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EP0119023A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Improving catalytic activity of aluminosilicate zeolites

Assignee: BP PLC
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Filing: 1984-02-20
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Granted: —
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Expires: 2004-02-20
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Abstract

Abstract The present invention relates to a method of improving catalytic activity of a zeolite by first steam treating the zeolite and then loading the zeolite so treated with a Group IIIb metal, especially gallium. It has been found that steam treatment prior to gallium loading gives a catalyst which has a higher conversion and selectivity of hydrocarbon feeds to aromatics than otherwise.

Inventors

  • 👤 Clive David Telford
  • 👤 Dennis Young

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-03 04:51
CPC Classifications
B; B01; B01J; B01J29/00; B01J29/04; B01J29/06; B01J29/061

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 52 words
A process for activating an aluminosilicate loaded with a compound of a metal from Group IIIB of the Periodic Table said process comprising bringing into contact the unloaded zeolite with steam at an elevated temperature prior to loading thereof with a compound of a metal from Group IIIB of the Periodic Table.
Claim 2
Dependent Claim 52 words
A process for activating an aluminosilicate loaded with a compound of a metal from Group IIIB of the Periodic Table said process comprising bringing into contact the unloaded zeolite with steam at an elevated temperature prior to loading thereof with a compound of a metal from Group IIIB of the Periodic Table.
Claim 3
Dependent Claim 18 words
A process according to claim 1 wherein the aluminosilicate has a silica to alumina ratio greater than 5:1.
Claim 4
Dependent Claim 21 words
A process according to claims 1 or 2 wherein the Group IIIB metal is selected from aluminium, gallium, indium and thallium.
Claim 5
Dependent Claim 22 words
,4. A process according to any one of the preceeding claims wherein the compound of the Group IIIB metal is gallium oxide.
Claim 6
Dependent Claim 37 words
A process according to any one of the preceeding claims wherein the steaming step is carried out on a zeolite in which substantially all of the exchangeable metal ions have been exchanged with hydrogen or ammonium ions.
Claim 7
Dependent Claim 31 words
A process according to any one of the preceeding claims wherein the steam treatment of the zeolite is carried out using steam as such or a carrier gas stream comprising steam.
Claim 8
Dependent Claim 25 words
A process according to any one of the preceeding claims wherein the steam treatment is carried out at a pressure between 0.01 to 1.0 MPa.
Claim 9
Dependent Claim 24 words
A process according to any one of the preceeding claims wherein the steam treatment is carried out at a temperature from 300 to 750°C.
Claim 10
Dependent Claim 27 words
A process according to any one of the preceeding claims wherein the steam treatment is carried out for a duration of between 5 minutes and 200 hours.
Claim 11
Dependent Claim 39 words
A process for activating an alumina silicate loaded with a compound of a metal from Group IIIB of the Periodic Table as claimed in any one of the preceeding claims and as hereinbefore described with reference to the Examples.

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