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EP0103448A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Production of sintered glasses and ceramics

Assignee: Corning Glass Works
•
Filing: 1983-09-05
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Granted: —
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Expires: 2003-09-05
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Abstract

Abstract A process for the production of a glass or ceramic article comprising a vapour phase oxidation wherein vaporized compounds are oxidized to form particulate oxide soot which is captured and consolidated to a unitary article by sintering, characterised in that at least one of the compounds is a β-diketonate complex of a metal selected from Groups IA, IB, IIA, IIB, IIIA, IIIB, IVA, IVB and the rare earth series of the Periodic Table is disclosed. A process for the production of a glass optical waveguide comprising a vapour phase oxidation wherein compounds of selected metals are vaporized, the vapours are transported to an oxidation site, the vapours are oxidized at the site to form particulate metal oxide soot, the soot is captured and consolidated into clear glass and the glass is drawn into optical waveguide fibre, characterised in that at least one of the compounds is a β-diketonate complex of a metal selected from Groups lA, IB, IIA, IIB, IIIA, IIIB, IVA, IVB and the rare earth series of the Periodic Table is also disclosed. The present invention offers advantages over the prior art.

Inventors

  • 👤 Stephen Bruce Miller
  • 👤 Ronald Leroy Stewart
  • 👤 David Allen Thompson

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-05 11:40
CPC Classifications
C; C07; C07C; C07C45/00; C07C45/77; C03; C03B; C03B19/00; C03B19/14; C03B19/1415; C03B37/00; C03B37/01; C03B37/012; C03B37/014; C03B37/01413; C03C; C03C1/00; C03C13/00; C03C13/04; C03C13/045; C03C13/046; C03C3/00; C03C3/04; C03C3/06; C04; C04B; C04B35/00; C04B35/622; C04B35/626; C04B35/63; C04B35/632; C04B35/6325; C07C49/00; C07C49/92; C07F; C07F3/00; C07F3/003; C03B2207/00; C03B2207/30; C03B2207/32; C03B2207/80; C03B2207/85; C03B2207/87; C03B2207/90; C03C2201/00; C03C2201/06; C03C2203/00; C03C2203/40; Y; Y10; Y10S; Y10S65/00; Y10S65/901

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 73 words
A process for the production of a glass or ceramic article comprising a vapour phase oxidation wherein vaporized compounds are oxidized to form particulate oxide soot which is captured and consolidated to a unitary article by sintering, characterised in that at least one of the compounds is a β-diketonate complex of a metal selected from Groups IA, IB, IIA, IIB, IIIA, IIIB, IVA, IVB and the rare earth series of the Periodic Table.
Claim 2
Dependent Claim 73 words
A process for the production of a glass or ceramic article comprising a vapour phase oxidation wherein vaporized compounds are oxidized to form particulate oxide soot which is captured and consolidated to a unitary article by sintering, characterised in that at least one of the compounds is a β-diketonate complex of a metal selected from Groups IA, IB, IIA, IIB, IIIA, IIIB, IVA, IVB and the rare earth series of the Periodic Table.
Claim 3
Dependent Claim 97 words
A process for the production of a glass optical waveguide comprising a vapour phase oxidation wherein compounds of selected metals are vaporized, the vapours are transported to an oxidation site, the vapours are oxidized at the site to form particulate metal oxide soot, the soot is captured and consolidated into clear glass and the glass is drawn into optical waveguide fibre, characterised in that at least one of the compounds is a β-diketonate complex of a metal selected from Groups IA, IB, IIA, IIB, IIIA, IIIB, IVA, IVB and the rare earth series of the Periodic Table.
Claim 4
Dependent Claim 97 words
A process for the production of a glass optical waveguide comprising a vapour phase oxidation wherein compounds of selected metals are vaporized, the vapours are transported to an oxidation site, the vapours are oxidized at the site to form particulate metal oxide soot, the soot is captured and consolidated into clear glass and the glass is drawn into optical waveguide fibre, characterised in that at least one of the compounds is a β-diketonate complex of a metal selected from Groups IA, IB, IIA, IIB, IIIA, IIIB, IVA, IVB and the rare earth series of the Periodic Table.
Claim 5
Dependent Claim 56 words
A process as claimed in claim 1 or claim 2 wherein the metal is selected from Li, Na, Be, Mg, Sc, Y, Cu, Hf, Zr, Ti, Zn, Cd, Al, Ga, Tl and Ce and wherein the β-diketonate complex has a vapour pressure of at least 10 mm Hg (13.34 millibars) at a temperature not exceeding 250°C.
Claim 6
Dependent Claim 27 words
A process as claimed in any of claims 1 to 3 wherein the β-diketonate complex comprises a β-diketonate ligand having a formula weight of at least 153.
Claim 7
Dependent Claim 22 words
5-. A process as claimed in any of claims 1 to 4 wherein the β-diketonate ligand is derived from a fluorinated β-diketone..
Claim 8
Dependent Claim 26 words
A process as claimed in any of claims 1 to 4 wherein the β-diketonate ligand is selected from (tfa), (hfa), (thd), (dfhd), (tod) and (fod) ligands.
Claim 9
Dependent Claim 23 words
A process as claimed in any of claims 1 to 6 wherein the β-diketonate complex is adducted with at least one Lewis base.
Claim 10
Dependent Claim 13 words
A process as claimed in claim 7 wherein the Lewis base is tetrahydrofuran.
Claim 11
Dependent Claim 23 words
A process as claimed in any of claims 1 to 8 wherein the particulate metal oxide soot is captured on a rotating mandrel.
Claim 12
Dependent Claim 30 words
A process as claimed in any of claims 1 to 9 wherein the captured soot is treated prior to or during consolidation to remove water, carbon and/or fluorine impurities therefrom.

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