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EP0116758A1 Expired / Lapsed EP ⏱️ 0.0 years remaining

Polyurethane polymer polyols made with aromatic nitrogen-containing polyols and polyurethanes therefrom

Assignee: Texaco Development Corp
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Filing: 1983-11-24
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Granted: —
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Expires: 2003-11-24
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Abstract

Abstract A polyurethane polymer polyol can be made by the reaction of an aromatic nitrogen-containing polyol, a polyether polyol and an organic polyisocyanate. The aromatic nitrogen-containing polyol may be made by reacting 2 to 5 moles of an alkylene oxide, e.g. ethylene or propylene oxide, with 1 mole of the Mannich reaction product of a mole of a phenol, e.g. phenol or nonylphenol, with 1 or 2 moles of a hydroxy amine, e.g. diethanolamine, and may have a molecular weight of 300 to 800. The polyether polyol may have a molecular weight of 3.000 to 8,000. This polyurethane polymer polyol may be used in the manufacture of flexible polyurethane foams which are firmer and stronger than similar products made using conventional polyols.

Inventors

  • 👤 Michael Cuscurida
  • 👤 George Phillip Speranza

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-08 15:50
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/65; C08G18/66; C08G18/6666; C08G18/667; C08G18/6681; C08G18/6688; C08G18/08; C08G18/10; C08G18/12; C08G18/40; C08G18/48; C08G18/4804; C08G18/482; C08G18/50; C08G18/5021; C08G18/5033; C08G18/54; C08G18/546; C08G2110/00; C08G2110/0008; C08G2110/0041; C08G2110/005; C08G2110/0083

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 53 words
A polyurethane polymer polyol made by the reaction of an aromatic nitrogen-containing polyol, a polyether polyol and an organic polyisocyanate characterized in that the molar ratio of aromatic nitrogen-containing polyol to polyether polyol is 0.5:1 to 3.5:1, and the molar ratio of total hydroxyl groups to isocyanate groups is from 1.5:1 to 3.0:1.
Claim 2
Dependent Claim 53 words
A polyurethane polymer polyol made by the reaction of an aromatic nitrogen-containing polyol, a polyether polyol and an organic polyisocyanate characterized in that the molar ratio of aromatic nitrogen-containing polyol to polyether polyol is 0.5:1 to 3.5:1, and the molar ratio of total hydroxyl groups to isocyanate groups is from 1.5:1 to 3.0:1.
Claim 3
Dependent Claim 71 words
A polyurethane polymer polyol according to claim 1 characterized in that the aromatic nitrogen-containing polyol is the reaction product of an alkylene oxide with a Mannich base from a phenol and an alkanolamine of the formula wherein R is hydrogen or alkyl having 1 to 4 carbon atoms, R' is hydrogen, alkyl having 1 to 4 carbon atoms or -(CHR) -OH, and n is a positive integer from 2 to 5.
Claim 4
Dependent Claim 52 words
A polyurethane polymer polyol according to claim 2 characterized in that the aromatic nitrogen-containing polyol is made by reacting from 2 to 5 moles of ethylene oxide or propylene oxide with 1 mole of the Mannich reaction product of 1 mole of phenol or nonylphenol with 1 or 2 moles of diethanolamine.
Claim 5
Dependent Claim 28 words
A polyurethane polymer polyol according to any one of the preceding claims characterized in that the aromatic nitrogen-containing polyol has a molecular weight of from 300 to 800.
Claim 6
Dependent Claim 26 words
A polyurethane polymer polyol according to any one of the preceding claims characterized in that the polyether polyol has a molecular weight from 3,000 to 8,000.
Claim 7
Dependent Claim 38 words
G. A method for producing a polyurethane by reacting a polyisocyanate with at least one active- hydrogen-containing compound, characterized in that the active hydrogen-containing compound comprises a polyurethane polymer polyol according to any one of the preceding claims.
Claim 8
Dependent Claim 20 words
A method according to claim 6 characterized in that the active hydrogen-containing compound additionally includes a polyol known per se.
Claim 9
Dependent Claim 25 words
A method according to claim 6 or 7 characterized by the presence of water and/or an organic blowing agent whereby to produce a polyurethane foam.

References Cited (Backward Citations)

US3264268A Cited
US3297597A Cited
US3655588A Cited
US4296213A Cited

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