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EP0123400A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Fabric conditioning agents, compositions and processes

Assignee: Procter and Gamble Co
•
Filing: 1984-03-14
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Granted: —
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Expires: 2004-03-14
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Abstract

Abstract Through-the-wash fabric conditioning compositions are disclosed especially for use with machine dryers that minimize adverse reactions taking place in the wash that otherwise adversely affect the performance of the separate detergent and fabric conditioning ingredients. This is accomplished by utilizing salts of certain tertiary amines and carboxylic acids in the form of 0.05 to 2 mm. nodules that pass virtually unchanged through the wash and rinse; become entangled in the fabrics when spun or wrung out; and then melt, spread, and condition the fabrics when heated in a dryer.

Inventors

  • 👤 Nabil George Kardouche
  • 👤 Philip Joseph Vincent Giardina

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-10 01:22
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/16; C11D3/20; C11D3/2075; C11D3/0005; C11D3/001; C11D3/26; C11D3/30

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 220 words
A fabric conditioning agent characterised by a salt of (i) a tertiary amine having the formula wherein R 1 , R 2 and R 3 are each, independently, saturated or unsaturated and wherein R 1 is a long chain aliphatic group having from 12 to 22 carbon atoms and R 2 and R 3 are the same or different from each other and are selected from aliphatic groups containing from 1 to 22 carbon atoms, hydroxyalkyl groups of the formula -R 4 OH wherein R 4 is an alkylene group having from 1 to 3 carbon atoms, and alkyl ether groups having the formula R 5 O(C n H 2n O) m - wherein R 5 is hydrogen or an alkyl or alkenyl group having from 1 to 20 carbon atoms, n is 2 or 3, and m is from 1 to 20; and (ii) a carboxylic acid having the formula wherein R 6 is hydrogen, or an alkyl, alkenyl, aryl, alkaryl or aralkyl group having 1 to 22 carbon atoms, or a substituted alkyl, alkenyl, aryl, alkaryl, or aralkyl group having from 1 to 22 carbon atoms wherein the substituents are selected from halogen, carboxyl, and hydroxyl ; wherein said tertiary amine/carboxylic acid salt exists in the form of discrete nodules having a particle size from 0.05 to 2mm.
Claim 2
Dependent Claim 220 words
A fabric conditioning agent characterised by a salt of (i) a tertiary amine having the formula wherein R 1 , R 2 and R 3 are each, independently, saturated or unsaturated and wherein R 1 is a long chain aliphatic group having from 12 to 22 carbon atoms and R 2 and R 3 are the same or different from each other and are selected from aliphatic groups containing from 1 to 22 carbon atoms, hydroxyalkyl groups of the formula -R 4 OH wherein R 4 is an alkylene group having from 1 to 3 carbon atoms, and alkyl ether groups having the formula R 5 O(C n H 2n O) m - wherein R 5 is hydrogen or an alkyl or alkenyl group having from 1 to 20 carbon atoms, n is 2 or 3, and m is from 1 to 20; and (ii) a carboxylic acid having the formula wherein R 6 is hydrogen, or an alkyl, alkenyl, aryl, alkaryl or aralkyl group having 1 to 22 carbon atoms, or a substituted alkyl, alkenyl, aryl, alkaryl, or aralkyl group having from 1 to 22 carbon atoms wherein the substituents are selected from halogen, carboxyl, and hydroxyl ; wherein said tertiary amine/carboxylic acid salt exists in the form of discrete nodules having a particle size from 0.05 to 2mm.
Claim 3
Dependent Claim 85 words
A fabric conditioning agent according to claim 1 wherein R 1 is an aliphatic alkyl chain having from 12 to 22 carbon atoms, R 2 is an aliphatic alkyl chain having from 12 to 22 carbon atoms, and R 3 is an aliphatic alkyl chain having from 1 to 3 carbon atoms; wherein R 6 is a long chain, unsubstituted alkyl or alkenyl group having from 11 to 17 carbon atoms: and wherein the melting point of said discrete nodules is from 35 to 115°C.
Claim 4
Dependent Claim 35 words
A fabric conditioning agent according to claim 1 or 2 wherein the particle size of said nodules is from 0.1 to 1mm and wherein the melting point of said nodules is from 35 to 85°C.
Claim 5
Dependent Claim 51 words
