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EP0134664A1 Expired / Lapsed EP ⏱️ 0.0 years remaining

Improvements in or relating to the ozone oxidation of deposits in cooling systems of nuclear reactors

Assignee: Westinghouse Electric Corp
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Filing: 1984-07-11
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Granted: —
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Expires: 2004-07-11
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Abstract

Abstract Process for oxidizing chromium in deposits in the cooling system of a nuclear reactor using a solution of ozone which consists of adding to the solution from 0.01 to 0.5% of a water-soluble cerium IV compound, from 0.1 to 0.5% of a water-soluble aromatic compound having at least one ketone group on an aromatic ring, or adding both. Further a composition of water, ozone, the cerium IV compound and the aromatic compound. Also a process for decontaminating the cooling system of nuclear reactors by adding a decontamination composition to the coolant, circulating the coolant between the cooling system and a cation exchange resin, removing the decontamination composition by passing it through an anion exchange resin, adjusting the temperature to 40 to 100°C, adding the ozone oxidation composition, circulating the coolant through the cooling system, raising the temperature to at least 100°C, passing the coolant through an anion exchange resin or a mixed resin, adjusting the temperature to frm 60 to 100°C and repeating the addition of the decontamination composition and its removal.

Inventors

  • 👤 Alexander Peter Murray
  • 👤 Lawrence Frederick Becker, Jr.
  • 👤 Clifton Greene Slater
  • 👤 Michael Charles Skriba

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-03 01:14
CPC Classifications
G; G21; G21F; G21F9/00; G21F9/001; G21F9/002; G21F9/004; G21C; G21C15/00; G21C15/28; Y; Y02; Y02E; Y02E30/00; Y02E30/30

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 68 words
A process for oxidizing chromium in deposits in the cooling system of a nuclear reactor using an aqueous solution of ozone, which comprises employing in said solution either (a) 0.01 to 0.5% of at least one water-soluble cerium IV compound, (b) 0.01 to 0.5% of at least one water-soluble aromatic compound having at least one ketone group on an aromatic ring, or (c) mixtures of (a) and (b).
Claim 2
Dependent Claim 68 words
A process for oxidizing chromium in deposits in the cooling system of a nuclear reactor using an aqueous solution of ozone, which comprises employing in said solution either (a) 0.01 to 0.5% of at least one water-soluble cerium IV compound, (b) 0.01 to 0.5% of at least one water-soluble aromatic compound having at least one ketone group on an aromatic ring, or (c) mixtures of (a) and (b).
Claim 3
Dependent Claim 15 words
A process according to claim 1, wherein the cerium IV compound is ceric ammonium nitrate.
Claim 4
Dependent Claim 14 words
A process according to claim 1 or 2, wherein the aromatic compound is quinone.
Claim 5
Dependent Claim 20 words
A process according to claim 1, 2 or 3, wherein the solution comprises the aqueous coolant of the nuclear reactor.
Claim 6
Dependent Claim 27 words
A process according to any of claims 1 to 4, wherein the solution containing (a), (b) or (c) is made up and passed through the cooling system.
Claim 7
Dependent Claim 24 words
A process according to any of claims 1 to 5, wherein the cooling system is in the steam generator of a pressurized water reactor.
Claim 8
Dependent Claim 47 words
A composition which comprises water, dissolved ozone, and either (a) 0.01 to 0.5% of a water-soluble cerium IV compound, (b) 0.01 to 0.5% of at least one water-soluble aromatic compound having at least one ketone group on an aromatic ring, or (c) mixtures of (a) and (b).
Claim 9
Dependent Claim 47 words
A composition which comprises water, dissolved ozone, and either (a) 0.01 to 0.5% of a water-soluble cerium IV compound, (b) 0.01 to 0.5% of at least one water-soluble aromatic compound having at least one ketone group on an aromatic ring, or (c) mixtures of (a) and (b).
Claim 10
Dependent Claim 15 words
A composition according to claim 7, wherein the cerium IV compound is ceric ammonium nitrate.
Claim 11
Dependent Claim 12 words
A composition according to claim 8, wherein the aromatic compound is quinone.
Claim 12
Dependent Claim 169 words
A process for decontaminating the cooling system of a nuclear reactor which comprises the steps of shutting down said reactor, adding a decontamination composition to the coolant in said cooling system, circulating said coolant between a cation exchange resin and said cooling system until the radioactivity in said coolant leaving said cooling system is not substantially greater than the radioactivity of said coolant entering said cooling system, removing said decontamination composition from said coolant by passing said coolant through an anion exchange resin, adjusting the temperature of said coolant to from 40 to 100°C, adding compounds to said coolant so that said coolant comprises a composition according to claim 7, 8 or 9, circulating said coolant in said cooling system until the chromium concentration no longer increases substantially, raising the temperature of said coolant to at least 100°C, passing said coolant through an ion exchange resin containing an anion resin, adjusting the temperature of said coolant to from 60 to 200°C, and repeating the second, third and fourth steps.
Claim 13
Dependent Claim 17 words
A process according to claim 10, wherein the decontamination composition is an organic acid and a chelate.

References Cited (Backward Citations)

DE2358683A1 Cited
FR2347752A1 Cited
US4287002A Cited

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