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EP0110683A1 Expired / Lapsed EP ⏱️ 0.0 years remaining

Determining the degree of cooking in a sulphite digester delignification

Assignee: Babcock and Wilcox Co
•
Filing: 1983-11-24
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Granted: —
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Expires: 2003-11-24
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Abstract

Abstract To determine the degree of cooking in a sulphite digester used for delignification, the digester temperature (T) and pressure (P d ) are sensed (12, 15) and utilised in a unit comprising a plurality of function blocks to calculate the digester reaction rate (k) according to the Arrhenius equation. This output is multiplied by a value proportional to the partial pressure (p S0 2 ) of sulphur dioxide in the digester to obtain a delignification rate value. The delignification rate value is integrated over time to determine the degree of cooking or Kappa Number. This num- beris compared to a desired set point value forthe Kappa Number. When the actual Kappa number reaches the desired set point, a signal is produced which is provided to an operator. Function blocks spread over two controller modules are utilised to achieve the needed calculations in a simple manner without the use of an analog or digital computer.

Inventors

  • 👤 Ralph K. Johnson
  • 👤 Marion A. Keyes Iv
  • 👤 Azmi Kaya

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-09 03:56
CPC Classifications
D; D21; D21C; D21C3/00; D21C3/22; D21C3/228; D21C3/04; D21C3/06

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 158 words
A method of determining the degree of cooking in a sulphite digester for delignification reactions, the method being characterised by: sensing (12) the digester temperature (T); sensing (15) the digester pressure (P d ); providing values corresponding to a plurality of constants including an energy of activity constant (E) for the digester reaction and the gas constant (R); continuously calculating the digester reaction rate (k) of the sulphite digester as a function of digester temperature (T), digester pressure (P d ) and the plurality of constants, to obtain values therefor over time; obtaining a value corresponding to the partial pressure of sulphur dioxide as a function of digester temperature (T) and pressure (P d ); multiplying the partial pressure value by the reaction rate value to obtain a delignification rate value; and integrating the delignification rate value over time to obtain a Kappa number for cooking in the digester which corresponds to the degree of cooking (CD) therein.
Claim 2
Independent Claim 158 words
A method of determining the degree of cooking in a sulphite digester for delignification reactions, the method being characterised by: sensing (12) the digester temperature (T); sensing (15) the digester pressure (P d ); providing values corresponding to a plurality of constants including an energy of activity constant (E) for the digester reaction and the gas constant (R); continuously calculating the digester reaction rate (k) of the sulphite digester as a function of digester temperature (T), digester pressure (P d ) and the plurality of constants, to obtain values therefor over time; obtaining a value corresponding to the partial pressure of sulphur dioxide as a function of digester temperature (T) and pressure (P d ); multiplying the partial pressure value by the reaction rate value to obtain a delignification rate value; and integrating the delignification rate value over time to obtain a Kappa number for cooking in the digester which corresponds to the degree of cooking (CD) therein.
Claim 3
Dependent Claim 21 words
A method according to claim 1, including calculating the digester reaction rate (k) according to the equation: where A is constant.
Claim 4
Dependent Claim 55 words
A method according to claim 1 or claim 2, wherein steam pressure (P ) in the digester is calculated (14) as a function of digester temperature (T) and a difference is taken (16) between the steam pressure (P ) and the digester pressure (Pd), which difference is proportional to the partial pressure of sulphur dioxide.
Claim 5
Dependent Claim 52 words
A method according to claim 1, -claim 2 or claim 3, including selecting a desired Kappa Number for a desired degree of cooking in the sulphite digester, comparing the desired Kappa number with the obtained Kappa number, and, when the desired Kappa number corresponds to the obtained Kappa number, generating a signal.
Claim 6
Dependent Claim 223 words
Apparatus for determining the degree of cooking in a sulphite digester for delignification, the apparatus being characterised by: a first sensor (12) for sensing a digester temperature (T); a second sensor (15) for sensing a digester pressure (P d ); a first controller module (10) connected to the first and second sensors (12, 15) and having means (18 to 20) for providing a plurality of constants including an energy of activity constant (E) for the digester reaction and the gas constant (R); means in the first controller module (10) for continuously calculating a digester reaction rate (k) of the digester as a function of digester temperature (T), pressure (P d ), and the plurality of constants to obtain values therefor over time; means in the first controller module (10) for obtaining a value corresponding to the partial pressure of sulphur dioxide in the digester as a function of the digester temperature (T) and pressure (P d ); at least one multiplier in the first controller module . (10) for multiplying the partial pressure value by the digester reaction rate value to obtain a delignification rate value; and a second controller module (30) connected to the first controller module (10) for receiving the delignification rate value and integrating the delignification rate value over time to obtain a Kappa value of cooking in the digester.
Claim 7
Dependent Claim 223 words
Apparatus for determining the degree of cooking in a sulphite digester for delignification, the apparatus being characterised by: a first sensor (12) for sensing a digester temperature (T); a second sensor (15) for sensing a digester pressure (P d ); a first controller module (10) connected to the first and second sensors (12, 15) and having means (18 to 20) for providing a plurality of constants including an energy of activity constant (E) for the digester reaction and the gas constant (R); means in the first controller module (10) for continuously calculating a digester reaction rate (k) of the digester as a function of digester temperature (T), pressure (P d ), and the plurality of constants to obtain values therefor over time; means in the first controller module (10) for obtaining a value corresponding to the partial pressure of sulphur dioxide in the digester as a function of the digester temperature (T) and pressure (P d ); at least one multiplier in the first controller module . (10) for multiplying the partial pressure value by the digester reaction rate value to obtain a delignification rate value; and a second controller module (30) connected to the first controller module (10) for receiving the delignification rate value and integrating the delignification rate value over time to obtain a Kappa value of cooking in the digester.
Claim 8
Dependent Claim 37 words
Apparatus according to claim 5, wherein the first and second controller modules (10, 30) include a plurality of function blocks each for conducting one of a comparison function, an arithmetic function, and a plurality of arithmetic functions.
Claim 9
Dependent Claim 151 words
Apparatus according to claim 5 or claim 6, wherein the first controller module (10) includes a first function generator (14) for receiving a signal from the first sensor (12) and generating a value corresponding to a steam pressure (P ) of the digester, a comparator (16) connected to the first function generator (14) and the second sensor (15) for obtaining a difference between the steam pressure (P ) and digester pressure (P d ), a second function generator (17) connected to the comparator (16) for generating a value corresponding to the partial pressure of sulphur dioxide in the digester, the second function generator (17) being connected to said at least one multiplier of the first controller module (10), and an Arrhenius equation unit (23) connected to the first sensor (12) and connected to the means (18 to 20) for providing the plurality of constants for generating the digester reaction rate value.
Claim 10
Dependent Claim 79 words
Apparatus according to claim 5, claim 6 or claim 7, wherein the second controller module (30) includes means (32, 33) for manually setting a percent total sulphur dioxide value and a percent-free sulphur dioxide value and a comparator (34) connected to the total and free sulphur dioxide setting means (32, 33) for obtaining a difference therebetween, the comparator (34) being connected in the second controller module (30) through a multiplier (37) for multiplying said difference with the delignification rate.

References Cited (Backward Citations)

US3941649A Cited

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