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EP0083408A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Methods and apparatus for testing lithographic masks using electron beam scanning

Assignee: International Business Machines Corp
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Filing: 1982-11-05
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Granted: —
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Expires: 2002-11-05
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Abstract

Abstract In electron beam testing systems wherein high energy, 'high resolution electron beams 14 are used to test litho- tgraphic masks 16, a technique and apparatus is described for discharging electrons which are left on the surface of the mask. The materials used in these masks e.g. for substrate are such that induced photoconductivity and photoemissivity are extremely low and are incapable of providing sufficient eletron discharge. The electrons are discharged by using a thin, low work function (e.g. between 1 and 3eV) coating 20 which is applied over the entire mask surface, the coating 20 being transparent to the radiation which will later be incident upon the mask when it is used in a fabrication process. Due to induced photoemission in the thin coating layer, enough photoemitted electrons will be produced to balance the buildup of electrons from the electron beam, thereby discharging the surface of the mask. The electron beam is a high energy beam, having energies greater than about 5000 eV, and a resolution less than about 1 micrometer. Cesium telluride (CsTe) is a suitable coating material.

Inventors

  • 👤 Warren David Grobman

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-02 15:01
CPC Classifications
G; G03; G03F; G03F1/00; G03F1/68; G03F1/82; G03F1/84; G03F1/86; G01; G01N; G01N23/00; G01N23/20; G01N23/203; G03F1/38; G03F1/40

