitive composition by admixing the radiation sensitive compound with an acid degradable compound.
Claim 10
Independent Claim 32 words
A method according to any one of claims 3 to 8 and comprising the additional step of forming a radiation sensitive plate by coating the radiation sensitive composition on to a substrate.

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