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EP0097789A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Method of filling trenches in semiconductor substrates with silicon

Assignee: International Business Machines Corp
•
Filing: 1983-05-02
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Granted: —
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Expires: 2003-05-02
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Abstract

Abstract A relatively deep trench let into a surface of a semiconductor substrate is filled with silicon to provide a void-free isolation region by covering the semiconductor surface into which the trench is let and the base (3) and/or the side walls (4) of the trench with non-nucleating material (7), providing a layer of nucleating material (8) on at least a portion of the surface of the non-nucleating material and growing silicon (9) perpendicularly from the base or sidewalls of the trench.

Inventors

  • 👤 Linda Mero Ephrath
  • 👤 Victor Joseph Silvestri
  • 👤 Denny Duan-Lee Tang

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-31 10:02
CPC Classifications
H; H10; H10P; H10P14/00; H10P14/20; H10P14/24; H10P14/27; H10P14/271; H10P14/29; H10P14/2901; H10P14/2902; H10P14/2905; H10P14/34; H10P14/3402; H10P14/3404; H10P14/3411; H10W; H10W10/00; H10W10/01; H10W10/041; H10W10/40; H10W20/00; H10W20/01; H10W20/021

Claims Analysis

Total Claims: 26
Claim 1
Independent Claim 73 words
A method of filling a trench let into a surface of a semiconductor substrate with silicon, comprising the steps of covering the semiconductor surface into which the trench is let and the base and/or the side walls of the trench with non-nucleating material, providing a layer of nucleating material on at least a portion of the surface of the non-nucleating material and growing silicon perpendicularly from the base or sidewalls of the trench.
Claim 2
Independent Claim 73 words
A method of filling a trench let into a surface of a semiconductor substrate with silicon, comprising the steps of covering the semiconductor surface into which the trench is let and the base and/or the side walls of the trench with non-nucleating material, providing a layer of nucleating material on at least a portion of the surface of the non-nucleating material and growing silicon perpendicularly from the base or sidewalls of the trench.
Claim 3
Dependent Claim 23 words
A method as claimed in claim 1, in which the sidewalls of the trench are vertical or less than 5° from the vertical.
Claim 4
Dependent Claim 35 words
A method as claimed in claim 1 or claim 2, in which the ratio of the depth of the trench to the width of the trench between about 3.5 to 1 and 2.5 to 1.
Claim 5
Independent Claim 32 words
A method as claimed in any preceding claim, in which the depth of the trench is about 3.5 to about 4 microns and the width is about 1 to about 2 microns.
Claim 6
Independent Claim 21 words
A method as claimed in any preceding claim, in which the non-nucleating material comprises silicon dioxide, silicon nitride, or aluminium oxide.
Claim 7
Independent Claim 21 words
A method as claimed in any preceding claim, in which the non-nucleating layer is about 0.2 to about 0.5 nm thick.
Claim 8
Independent Claim 23 words
A method as claimed in any preceding claim, in which the layer of nucleating material is about 300 to about 2500 angstroms thick.
Claim 9
Independent Claim 16 words
A method as claimed in any preceding claim, in which the nucleating material is polycrystalline silicon.
Claim 10
Independent Claim 17 words
A method as claimed in any preceding claim, in which the semiconductor substrate is a silicon substrate.
Claim 11
Dependent Claim 64 words
10 A method as claimed in any preceding claim, in which (Figs 1 to 6) both the side walls and the base of the trench are covered with the non-nucleating material and the layer of nucleating material is provided on the substrate surface into which the trench is let and on the base of the trench, but not on the sidewalls of the trench.
Claim 12
Independent Claim 51 words
A method as claimed in any of claims 1 to 9, in which (Fig 7) the sidewalls but not the base, of the trench are covered with the non-nucleating material and the nucleating material is provided only on the non-nucleating material covering the substrate surface into which the trench is let.
Claim 13
Independent Claim 56 words
A method as claimed in any of claims 1 to 9, in which (Fig 8) the sidewalls, but not the base, of the trench are covered with the non-nucleating material and the nucleating material is provided on the non-nucleating material covering the sidewalls of the trench and the substrate surface into which the trench is let.
Claim 14
Independent Claim 49 words
A method as claimed in any of claims 1 to 9, in which (Fig 9) the sidewalls, but not the base, of the trench are covered with the non-nucleating material and the layer of nucleating material is provided only on the non-nucleating material covering the sidewalls of the trench.
Claim 15
Independent Claim 46 words
A method as claimed in any of claims 1 to 9, in which (Fig 10) both the base and the sidewalls of the trench are covered with the non-nucleating material and the layer of nucleating material is provided over the whole surface of the non-nucleating material.
Claim 16
Independent Claim 55 words
A method as claimed in any of claims 1 to 9, in which (Fig 11) the sidewalls, but not the base, of the trench are covered with the non-nucleating material and the layer of nucleating material is provided over the whole surface of the non-nucleating material and over the exposed substrate base of the trench.
Claim 17
Independent Claim 57 words
A method as claimed in any of claims 1 to 9, in which (Figs 12 and 13) the base, but not the sidewalls, of the trench is covered with the non-nucleating material and the layer of nucleating material is provided on the uncovered substrate sidewalls of the trench and over the whole surface of the non-nucleating material.
Claim 18
Independent Claim 20 words
A method as claimed in any preceding claim, in which the silicon is grown by a gas-solid heterogeneous reaction system.
Claim 19
Dependent Claim 18 words
A method as claimed in claim 17, in which the heterogeneous reaction system includes hydrogen, silicon, and chlorine.
Claim 20
Dependent Claim 23 words
A method as claimed in claim 18, in which the heterogeneous reaction system is a combination of SiCl 4 and H 2 .
Claim 21
Independent Claim 26 words
A method as claimed in any of claims 17 to 19, in which the silicon is grown at a temperature between about 900 and about 1100°C.
Claim 22
Independent Claim 26 words
A method as claimed in any of claims 17 to 20, in which the silicon is grown in a period of less than about 20 minutes.
Claim 23
Independent Claim 22 words
A method as claimed in any preceding claim, further comprising planarizing the surface of the structure after the silicon has been grown.
Claim 24
Dependent Claim 18 words
A method as claimed in claim 22, in which the planarizing is carried out by reactive ion etching.
Claim 25
Dependent Claim 25 words
A method as claimed in claim 23, in which the planarizing is carried out employing a gaseous mixture of 0 2 and CF 4 .
Claim 26
Dependent Claim 30 words
A method as claimed in claim 24, in which the gaseous mixture contains about 20% 0 2 and is at a pressure of about 100 millitorr (13.3 N/m 2 ).

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