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EP0115192B1 Expired / Lapsed EP ⏱️ 0.0 years remaining

Process for producing stretched filaments of ultrahigh-molecular-weight polyethylene

Assignee: Mitsui Chemicals Inc
•
Filing: 1983-12-23
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Granted: 1986-05-21
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Expires: 2003-12-23
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Abstract

No abstract record available.

Inventors

  • 👤 Masanori Motooka
  • 👤 Hitoshi Mantoku
  • 👤 Takao Ohno

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-04 02:42
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/18; B; B29; B29C; B29C48/00; B29C48/022; B29C48/03; B29C48/05; B29C48/07; B29C48/08; B29C48/25; B29C48/78; B29C48/80; B29C48/802; B29C48/86; B29C48/865; B29C48/88; B29C48/91; B29C48/919; C08F; C08F255/00; C08F255/02; C08L; C08L23/00; C08L23/02; C08L23/04; C08L23/06; D; D01; D01F; D01F6/00; D01F6/44; D01F6/46; B29C48/001; B29C48/0018; B29C48/15; B29C55/00; B29K; B29K2023/00; B29K2023/04; B29K2023/06; B29K2023/0658; B29K2023/0683; B29K2995/00; B29K2995/0037; B29K2995/0088; B29L; B29L2007/00; B29L2007/008; C08J2323/00; C08J2323/02; C08J2323/04; C08J2323/06

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 217 words
A process for producing a stretched article of ultrahigh-molecular-weight polyethylene, which comprises (1) melt-kneading a mixture composed of (A) 15 to 80 parts by weight, per 100 parts by weight of the components (A) and (B) combined, of ultrahigh-molecularweight polyethylene having an inherent viscosity [η], determined at 135°C in decalin, of at least 5 dl/g and (B) 85 to 20 parts by weight, per 100 parts by weight of the components (A) and (B) combined, of a paraffinic wax having a melting point, determined by the DSC method, of 40 to 120°C and a weight average molecular weight (Mw), determined by the GPC method, of at least 230 but less than 2,000 in a screw extruder while maintaining the temperature of the mixture at 180 to 280°C, (2) melt-extruding the molten mixture through a die kept at a temperature of 180 to 300°C, (3) cooling the resulting unstretched extrudate to solidify it, and (4) subjecting the unstretched solidified extrudate to a stretching treatment at a temperature of 60 to 140° C at a stretch ratio of at least about 3:1 when step (2) is carried out while a draft is applied to the unstretched extrudate or at a stretch ratio of at least about 10:1 when step (2) is carried out in the absence of a draft.
Claim 2
Dependent Claim 217 words
A process for producing a stretched article of ultrahigh-molecular-weight polyethylene, which comprises (1) melt-kneading a mixture composed of (A) 15 to 80 parts by weight, per 100 parts by weight of the components (A) and (B) combined, of ultrahigh-molecularweight polyethylene having an inherent viscosity [η], determined at 135°C in decalin, of at least 5 dl/g and (B) 85 to 20 parts by weight, per 100 parts by weight of the components (A) and (B) combined, of a paraffinic wax having a melting point, determined by the DSC method, of 40 to 120°C and a weight average molecular weight (Mw), determined by the GPC method, of at least 230 but less than 2,000 in a screw extruder while maintaining the temperature of the mixture at 180 to 280°C, (2) melt-extruding the molten mixture through a die kept at a temperature of 180 to 300°C, (3) cooling the resulting unstretched extrudate to solidify it, and (4) subjecting the unstretched solidified extrudate to a stretching treatment at a temperature of 60 to 140° C at a stretch ratio of at least about 3:1 when step (2) is carried out while a draft is applied to the unstretched extrudate or at a stretch ratio of at least about 10:1 when step (2) is carried out in the absence of a draft.
Claim 3
Dependent Claim 25 words
A process according to claim 1 wherein the weight average molecular weight of the paraffinic wax (B) is at least 230 but less than 1,000.
Claim 4
Dependent Claim 22 words
A process according to claim 1 or 2 wherein the inherent viscosity of the ultrahigh-molecular-weight polyethylene (A) is 5 to 30 dl/g.
Claim 5
Dependent Claim 22 words
A process according to claim 1, 2 or 3 wherein the melting point of the paraffinic wax (B) is 45 to 110°C.
Claim 6
Dependent Claim 67 words
A process according to any one of the preceding claims wherein the paraffinic wax (B) is selected from n-alkanes having at least 22 carbon atoms, mixtures of a major proportion of the n-alkanes and a minor proportion of lower n-alkanes, paraffin wax, polyethylene waxes, ethylene copolymer waxes, heat-degraded polyethylene waxes, heat-degraded ethylene copolymer waxes, oxidation products of these waxes, and alpha,beta-unsaturated acid-modified products of the foregoing waxes.

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