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EP0122797A1 Expired / Lapsed EP ⏱️ 0.0 years remaining

Process for producing granular, water-swellable crosslinked acrylic copolymer, and its use

Assignee: Mitsui Chemicals Inc
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Filing: 1984-04-13
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Granted: —
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Expires: 2004-04-13
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Abstract

Abstract A process for producing a granular, water-swellable crosslinked acrylic copolymer, which comprises copolymerizing in an aqueous medium in the presence of a radical polymerization initiator a monomeric mixture comprising (a) at least one acrylic amide monomer selected from the group consisting of acrylamide, methacrylamide and N-methyl substitution products of these amides and (b) at least one acrylic crosslinkable comonomer selected from the group consisting of N,N min -alkylene- or arylene-bis-acrylamides, N,N min -alkylenebismethacrylamides, alkylenebisacrylates, alkylenebismethacrylates, alkylene glycolbisacrylates, polyalkylene glycol-bisacrylates, alkylene glycol-bismethacrylates and polyalkylene glycol-bismethacrylates, the proportion of the comonomer (b) being 0.01 to 5 moles per 100 moles of the acrylic amide monomer (a), and forming a granular copolymer; and (i) drying the resulting granular copolymer at a temperature of 105 to 150 DEG C, or (ii) heat-treating the resulting granular copolymer in the presence of moisture under substantially sealed conditions at a temperature of 100 to 160 DEG C; and a method of hydroponically growing a plant, which comprises growing the plant in artificial soil composed of a granular, water-swellable crosslinked acrylic copolymer.

Inventors

  • 👤 Narimichi Honda
  • 👤 Hiroshi Wakumoto
  • 👤 Takayuki Nakano
  • 👤 Hiromi Ueki
  • 👤 Jyunzo Hiratsuka

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-01 13:35
CPC Classifications
C; C08; C08F; C08F220/00; C08F220/02; C08F220/52; C08F220/54; A; A01; A01G; A01G24/00; A01G24/30; A01G24/35; A01G24/40; A01G24/42

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 136 words
A process for producing a granular, water-swellable crosslinked acrylic copolymer, which comprises copolymerizing in an aqueous medium in the presence of a radical polymerization initiator a monomeric mixture comprising (a) at least one acrylic amide monomer selected from acrylamide, methacrylamide and N-methyl substitution products of these amides and (b) at least one acrylic crosslinkable comonomer selected from N,N'-alkylene- or arylene-bisacrylamides, N,N'-alkylene-bismethacrylamides, alkylene-bisacrylates, alkylene-bismethacrylates, alkylene glycol-bisacrylates, polyalkylene glycol-bisacrylates, alkylene glycol-bismethacrylates and polyalkylene glycol-bismethacrylates, the proportion of the comonomer (b) being 0.01 to 5 moles per 100 moles of the acrylic amide monomer (a), and forming a granular copolymer; and (i) drying the resulting granular copolymer at a temperature of 105 to 150 0 C, or (ii) heat-treating the resulting granular copolymer in the presence of moisture under substantially sealed conditions at a temperature of 100 to 160°C.
Claim 2
Dependent Claim 136 words
A process for producing a granular, water-swellable crosslinked acrylic copolymer, which comprises copolymerizing in an aqueous medium in the presence of a radical polymerization initiator a monomeric mixture comprising (a) at least one acrylic amide monomer selected from acrylamide, methacrylamide and N-methyl substitution products of these amides and (b) at least one acrylic crosslinkable comonomer selected from N,N'-alkylene- or arylene-bisacrylamides, N,N'-alkylene-bismethacrylamides, alkylene-bisacrylates, alkylene-bismethacrylates, alkylene glycol-bisacrylates, polyalkylene glycol-bisacrylates, alkylene glycol-bismethacrylates and polyalkylene glycol-bismethacrylates, the proportion of the comonomer (b) being 0.01 to 5 moles per 100 moles of the acrylic amide monomer (a), and forming a granular copolymer; and (i) drying the resulting granular copolymer at a temperature of 105 to 150 0 C, or (ii) heat-treating the resulting granular copolymer in the presence of moisture under substantially sealed conditions at a temperature of 100 to 160°C.
Claim 3
Dependent Claim 22 words
A process according to claim 1 wherein the granular water-swellable crosslinked acrylic copolymer has a water swelling ratio of at least 65.
Claim 4
Dependent Claim 36 words
A process according to claim 1 or 2 wherein the resulting granular copolymer is (i) dried at 110 to 150°C, or (ii) heat-treated at 110 to 150°C in the presence of moisture under substantially sealed conditions.
Claim 5
Dependent Claim 29 words
Use of a granular water-swellable crosslinked acrylic copolymer when produced by a process as claimed in any one of claims 1 to 3 as an artificial soil for hydroponics.
Claim 6
Dependent Claim 42 words
Use of a granular copolymer as artificial soil in hydroponics, said granular copolymer being prepared by copolymerizing in an aqueous medium in the presence of a radical polymerization initiator a monomeric mixture as defined in claim 1 and forming a granular copolymer.

References Cited (Backward Citations)

EP0037138A2 Cited
JPS56145908A Cited

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