A fabric conditioning agent according to any of claims 1 to 3 wherein R l and R 2 are each, independently, a saturated linear alkyl chain having from 16 to 18 carbon atoms; R3 is methyl; and R6 is a saturated linear alkyl chain having from 15 to 17 carbon atoms.
Claim 6
Dependent Claim 36 words
A fabric conditioning/stain removal composition characterised by: (a) a fabric conditioning agent according to any of claims 1 to 4, and (b) a stain removal agent selected from enzyme, peroxy bleach, halogen bleach, and porphine bleach.
Claim 7
Dependent Claim 60 words
A fabric conditioning/stain removal composition according to claim 5 wherein the enzyme is amylase, protease or lipase; the peroxygen bleach is an alkali metal salt of sodium perborate or sodium percarbonate or is diperoxyazelaic acid or diperoxydodecanedioic acid; the halogen bleach is sodium or potassium dichlorocyanurate or trichloro isocyanuric acid; and the porphine bleach is zinc or aluminium phthalocyanine sulfonate.
Claim 8
Dependent Claim 131 words
A fabric conditioning/stain removal composition according to claim 5 or 6 wherein when component (b) is enzyme, it is present at from 1 to 50% and the fabric conditioning agent is present at from 1% to 99%; when component (b) is peroxygen bleach, it is present at from 5% to 95% and the fabric conditioning agent is present at 1% to 95%; when component (b) is halogen bleach it is present at from 0.5 to 60% and the fabric conditioning agent is present at from 1% to 99.5%; and when component (b) is porphine bleach, it is present at from 0.005% to about 12% and the fabric conditioning agent is present at from 1% to 99.995% of the composition; wherein all percentages are by weight of the fabric conditioning/stain removal composition.
Claim 9
Dependent Claim 72 words
A fabric conditioning/stain removal composition according to claim 5 or 6 wherein the enzyme is protease or amylase; and wherein the amounts of the components, expressed in weight % based on the active ingredients of the fabric conditioning/stain removal composition, are: fabric conditioning agent from 5 to 99.995%; enzyme from 0 to 10%; peroxide bleach from 0 to 95%; halogen bleach from 0 to 10%; and porphine bleach from 0 to 1%.
Claim 10
Dependent Claim 47 words
A fabric cleaning/conditioning composition characterised by (A) an anionic, nonionic, amphoteric or zwitterionic surfactant; (B) a detergency builder; and (C) a fabric conditioning agent according to any of claims 1 to 4, wherein said surfactant and said detergency builder are present in the form of detergent granules.
Claim 11
Dependent Claim 96 words
A fabric ' cleaning/conditioning composition according to claim 9 wherein said surfactant is present in an amount from 1% to 50%, preferably from 5% to 30%, more preferably from 10% to 20% by weight of the composition; said detergency builder is present in an amount from 5% to 95%, preferably from 10% to 60%, more preferably from 15% to 40% by weight of the composition; and wherein said fabric conditioning agent is present in an amount from 1% to 30%, preferably from 3% to 20%, more preferably from 5% to 15% by weight of the composition.
Claim 12
Dependent Claim 26 words
A fabric cleaning/conditioning composition according to claim 9 or 10 wherein there is also present from 1% to 20%, preferably from 2% to 12% smectite clay.
Claim 13
Dependent Claim 43 words
A fabric cleaning/conditioning composition according to claim 11 wherein the smectite clay has a cation exchange capacity of at least 60 meq./100 gm. and is selected from the sodium and calcium montmorillonites; lithium, sodium and magnesium saponites; and lithium, sodium and magnesium hectorites.
Claim 14
Dependent Claim 45 words
A process for conditioning fabrics comprising the steps of: (a) contacting the fabrics with an effective amount of a fabric conditioning agent according to any of claims 1 to 4; and (b) subjecting the fabrics to a temperature within the range from 40°C. to 95°C.
Claim 15
Dependent Claim 28 words
A process according to claim 13 wherein the fabric conditioning agent is applied to tBe fabrics from an aqueous bath, for example a laundry wash or rinse liquor.
Claim 16
Dependent Claim 26 words
A process according to claim 13 wherein the fabrics are caused to tumble in relative motion to each other while being subjected to temperatures of 50-95°C.

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