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 167 words
A method for testing a mask to be used in a lithographic process wherein radiation is directed onto said mask, said mask including a patterned layer of material on a substrate in which photoconductivity and photoemissivity cannot be easily induced, including the steps of: coating said patterned layer with a thin layer of a low work function material in which photoemission can readily be induced, said coating being substantially transparent to an electron beam and to said radiation, scanning said patterned layer with an electron beam to test for defects in said patterned layer, said electron beam causing a buildup of electrons on the surface of said coated mask, and directing ultraviolet light onto said coated mask in an area overlapping the area of said mask being hit by said electron beam to cause photoemission of electrons from said thin coating layer in an amount to produce a positive charge thereon sufficient to balance the negative charge induced by the incidence of electrons from said electron beam.
Claim 2
Independent Claim 167 words
A method for testing a mask to be used in a lithographic process wherein radiation is directed onto said mask, said mask including a patterned layer of material on a substrate in which photoconductivity and photoemissivity cannot be easily induced, including the steps of: coating said patterned layer with a thin layer of a low work function material in which photoemission can readily be induced, said coating being substantially transparent to an electron beam and to said radiation, scanning said patterned layer with an electron beam to test for defects in said patterned layer, said electron beam causing a buildup of electrons on the surface of said coated mask, and directing ultraviolet light onto said coated mask in an area overlapping the area of said mask being hit by said electron beam to cause photoemission of electrons from said thin coating layer in an amount to produce a positive charge thereon sufficient to balance the negative charge induced by the incidence of electrons from said electron beam.
Claim 3
Independent Claim 237 words
A method for testing lithographic masks to be used in lithographic processes wherein radiation is directed onto said mask, including the steps of: placing said masks in a vacuum environment in which a scanning electron beam will be directed to said mask for detection of said faults therein, said mask including a substrate having a patterned layer thereon, said patterned layer including first regions which are transparent to said radiation and second regions which are opaque to said radiation, said substrate being comprised of a material in which photoconductivity and photoemission are only very weakly induced by ultraviolet excitation having an energy spectrum less than about 6eV, coating said mask with a thin layer of a material having a low work function in which photoemission can readily be induced, said coating being substantially transparent to said radiation, testing said mask by impinging a high resolution scanning electron beam thereon over an area termed a scan field, said testing producing a net negative charge due to the electrons incident on said mask, producing a net positive charge of an amount sufficient to balance the said negative charge in order to discharge said mask, said net positive charge being produced by the application of ultraviolet energy having an energy spectrum of energies less than 6eV, where said ultra- violet radiation is applied to said thin coating layer over an area which overlaps said scan field of said electron beam.
Claim 4
Independent Claim 237 words
A method for testing lithographic masks to be used in lithographic processes wherein radiation is directed onto said mask, including the steps of: placing said masks in a vacuum environment in which a scanning electron beam will be directed to said mask for detection of said faults therein, said mask including a substrate having a patterned layer thereon, said patterned layer including first regions which are transparent to said radiation and second regions which are opaque to said radiation, said substrate being comprised of a material in which photoconductivity and photoemission are only very weakly induced by ultraviolet excitation having an energy spectrum less than about 6eV, coating said mask with a thin layer of a material having a low work function in which photoemission can readily be induced, said coating being substantially transparent to said radiation, testing said mask by impinging a high resolution scanning electron beam thereon over an area termed a scan field, said testing producing a net negative charge due to the electrons incident on said mask, producing a net positive charge of an amount sufficient to balance the said negative charge in order to discharge said mask, said net positive charge being produced by the application of ultraviolet energy having an energy spectrum of energies less than 6eV, where said ultra- violet radiation is applied to said thin coating layer over an area which overlaps said scan field of said electron beam.
Claim 5
Dependent Claim 21 words
A method as claimed in claim 2 in which said scan field of said electron beam is a few millimeters wide.
Claim 6
Dependent Claim 25 words
.A method as claimed in claim 1, 2 or 3 in which said electron beam has a high beam energy greater than about 5000 eV.
Claim 7
Independent Claim 22 words
A method as claimed in any one of claims 1 to 4 in which said mask is an optical or x-ray mask.
Claim 8
Independent Claim 26 words
A method as claimed in any one of claims 1 to 5, in which the thickness of said thin coating layer is less than approximately 1000A.
Claim 9
Independent Claim 26 words
A method as claimed in any one of claims 1 to 6, in which said thin coating layer has a work function less than approximately 3eV.
Claim 10
Dependent Claim 17 words
A method as claimed in claim 7, in which the work function is between 1 and 2eV.
Claim 11
Independent Claim 26 words
A method as claimed in any one of claims 1 to 8, in which said ultra-violet radiation includes a spectrum of energies less than approximately 6eV.
Claim 12
Independent Claim 28 words
A method as claimed in any one of claims 1 to 9, in which said thin coating layer comprises CsTe, CsI, or one of the alkali metal halides.
Claim 13
Dependent Claim 41 words
A method as claimed in claim 1, in which said mask comprises a patterned layer of chromium on a glass substrate, and said thin coating layer has a thickness less than about 100OR and a work function less than about 3eV.
Claim 14
Dependent Claim 1 words
1
Claim 15
Dependent Claim 1 words
1
Claim 16
Independent Claim 287 words
An apparatus for testing lithography masks, said masks being used in lithographic processes wherein radiation is directed onto said masks for exposure of layers behind said masks, comprising in combination: a mask comprising a patterned layer located on a substrate, said patterned layer including first regions which are substantially transparent to said radiation and second regions which are substantially opaque to said radiation, said substrate being comprised of a material which does not strongly support induced photoconductivity and photoemission at excitations less than about 6eV, a thin coating layer formed on said patterned layer comprised of a material which exhibits a strong photoemissive effect at an excitation less than about 6eV, said coating layer being sufficiently thin that it is transparent to said radiation, a vacuum chamber into which said mask is placed for testing, an electron beam source for directing a high energy scanning beam of electrons into said vacuum chamber and onto said coated mask for testing said mask, said electron beam striking said mask over an area defined as a scan field, the intensity of said electron beam being sufficient that negative charge will occur on said coated mask of an amount sufficient to alter the trajectory of said electron beam to thereby cause errors in the testing of said masks, means for shining ultraviolet light of an energy less than about 6eV on said mask in an area overlapping said scanned field for producing photoemission from said thin coating layer of an amount to produce a net positive charge which balances the net negative charge produced by said electron beam to thereby sufficiently discharge the surface of said coated mask so that the trajectory of the scanning electron beam is not adversely affected.
Claim 17
Independent Claim 287 words
An apparatus for testing lithography masks, said masks being used in lithographic processes wherein radiation is directed onto said masks for exposure of layers behind said masks, comprising in combination: a mask comprising a patterned layer located on a substrate, said patterned layer including first regions which are substantially transparent to said radiation and second regions which are substantially opaque to said radiation, said substrate being comprised of a material which does not strongly support induced photoconductivity and photoemission at excitations less than about 6eV, a thin coating layer formed on said patterned layer comprised of a material which exhibits a strong photoemissive effect at an excitation less than about 6eV, said coating layer being sufficiently thin that it is transparent to said radiation, a vacuum chamber into which said mask is placed for testing, an electron beam source for directing a high energy scanning beam of electrons into said vacuum chamber and onto said coated mask for testing said mask, said electron beam striking said mask over an area defined as a scan field, the intensity of said electron beam being sufficient that negative charge will occur on said coated mask of an amount sufficient to alter the trajectory of said electron beam to thereby cause errors in the testing of said masks, means for shining ultraviolet light of an energy less than about 6eV on said mask in an area overlapping said scanned field for producing photoemission from said thin coating layer of an amount to produce a net positive charge which balances the net negative charge produced by said electron beam to thereby sufficiently discharge the surface of said coated mask so that the trajectory of the scanning electron beam is not adversely affected.
Claim 18
Dependent Claim 40 words
Apparatus as claimed in claim 12, in which said mask is an optical mask comprising a patterned layer of chromium on a glass substrate or an x-ray mask comprising a patterned layer of a heavy metal on an insulating substrate.
Claim 19
Dependent Claim 22 words
Apparatus as claimed in claim 12 or 13, in which said thin coating layer as a work function less than approximately 3eV.
Claim 20
Dependent Claim 22 words
Apparatus as claimed in claim 12, 13 or 14, in which said thin coating layer has a thickness less than about 1000R.
Claim 21
Dependent Claim 25 words
Apparatus as claimed in any one of claims 12 to 15, in which said electron beam has a beam energy greater than about 5000 eV.
Claim 22
Dependent Claim 24 words
Apparatus as claimed in any one of claims 12 to 16, in which said electron beam has a resolution less than about 1 micrometer.

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