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EP0125907A1 Expired / Lapsed EP ⏱️ 0.0 years remaining

Separation of dewaxing solvent from dewaxed oil in a lube oil dewaxing process using asymmetric polyimide membranes

Assignee: ExxonMobil Technology and Engineering Co
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Filing: 1984-05-11
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Granted: —
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Expires: 2004-05-11
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Abstract

Abstract Dewaxing solvents, particularly ketone solvents and ketone/toluene solvents, are separated from a mixture of dewaxing solvents and dewaxed oil in a lube oil dewaxing process by use of an asymmetric permselective polyimide membrane. Said asymmetric polyimide membrane permits the selective permeation of the ketone or ketone/toluene dewaxing solvents while being less permeable to oil. Said separation is conducted by contacting the ketone or ketone// toluene solvent/oil mixture with the dense side [(1), Figure 1] of the asymmetric polyimide membrane [(4), Figure 1] under pressure. The recovered ketone or ketone/ toluene solvent is of high enough purity to be returned to the dewaxing process without further treatment. The recovered oil is passed to subsequent conventional treatment means (e.g., distillation) for removal of any ketone or ketone/toluene solvent remaining therein.

Inventors

  • 👤 William Wallace Wight

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-10 01:28
CPC Classifications
C; C10; C10G; C10G73/00; C10G73/02; C10G73/06; B; B01; B01D; B01D61/00; B01D61/02; B01D61/025; B01D63/00; B01D63/10; B01D71/00; B01D71/06; B01D71/58; B01D71/62; B01D71/64; B01D71/641; B01D2311/00; B01D2311/02

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 83 words
The solvent dewaxing of waxy hydrocarbon oils wherein the waxy oil is contacted with a dewaxing solvent cooled to precipitate the wax to yield a wax-oil-solvent slurry and wherein the slurry is separated into a wax stream and a solvent/oil stream and wherein the solvent/oil stream is separated into a solvent stream and an oil stream, wherein at least part of the solvent oil separation is conducted under reverse osmosis conditions using a selective permeation barrier which is an permeable asymmetric polyimide membrane.
Claim 2
Dependent Claim 83 words
The solvent dewaxing of waxy hydrocarbon oils wherein the waxy oil is contacted with a dewaxing solvent cooled to precipitate the wax to yield a wax-oil-solvent slurry and wherein the slurry is separated into a wax stream and a solvent/oil stream and wherein the solvent/oil stream is separated into a solvent stream and an oil stream, wherein at least part of the solvent oil separation is conducted under reverse osmosis conditions using a selective permeation barrier which is an permeable asymmetric polyimide membrane.
Claim 3
Dependent Claim 34 words
The process of claim 1 wherein the solvent/oil stream to be separated is contacted with the dense side of the asymmetric polyimide membrane, which polyimide membrane is made from an aromatic, fully imidized polyimide.
Claim 4
Dependent Claim 28 words
The process of claim 1 or claim 2 wherein the solvent recovered by means of the asymmetric polyimide membrane is recycled to the waxy hydrocarbon oil dewaxing process.
Claim 5
Dependent Claim 39 words
The process of any one of claims 1 to 3 wherein the dewaxing solvent is selected from the groups consisting of aliphatic ketones having from 3 to 6 carbons, aromatic hydrocarbons, halogenated low molecular weight hydrocarbons and mixtures thereof.
Claim 6
Dependent Claim 25 words
The process of any one of claims 1 to 4 wherein the dewaxing solvent is a mixture of methyl ethyl ketone and methyl isobutyl ketone.
Claim 7
Dependent Claim 23 words
The process of any one of claims 1 to 4 wherein the dewaxing solvent is a mixture of methyl ethyl ketone and toluene.
Claim 8
Dependent Claim 20 words
The process of any one of claims 1 to 6 wherein the waxy hydrocarbon oil is a waxy petroleum oil.
Claim 9
Dependent Claim 21 words
The process of any one of claims 1 to 7 wherein the waxy hydrocarbon oil is a waxy lubricating oil stock.
Claim 10
Dependent Claim 25 words
The process of any one of claims 1 to 8 wherein the permeable asymmetric polyimide membrane is in the form of a spiral wound element.

References Cited (Backward Citations)

US3556991A Cited

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